利用激光熔覆技术在0Cr18Ni9不锈钢基体上制备NiCr/Cr3C2耐磨涂层与NiCr/Cr3 C2-30% WS2耐磨自润滑涂层,采用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、能谱仪(EDS)分析了涂层的物相组成及显微组织.在室温、300℃和600℃下分别测试了上述涂层的干滑动摩擦学性能,并讨论其磨损机理.实验结果表明:添加WS2的熔覆涂层主要有Cr7C3、(Cr,W)C碳化物增强相、r(Fe,Ni)/Cr7C3共晶增韧相、WS2及CrS润滑相.两种涂层都随温度的升高,摩擦因数降低,而磨损率增大.在室温及300℃时,添加WS2涂层由于润滑相的作用拥有较好的减摩耐磨性能.在600℃时,由于涂层中碳化物硬质相的强度降低,两种涂层的磨损率显著增大.
参考文献
[1] | 李桂花,邹勇,邹增大,魏希旺,田宝林.激光熔覆原位生成Nb2(C,N)及V8C7陶瓷粒子增强铁基金属涂层[J].材料工程,2012(01):29-33. |
[2] | Xu J;Liu WJ;Zhong ML .Microstructure and dry sliding wear behavior of MoS2/TiC/Ni composite coatings prepared by laser cladding[J].Surface & Coatings Technology,2006(14/15):4227-4232. |
[3] | Donnet C;Erdemir A .Historical developments and new trends in tribological and solid lubricant coatings[J].Surface & Coatings Technology,2004(0):76-84. |
[4] | DONNET C;ERDEMIR A .Solid lubricant coatings:recent developments and future trends[J].Tribology Letters,2004,17(03):389-397. |
[5] | 曾维华,刘洪喜,王传琦,张晓伟,蒋业华.工艺参数对不锈钢表面激光熔覆Ni基涂层组织及耐腐蚀性能的影响[J].材料工程,2012(08):24-29. |
[6] | HUANG C B;DU L Z;ZHANG W G .Effects of solid content on the microstructure and properties of NiCr/Cr3C2-BaF2 @ CaF2 composite coatings[J].Journal of Alloys and Compounds,2009,479:777-784. |
[7] | 俞友军,周健松,陈建敏,周惠娣,郭纯.激光熔覆NiCr/Cr3C2-Ag-BaF2/CaF2金属基高温自润滑耐磨覆层的组织结构及摩擦学性能[J].中国表面工程,2010(03):64-69,73. |
[8] | 闫来成,谭华玉,韩欢庆,罗锡裕.一种低摩擦系数复合润滑膜的结构与性能研究[J].航空材料学报,2011(05):58-61. |
[9] | Wang AH;Zhang XL;Zhang XF;Qiao XY;Xu HG;Xie CS .Ni-based alloy/submicron WS2 self-lubricating composite coating synthesized by Nd : YAG laser cladding[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(1/2):312-318. |
[10] | 张祥林,章小峰,王爱华,乔晓勇.激光熔覆金属基固体自润滑涂层的组织结构[J].中国机械工程,2006(19):2084-2088. |
[11] | ZHANG Xiao-feng,ZHANG Xiang-lin,WANG Ai-hua,HUANG Zao-wen.Microstructure and properties of HVOF sprayed Ni-based submicron WS2/CaF2 self-lubricating composite coating[J].中国有色金属学会会刊(英文版),2009(01):85-92. |
[12] | 黄传兵,杜令忠,张伟刚.NiCr/Cr3C2-BaF2·CaF2高温自润滑耐磨涂层的制备与摩擦磨损特性[J].摩擦学学报,2009(01):68-74. |
[13] | 沈莲.机械工程材料[M].北京:机械工业出版社,2007:131-137. |
[14] | 何祥明,刘秀波,杨茂盛,石世宏,王明娣,傅戈雁.奥氏体不锈钢激光熔覆镍基复合涂层高温磨损行为[J].中国激光,2011(09):79-84. |
[15] | ZHANG H;SHI Y;KUTSUNA M et al.Laser cladding of colmony 6 powder on AISI316L austenitic stainless steel[J].Nuclear Engineering and Design,2010,240(10):2691-2696. |
[16] | 石岩,张宏,徐春鹰.激光熔覆科尔莫落依合金涂层的奥氏体不锈钢表面组织和耐磨性研究[J].兵工学报,2010(07):927-932. |
[17] | 刘秀波,虞钢,郭建,张振国,商全义,谷亦杰,崔洪芝.等离子熔覆γ/Cr7C3复合材料涂层组织与耐磨性研究[J].材料热处理学报,2006(06):114-117. |
[18] | Lu XD;Wang HM .Metallic tribological compatibility of laser clad Mo2Ni3Si/NiSi metal silicide coatings[J].Surface & Coatings Technology,2005(7):2380-2385. |
[19] | LIU Y;WANG H M .Elevated temperature wear behaviors of a Co-Mo-Si ternary metal silicide alloy[J].Scripta Materialia,2005,52:1235-1240. |
[20] | L. Q. Zhang;H. M. Wang .High-temperature sliding wear resistance of a Cr_3Si/Cr_(13)Ni_5Si_2 multiphase intermetallic alloy[J].Materials Letters,2003(18):2710-2715. |
[21] | Xiong DS. .Lubrication behavior of Ni-Cr-based alloys containing MoS2 at high temperature[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,2001(2):1094-1099. |
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