采用非平衡闭合场磁控溅射方法在Cr12MoV冷作模具钢表面制备不同Mo含量的CrMoN涂层,通过XRD、SEM、显微硬度和磨损试验分析涂层的相结构、表面性能和耐磨性.实验结果表明,CrMoN涂层均呈面心立方结构,无明显的柱状晶,其厚度随Mo含量的增加而增厚.CrMoN涂层显著提高了Cr12MoV钢的表面硬度和耐磨性,尤其是中等Mo含量(20.72%Mo)的涂层.经18h冲击磨损后,该涂层的磨损速率(5.3×10-5mm3/h)明显低于未表面处理试样(1.0×10-3mm3/h),微区逐层剥落的疲劳磨损为主要磨损机制.然而,低Mo含量涂层磨损速率略高于未表面处理试样,磨损机制从疲劳磨损转变为三体磨粒磨损.
参考文献
[1] | P. J. Kelly;R. D. Arnell .Magnetron sputtering: a review of recent developments and applications[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2000(3):159-172. |
[2] | 李佳,夏长清,刘昌斌,戴晓元.Al含量对(Ti,Al)N涂层结构性能的影响[J].材料导报,2003(12):29-31,35. |
[3] | Zhang G.Up-scaled Tecr-UDP850/4 Unbalanced Magnelron Deposition System Used for Maes-Productioa of CrTiAlN Hard Coatings[A].,2004:827-831. |
[4] | Hailin Sun;Susan Field.The Study of Deposition Parameters Properties for PVD TixN and CrxN Coatings Using a Closed Field Unbalanced Magnetron Spotter Ion Plating System[A].,2004:841-846. |
[5] | Yang S.Application of Cr-Based Metal Nitride Hard Coatings Using Mahi-Magnetron Sputtering Sources and Elemental Metal Targets[A].,2004:821-825. |
[6] | Lyo In-Woong;Aim Hyo-Sok;Lira Dae-soon .Microstrueluro and tribological properties of plasma-sprayed chromium oxidemolybdenum oxide composite coatings[J].Surface and Coatings Technology,2003,163-164:413-421. |
[7] | Kim KH;Choi EY;Hong SG;Park BG;Yoon JH;Yong JH .Syntheses and mechanical properties of Cr-Mo-N coatings by a hybrid coating system[J].Surface & Coatings Technology,2006(7):4068-4072. |
[8] | Koshy R A;Graham M E;Marks L D .Synthesis and characterization of CrN-Mo2N muhilayers and phases of Molybdenum nitride[J].Surfane & Coatings Technology,2007,202:1123-1128. |
[9] | Gu B;Tu JP;Zheng XH;Yang YZ;Peng SM .Comparison in mechanical and tribological properties of Cr-W-N and Cr-Mo-N multilayer films deposited by DC reactive magnetron sputtering[J].Surface & Coatings Technology,2008(10):2189-2193. |
[10] | Maria Nordin;Mats Larsson .Deposition and characterisation of multilayered PVD TiN/CrN coatings on cemented carbide[J].Surface & Coatings Technology,1999(0):108-115. |
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