采用固液混合方法,利用改性堇青石制备蜂窝式V2O5-WO3/Cordierite-TiO2脱硝催化剂,通过扫描电子显微镜(SEM)、热分析(DSC-TG)、X射线衍射分析仪(XRD)、模拟烟气分析装置和磨损装置,考察其表面形貌、热稳定性、晶相变化、耐磨损性能和催化剂活性.结果表明,改性堇青石的引入,制备的催化剂具有表面微气孔多和热稳定性好的特点,700℃煅烧后,V2O5和WO3的仍呈现无定形态或微晶状态;引入10%的堇青石制备的催化剂磨损率低,尤其在250~460℃反应时,脱硝率可以保持在80%以上.
参考文献
[1] | Phil HH;Reddy MP;Kumar PA;Ju LK;Hyo JS .SO2 resistant antimony promoted V2O5/TiO2 catalyst for NH3-SCR of NOx at low temperatures[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(3/4):301-308. |
[2] | Busca G .Chemical and mechanistic aspects of the selective catalytic reduction of NOx by ammonia over oxide catalysts a review[J].Applied Catalysis B:Environmental,1998,18(1-2):1-36. |
[3] | Pio Forzatti .Present status and perspectives in de-NO_x SCR catalysis[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2001(1/2):221-236. |
[4] | 李锋 .以纳米TiO<,2>为载体的燃煤烟气脱硝SCR催化剂的研究[D].东南大学,2006. |
[5] | Lietti L;Alemany J L;Forzatti P et al.Reativity of V2O5-WO3/TiO2 catalysts in the selective catalytic reduction of nitric oxide by ammonia[J].Catalysis Today,1996,29:143-148. |
[6] | 刘宣勇;钱端芬;谢建国 等.堇青石蜂窝陶瓷烧成工艺的研究[J].陶瓷工程,1999,33(03):7-11. |
[7] | 曾令可;王慧;罗民华.多孔功能陶瓷制备与应用[M].北京:化学工业出版社,2006:5. |
[8] | Xinwen Zhu;Dongliang Jiang;Shouhong Tan .Reaction bonding of open cell SiC-Al{sub}2O{sub}3 composites[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2001(11):2003-2015. |
[9] | P. M. Then;P. Day .The Catalytic Converter Ceramic Substrate - An Astonishing and Enduring Invention[J].Interceram: International Journal for Bricks, Structural Clay Products, Refractories, Pottery, Fine Ceramics, Abrasives and Special Ceramics,2000(1):20-24. |
[10] | 李兰冬,章福祥,关乃佳,冯洪庆,刘德新.金属-ZSM-5/堇青石整体式催化剂上稀燃汽车尾气的净化[J].催化学报,2006(01):41-44. |
[11] | 董国君,张杰,郝树甫.钒系脱氮催化剂载体堇青石的表面改性研究[J].工业催化,2008(05):20-23. |
[12] | 刘仁龙,吕汉清,李国云,邬旭宏,谢银银,杜军.负载型V2O5-WO3/TiO2/堇青石脱硝催化剂的研制及性能[J].武汉理工大学学报,2011(07):20-23. |
[13] | 杨眉,刘清才,薛屺,高英.化学气相沉积制备V2O5-WO3/TiO2催化剂及表征[J].功能材料,2010(04):683-686. |
[14] | 杨眉,刘清才,薛屺,王小红,高英.气相沉积制备V2O5-WO3/TiO2催化剂及其脱硝性能的研究[J].动力工程学报,2010(01):52-55,62. |
[15] | Jung S M;Grange P .Characterization and reactivity of V2O5-WO3 supported on TiO2-SO42-catalyst for the SCR reaction[J].Applied Catalysis B:Environmental,2001,32(1-2):123-131. |
[16] | Kumar V;Lee N;Almquist C B .An investigation of the thermal stability and performance of wet-incipient WO3/V2O5/TiO2 catalysts and a compatison with flame aerosol catalysts of similar composition for the gas-phase oxidation of methanol[J].Applied Catalysis B:Environmental,2006,69(1-2):101-114. |
[17] | Ingemar Odenbrand C U;Bahamonde A;Avila P et al.[J].Applied Catalysis B:Environmental,1994,5(1-2):117-131. |
[18] | Kobayashi M;Kuma R;Masaki S et al.TiO2-SiO2 and V2O5/TiO2-SiO2 catalyst:physico-chemical characteristics and catalystic behavior in selective catalytic reduction of NO by NH3[J].Applied Catalysis B:Environmental,2005,60(3-4):173-179. |
[19] | 王剑波.针对中国煤质的SCR催化剂应用[A].北京,2005 |
[20] | Alemany J;Ferlazzo N;Forzatti P et al.Oxidation of SO2 to SO3 over honeycomb DeNOxing catalysts[J].Industrial and Engineering Chemistry Research,1993,32(05):826-834. |
[21] | Alemany LJ.;Ferlazzo N.;Forzatti P.;Busca G.;Giamello E. Bregani F.;Lietti L. .REACTIVITY AND PHYSICOCHEMICAL CHARACTERISATION OF V2O5-WO3/TIO2 DE-NOX CATALYSTS[J].Journal of Catalysis,1995(1):117-130. |
[22] | Kobayashi M;Hagi M .V2O5-WO3/TiO2-SiO2-SO42- catalysts: Influence of active components and supports on activities in the selective catalytic reduction of NO by NH3 and in the oxidation of SO2[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2006(1/2):104-113. |
[23] | Svachula J;Alemany L J;Ferlazzo N et al.Oxidation of SO2 to SO3 over honeycomb DeNOxing catalysts[J].Industrial and Engineering Chemistry Research,1999,28(07):2593-2598. |
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