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采用反应动力学分析、表面分析、扫描电镜(SEM)和X射线能谱仪(EDS)研究了诸外因对改性海绵铁除氧行为的影响及除氧相关机理.结果表明:改性海绵铁表面铜含量增加对除氧能力的促进作用大于比表面积减小使除氧能力降低的影响.改性海绵铁除氧过程为反应控制过程并符合一级反应动力学方程.另外,诸外因中溶液初始pH值和初始电导率对除氧速率常数的影响规律是先增后减.增加改性海绵铁投加量和溶液温度对除氧速率常数的提高具有促进作用,但继续增加改性海绵铁的投加量并不能无限提高除氧速率常数,速率常数存在极限值为0.3663min-1.

参考文献

[1] 丁磊,黄继萍,朱桐.海绵铁在水处理中应用理论与实践[J].现代矿业,2009(07):41-45.
[2] 徐波;贾铭椿;门金凤.一种改性海绵铁制备方法与除氧能力研究[A].Irvine:Scientific Research Publishing,2011:265-270.
[3] 唐敖庆.化学动力学导论[M].长春:吉林人民出版社,1982
[4] SANGKIL NAM;PAUL G. TRATNYEK .REDUCTION OF AZO DYES WITH ZERO-VALENT IRON[J].Water research: A journal of the international water association,2000(6):1837-1845.
[5] ZHANG X;LIN Y M;CHEN Z L .2,4,6-trinitrotoluene reduction kinetics in aqueous solution using nanoscale zero-valent iron[J].Journal of Hazardous Materials,2009,165(1-3):923-927.
[6] Raghuraman Venkatapathy;David G.Bessingpas;Silvio Canonica;Judith A.Perlinger .Kinetics models for trichloroethylene transformation by zero-valent iron[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2002(2):139-159.
[7] He, F.;Zhang, M.;Qian, T.;Zhao, D. .Transport of carboxymethyl cellulose stabilized iron nanoparticles in porous media: Column experiments and modeling[J].Journal of Colloid and Interface Science,2009(1):96-102.
[8] Antoine Ghauch;Almuthanna Tuqan;Hala Abou Assi .Antibiotic removal from water: Elimination of amoxicillin and ampicillin by microscale and nanoscale iron particles[J].Environmental Pollution,2009(5):1626-1635.
[9] William J. Epolito;Hanbae Yang;Lawrence A. Bottomley;Spyros G. Pavlostathis .Kinetics Of Zero-valent Iron Reductive Transformation Of The Anthraquinone Dye Reactive Blue 4[J].Journal of hazardous materials,2008(2/3):594-600.
[10] TARR M A.Chemical Degradation Methods for Wastes and Pollutants-environmental and Industrial Applications[M].New York:Marcel Dekker,Inc,2003
[11] Baolin Deng;David R. Burris;Timothy J. Campbell .Reduction of vinyl chloride in metallic iron-water systems[J].Environmental Science & Technology: ES&T,1999(15):2651-2656.
[12] Choe S.;Hwang KY.;Khim J.;Chang YY. .Kinetics of reductive denitrification by nanoscale zero-valent iron[J].Chemosphere,2000(8):1307-1311.
[13] Lavine BK.;Ritter J.;Auslander G. .Polarographic studies of zero valent iron as a reductant for remediation of nitroaromatics in the environment[J].Microchemical Journal: Devoted to the Application of Microtechniques in all Branches of Science,2001(2):69-83.
[14] Juan M.Triszcz;Andres Porta;Fernando S.Garcia Einschlag .Effect of operating conditions on iron corrosion rates in zero-valent iron systems for arsenic removal[J].Chemical engineering journal,2009(2/3):431-439.
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