基于炉渣结构的共存理论,建立了MnO-SiO2-Al2O3 三元渣系作用浓度的计算模型,考察了影响MnO作用浓度的影响因素.结果表明:模型计算所得的MnO作用浓度值NMnO与文献实测值αMnO(exp)非常吻合,且计算精度要高于正规溶液模型获得的计算值αMnO(cal),说明该模型能够反映该渣系的结构本质.利用此模型可以很好地预测Mn/Si脱氧钢的夹杂物成分,为生产高质量的帘线钢提供热力学参考.
参考文献
[1] | 王立峰,卓晓军,张炯明,王新华.冶金过程中帘线钢夹杂物成分控制[J].北京科技大学学报,2003(04):308-311. |
[2] | Sharma R A;Richardson F D .Activities of manganese oxide,sulfide capacities and activity coefficients in aluminate and silcate melts[J].Transactions of the AIME,1965,233:1586-1592. |
[3] | Toshiharu Fujisawa;Hiroshi Sakao .Equilibrium relations between the liquid iron alloys and the deoxidation products resulting from Mn-Si-Al complex deoxidation[J].Tetsu To Hagane-Journal of the Iron and Steel Institute of Japan,1977,63:1494-1503. |
[4] | Toshiharu Fujisawa;Hiroshi Sakao .Equilibrium between MnOS-Al2O3-FeO slags and liquid steel[J].Tetsu To Hagane-Journal of the Iron and Steel Institute of Japan,1977,63:1504-1151. |
[5] | HIROKI OHTA;HIDEAKI SUITO .Activities in MnO-SiO_2-Al_2O_3 Slags and Deoxidation Equilibria of Mn and Si[J].Metallurgical Transactions.B.Process Metallurgy,1996(2):263-270. |
[6] | DAE-HEE WOO;YOUN-BAE KANG;HAE-GEON LEE .Thermodynamic Study of MnO-SiO_2Al_2O_3 Slag System: Liquidus Lines and Activities of MnO at 1823K[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2002(6):915-920. |
[7] | Kang Y B;Lee H G .Inclusions chemistry for Mn/Si deoxidizedsteels; Thermodynamic predictions and experimental confirmslions[J].ISU International,2004,44(06):1006-1015. |
[8] | 张鉴 .关于炉渣结构的共存理论[J].北京钢铁学院学报,1984,1:21-29. |
[9] | 毛平;马延温;张鉴 .CaO-SiO2-Al2O3-MgO渣系的作用浓度模型及其应用[J].钢铁,1996,31:27-31. |
[10] | 梁小平,金杨,王雨,段红玲.RH精炼渣高熔点相作用浓度对粘渣的影响[J].过程工程学报,2009(02):324-328. |
[11] | 汪金良,张传福,童长仁,张文海.CaO-FeO-Fe2O3-SiO2-Cu2O渣系作用浓度计算模型[J].中南大学学报(自然科学版),2009(02):282-287. |
[12] | 成国光;张鉴 .Fe-S熔体作用浓度的计算模型[J].上海金属,1993,15:22-25. |
[13] | 陈家祥.炼钢常用数据图表手册[M].北京:冶金工业出版社,1984:122-123,134,145. |
[14] | 张鉴.冶金熔体和溶液的计算热力学[M].北京:冶金工业出版社,2007:318-319. |
[15] | Shiro Ban-ya .Mathematical expression of slag-metal reactions insteelmaking process by quadratic formalism based on the regularsolution model[J].ISU International,1993,33(01):2-11. |
[16] | Lumsden J.Physical chemistry of process metallurgy,Part I[M].New York:Interscience Publishers,1961:165. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%