欢迎登录材料期刊网

材料期刊网

高级检索

将镀锌钢试样浸入饱和Zn(OH)2海水溶液中以模拟腐蚀环境,采用失重法、扫描电镜(SEM)、极化曲线和交流阻抗谱研究了海水中Zn(OH)2对镀锌钢腐蚀行为的影响.结果表明:电极表面上由于腐蚀产物Zn(OH)2的吸附,镀锌层的膜结构遭到破坏,随着浸泡时间的延长,镀锌钢表面发生腐蚀反应时的电荷转移电阻逐渐减小,自腐蚀电流密度逐渐增大,腐蚀产物Zn(OH)2的吸附诱导了镀锌层表面点蚀的发生.

参考文献

[1] N.S. Azmat;K.D. Ralston;B.C. Muddle;I.S. Cole .Corrosion of Zn under fine size aerosols and droplets using inkjet printer deposition and optical profilometry quantification[J].Corrosion Science,2011(11):3534-3541.
[2] MOUANGA M;BERCOT P;RAUCH J Y .Comparison of corrosion behaviour of zinc in NaC1 and in NaOH solutions.part Ⅰ:corrosion layer characterization[J].Corrosion Science,2010,52(12):3984-3992.
[3] 孔纲,陈九龙,卢锦堂.饱和Ca(OH)2溶液pH值对热镀锌钢表面锌酸钙覆盖层的影响[J].材料工程,2010(09):74-79.
[4] 章江洪,张英杰.电镀锌稀土转化膜在5%NaCl溶液中耐蚀性能及耐蚀机理的研究[J].材料工程,2011(04):84-88,93.
[5] MUNOZ A G;SAIDMAN S B;BESSONE J B .Corrosion of an A1-Zn-In alloy in chloride media[J].Corrosion Science,2002,44(10):2171-2182.
[6] 刘栓,孙虎元,范汇吉,孙立娟,刘增文.镀锌钢腐蚀行为的研究进展[J].材料保护,2012(12):42-45.
[7] Shuan Liu;Huyuan Sun;Lijuan Sun;Huiji Fan .Effects of pH and Cl~- concentration on corrosion behavior of the galvanized steel in simulated rust layer solution[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2012(Dec.):520-527.
[8] Eiji Tada;Keiichi Sugawara;Hiroyuki Kaneko .Distribution of pH during galvanic corrosion of a Zn/steel couple[J].Electrochimica Acta,2004(7):1019-1026.
[9] MAHDY G A;NISHIKATA A;TSURU T .AC impedance study on corrosion of 55 % Al-Zn alloy coated steel under thin electrolyte layers[J].Corrosion Science,2000,42(09):15091521.
[10] 臧贝妮,孙虎元,王巍,孙立娟.海水中Al(OH)3对稀土铝热浸镀层腐蚀行为的影响[J].材料保护,2011(07):18-19,34.
[11] SUN H Y;ZANG B N;LIU S et al.Effects of Zn(OH)2 on corrosion behavior of hot dipped Zn coating in freshwater[J].Current Advances in Materials and Processes,2012,399-401:152-155.
[12] Y. Zou;J. Wang;Y.Y. Zheng .Electrochemical techniques for determining corrosion rate of rusted steel in seawater[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2011(1):208-216.
[13] LI Y .Formation of nano crystalline corrosion products on Zn-Al alloy coating exposed to seawater[J].Corrosion Science,2001,43(09):1973-1800.
[14] The Use Of Inorganic Conversion Coatings To Enhance the Corrosion Resistance Of Reinforcement And The Bond strength At The Rebar/concrete[J].Construction and Building Materials,2009(1):233-238.
[15] Investigation of the major reduction reaction occurring during the passivation of galvanized steel rebars[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2010(3):978.
[16] 曹楚南.腐蚀电化学原理[M].北京:化学工业出版社,2008:99-119.
[17] 刘倞,胡吉明,张鉴清,曹楚南.基于高频电化学阻抗谱测试的涂层防护性能评价方法[J].腐蚀科学与防护技术,2010(04):325-328.
[18] 曹楚南;张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002:84-92.
[19] 胡融刚,黄若双,杜荣归,林昌健.氯离子侵蚀下钢筋在混凝土中腐蚀行为的EIS研究[J].物理化学学报,2003(01):46-50.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%