由于只需几个物性参数和设定常数,Miedema模型就能简单地计算二元合金液相或者固相的热力学数据,而且计算值与实验值吻合度较高,因而被广泛应用于二元合金热力学的计算.在介绍了该理论的物理模型的基础上详细阐述了Miedema半经验公式的推导以及物性参数和常数的确定,并对此模型的应用和误差做了客观的分析和总结.
参考文献
[1] | 徐瑞.材料热力学与动力学[M].哈尔滨:哈尔滨工业大学出版社,2003 |
[2] | Miedema A R;de Chatel P F;de Boer F R .Cohesion in Alloys-fundamentals of A Semi-empirical Model[J].Physical B+C,1980,100(01):1-28. |
[3] | Miedema A R .A Simple Model for Alloys[J].Philips Technological Review,1973,33(06):149-161. |
[4] | Miedema A R .The Electronegativity Parameter for Transition Metals:Heat of Formation and Charge Transfer in Alloys[J].Journal of the Less-Common Metals,1973,32(01):117-136. |
[5] | Miedema A R;Boom R;De Boer F R .Work on the Heat of Formation of Solid Alloys[J].Journal of the Less-Common Metals,1975,41(02):283-298. |
[6] | Miedema A R .Work on the Heat of Formation of Solid AlloysII[J].Journal of the Less-Common Metals,1976,46(01):67-83. |
[7] | Miedema A R .Work on the Heat of Formation of Alloys[J].Philips Technological Review,1976,36(08):217-231. |
[8] | Miedema A R;De Boer F R;Boom R .Model Predictions for the Enthalpy of Formation of Transition Metal Alloys[J].CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,1977,40(01):341-359. |
[9] | Niessena A K;De Boer F R;Boom R .Model Predictions for the Enthalpy of Formation of Transition Metal Alloysll[J].CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,1983,7(01):51-70. |
[10] | De Boer F R;Boom R;Miedema A R.Cohesion in metals[M].Amsterdam:North-Holland Publishing Company,1988 |
[11] | 钱乙余,马鑫,薛松柏,Yoshida F.Cu-La和Pd-Sn二元合金混合焓的预测[J].中国稀土学报,2001(01):95-96. |
[12] | 孙顺平,易丹青,陈莹,吴春萍.Al-Er和Si-Er二元合金的热力学性质[J].中国有色金属学报,2009(09):1580-1586. |
[13] | Zhang BW.;Jesser WA. .Formation energy of ternary alloy systems calculated by an extended Miedema model[J].Physica, B. Condensed Matter,2002(1/3):123-132. |
[14] | 范鹏;周国治 .由组元的物性参数预测金属熔体的热力学性质[J].金属学报,1999,35(04):421-426. |
[15] | 罗利华;丁学勇;郭丹 等.活度相互作用系数数据库软件开发[J].金属学报,1998,34(04):388-392. |
[16] | Wang F M;Li X P;Han Q Y .A Model for Calculating Interaction Coefficients between Elements in Liquid and Iron-Base Alloy[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1995,28(01):109-113. |
[17] | Zhang RF;Sheng SH;Liu BX .Predicting the formation enthalpies of binary intermetallic compounds[J].Chemical Physics Letters,2007(4-6):511-514. |
[18] | Tanaka T;Gokcen N A;Morita Z I .Thermodynamic Relationship between Enthalpy of Mixing and Excess Entropy in Solid Solutions of Binary Alloys[J].Zeitschrift fur Metallkunde,1996,87(01):779-783. |
[19] | 陈星秋,丁学勇,刘新,郑海燕.二元合金熔体组元活度计算式的改进[J].金属学报,2000(05):492-496. |
[20] | 陈星秋,李海兰,丁学勇,P.Rogl.固态二元合金超额热力学函数的计算方法[J].东北大学学报(自然科学版),2001(03):299-302. |
[21] | 王丹,廖树帜,陈佳,谢斌,谢浩文,张邦维.Zr、Ti、Hf、Nb对NiAl非晶合金形成的亚规则模型[J].上海金属,2010(04):20-23. |
[22] | Chen Xingqiu;Podloucky R .Miedema's Model Revisited:The Parameter Ф* for Ti,Zr and Hf[J].Computer Coupling of Diagrams and Thermochemistry,2006,30:266. |
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