以三氯氧磷、苯酚和对苯二酚为主要原料,通过两步合成法,采用本体聚合制备了含磷阻燃剂聚苯氧基磷酸对苯二酚酯.使用红外光谱、1HNMR、13 C NMR和31P NMR确定了阻燃剂的结构.用热重分析测试了阻燃剂的热稳定性.结果表明,聚磷酸酯的结构与预期结构相符;其初始分解温度为364℃,最快分解温度为547℃,700℃时的残炭量为36%,表现出良好的热稳定性.
参考文献
[1] | Li Chen;Yu-Zhong Wang .A review on flame retardant technology in China - Part I: development of flame retardants[J].Polymers for advanced technologies,2010(1):1-26. |
[2] | Sergei V. Levchik;Edward D. Weil .A Review of Recent Progress in Phosphorus-based Flame Retardants[J].Journal of fire sciences,2006(5):345-364. |
[3] | Lu H;Song L;Hu Y .A review on flame retardant technology in China.Part Ⅰ:flame retardant polymeric nanocomposites and coatings[J].Polymers For Advanced Technologies,2011,22(04):379-394. |
[4] | 范瑞兰,云冠群,边占喜,陈树峰.几种新型高含磷含氮聚磷酰胺阻燃剂的合成与表征[J].功能材料,2011(12):2157-2161. |
[5] | 梁兵,曹俊,王长松.新型含磷阻燃剂BPAODOPE的合成与表征[J].功能材料,2011(z3):474-476. |
[6] | Annakutty K S;Kishore K .A novel-approach to structure flammability correlation in polyphosphate esters[J].Polymer,1988,29(07):1273-1276. |
[7] | Kishore K;Kannan P;Iyanar K .Synthesis,characterization,and fire retardancy of ferrocene containing polyphosphate esters[J].Journal of Polymer Science Part A:Polymer Chemistry,1991,29(07):1039-1044. |
[8] | 王筱梅,杨平,冯倩,欧育湘,张书香.芳香族聚磷酸酯的聚合度与阻燃性质的研究[J].高分子材料科学与工程,1999(04):81-83. |
[9] | 汪朝阳,赵耀明.聚磷酸酯阻燃剂研究进展[J].塑料,2003(03):1-5,8. |
[10] | Sundarrajan S;Kishore K;Ganesh K .A new polymeric flame retardant additive for vinyl polymers[J].Indian Journal of Chemistry Section a-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry,2001,40(01):41-45. |
[11] | Kannan P.;Kishore K.;Umamaheshwari N. .SYNTHESIS AND CHARACTERIZATION OF NEW FLAME-RETARDANT POLYARYL PHOSPHORAMIDE ESTERS CONTAINING FURAN AND THIOPHENE UNITS[J].Journal of Applied Polymer Science,1995(1):113-118. |
[12] | 方科益,李娟,柯晨皓,朱琦良,陶慷,严庆,王玉忠.超支化聚磷酸酯阻燃剂对尼龙6的成炭促进作用[J].高分子学报,2011(01):55-62. |
[13] | Markley F X;Worrel C J .Phenyl Phosphorodichloridates[P].US:3153081,1964. |
[14] | Krevelen D W V.Properties of polymers[M].Holland:Elsevter Science,1990 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%