采用微波法成功地合成含咔唑聚膦腈接枝偶氮硝基苯,通过UV-Vis、IR、1H NMR等手段分析了产物的结构并对光电导性质进行了测试.研究表明,微波功率为400W,反应时间为6min,此时产物的产率最高为78.1％(质量分数).光电导率随着施加电场强度、光强密度和偶氮生色团含量的增加而增强.为制备新型光电材料奠定了基础.
参考文献
| [1] | Allcock H R;Jonathan P T .Phosphorylation of phosphazenes and its effects on thermal properties and rire retardant behavior[J].Polymer Engine ering and Science,2007,40:1177-1189. |
| [2] | 岳鑫,刘慧,刘景东,王文继.三聚磷腈复合硫正极材料性能的改进研究[J].功能材料,2012(12):1602-1604,1609. |
| [3] | Najun Li;Jianmei Lu;Hua Li .Nonlinear optical properties and memory effects of the azo polymers carrying different substituents[J].Dyes and Pigments,2011(1):18-24. |
| [4] | 续通,毛庆辉,毛志平.聚磷腈的研究及应用[J].化工新型材料,2010(03):22-25. |
| [5] | Dong Yanmao;Jianmei Lu;QingfengXu .Effects of substituents on the third-order nonlinear optical properties of poly(3-alkoxythiophene) derivatives[J].Synthetic Metals,2010(5/6):409-412. |
| [6] | 梁利岩,张静娴,梅群波,吕满庚.含咔唑基聚合物的合成、发光性能及应用[J].精细化工,2007(08):743-746. |
| [7] | Yang Y;Wang Y;Xie Y et al.Fused perylenebismidecarbazole:new ladder chromophores with enhanced thirdorder nonlinear optical activities[J].Chemical Communications,2011,47(38):49-51. |
| [8] | 彭强,苏丹,徐军,付官文,朱卫国.新型咔唑-吲哚并咔唑共轭聚合物材料的合成与性能研究[J].功能材料,2011(05):838-841. |
| [9] | He Tingchao;Wang Changshun;Zhang Chaozhi et al.Nonlinear optical properties of an azo-based dye irradiated by picosecond and nanosend laser pulses[J].Condensed Matter,2011,406(03):488-493. |
| [10] | 张丽,杨正,姜治伟,石军,曹少魁.含咔唑生色团的聚磷腈的合成与表征[J].功能高分子学报,2005(04):630-634. |
| [11] | Gegye R;Smith F;Westaway K et al.The use of microwave O-vens for rapid organic synthesis[J].Tetrahedron Letters,1986,27(03):279-282. |
| [12] | Wang Jing;Jiang Fengchao .Recent development of microwave induced organic reantion[J].Chinese Journal of Inorganic Chemistry,2008,22:212-215. |
| [13] | 张文龙,于亚洲,董伟,戴亚杰,王暄.CEM/NVC共聚物的合成及光导性能[J].高分子材料科学与工程,2009(12):16-19. |
| [14] | 张文龙 .偶氮硝基苯接枝PVK基光折变材料的制备与性能研究[D].哈尔滨:哈尔滨理工大学,2008. |
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