碳微球(CMSs)是一种良好的光伏电池受体材料,为了提高CMSs在有机溶剂中的分散性、与给体材料的相容性以及最低未占有分子轨道能级,系统考察了十二胺对CMSs的修饰效果.首先采用体积比为1∶3的浓硝酸和浓硫酸对CMSs进行氧化处理,使其表面引入含氧官能团；然后在缩合剂N,N'-二环己基碳二亚胺(DCC)的作用下,用十二胺修饰CMSs,制备胺化CMSs.在胺化过程中考察了缩合剂DCC用量、反应时间和反应温度对胺化效果的影响.采用场发射扫描电子显微镜、红外光谱仪和热重分析仪对各阶段产物的形貌和结构进行了表征,并用电化学循环伏安法对最终产物进行了分析.结果表明,对于0.2g氧化CMSs,0.4g DCC,16.0g十二胺,温度70℃,反应时间24h时,所得胺化CMSs粒径均匀,并且胺化CMSs在氯仿中的分散稳定性明显提高,可增加其加工性能和与给体材料的相容性,为制备聚合物太阳能电池奠定了基础.
参考文献
| [1] | 程立强,刘应亮,张静娴,袁定胜,徐常威,孙广辉.球形碳材料的研究进展[J].化学进展,2006(10):1298-1304. |
| [2] | Wang Q.;Li H.;Chen LQ.;Huang XJ. .Novel spherical microporous carbon as anode material for Li-ion batteries[J].Solid state ionics,2002(Pt.A):43-50. |
| [3] | Lee K T;Jung Y S;Oh S M .Synthesis of tin-encapsulated spheril hollow carbon for anode material in lithium secondary matteries[J].Journal of the American Chemical Society,2003,125(19):56525653. |
| [4] | Yi Zheng Jin;Yong Jung Kim;Chao Gao .High temperature annealing effects on carbon spheres and their applications as anode materials in Li-ion secondary battery[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(4):724-729. |
| [5] | Xu B S;Guo J J;Jia H S.Hard carbon spherules derived from deoiled asphalt as a catalyst support for direct methanol fuel cell[A].Saskatoon,2006 |
| [6] | A.W.Morawski;R.Kalenczuk;M.Inagaki .Adsorption of trihalomethanes (THMs) onto carbon spheres[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2000(2):107-112. |
| [7] | O. Tanaike;M. Fukuoka;M. Inagaki .Adsorption properties of air-oxidized carbon sphere derived from phenol resin[J].Synthetic Metals,2002(2):255-257. |
| [8] | Yuan DS;Chen JX;Zeng JH;Tan SX .Preparation of monodisperse carbon nanospheres for electrochemical capacitors[J].Electrochemistry communications,2008(7):1067-1070. |
| [9] | Novoselov K;Geim A;Morozov S et al.Electric field effect in atomicaly thin carbon films[J].Science,2004,306(5696):666-669. |
| [10] | Yu G;Gao J;Hummelen J C et al.Polymer photovolataic cells:enhanced efficiencies via a network of internal donor-acceptor heterojunctions[J].Science,1995,270(5243):1789-1791. |
| [11] | Youjun He;Hsiang-Yu Chen;Jianhui Hou;Yongfang Li .Indene-C60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells[J].Journal of the American Chemical Society,2010(4):1377-1382. |
| [12] | 李莎,段菲菲,杨永珍,刘旭光,许并社.硅烷偶联剂对碳微球的表面化学修饰[J].功能材料,2011(01):25-29. |
| [13] | Guo Xingmei;Yang Yongzhen;Zhao Xuexia;Liu Xuguang.Carbon spheres surface modification and dispersion in polymer matrix[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2012:159-165. |
| [14] | 张福华,王荣国,赫晓东,刘文博,尤洁.1.6-己二胺化学修饰多壁碳纳米管[J].新型炭材料,2009(04):369-374. |
| [15] | 屈泽华;王国建;郭建龙 等.十二胺修饰多壁碳纳米管[J].北京科技大学学报,2006,10(28):127-129. |
| [16] | 杨永珍,宋静静,李勇,刘旭光,许并社.1,6-己二胺对碳微球的功能化修饰[J].化工学报,2012(10):3350-3357. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%