以透明导电玻璃ITO和铜片为工作电极,用0.1mol/L乙酸铜和0.02mol/L乙酸钠的混合溶液作为电解液,通过两电极电化学沉积方法制备了Cu2O薄膜.讨论了pH值和沉积电位对Cu2O薄膜的影响,利用X射线衍射仪(XRD)、场发射扫描电子显微镜(SEM)、X射线光电子能谱(XPS)对薄膜进行表征.结果表明,两电极电化学沉积法制备Cu2O薄膜最佳的pH值为5.7～5.9,沉积电位为1.1～1.3V.此外,分析了沉积电位对Cu2O薄膜形貌的影响.
参考文献
| [1] | Formation and characterization of the Cu_2O overlayer on Zn-terminated ZnO(0001)[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,2009(13):2163-2170. |
| [2] | Papadimitropoulos G;Vourdas N;Vamvakas V E et al.Deposition and characterization of copper oxide thin films[J].Journal of Physics:Conference Series,2005,10:182-185. |
| [3] | Keevers MJ.;Green MA. .EXTENDED INFRARED RESPONSE OF SILICON SOLAR CELLS AND THE IMPURITY PHOTOVOLTAIC EFFECT[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1996(0):195-204. |
| [4] | 王华,何为,刘忠祥,王守绪.电解液组成对电沉积制备氧化亚铜晶体生长机理的研究[C].第六届中国功能材料及其应用学术会议论文集,2007:4040-4043. |
| [5] | Mittiga A;Salza E;Sarto F et al.Electrodeposited ZnO/Cu2O heterojunction solar cells[J].Applied Physics Letters,2008,53(05):2226-2231. |
| [6] | 顾修全,王波,陈凡,张家正,王明月.氧化亚铜在太阳能电池、光催化领域的研究进展[J].现代化工,2012(02):19-23. |
| [7] | A. Sivasankar Reddy;G. Venkata Rao;S. Uthanna;P. Sreedhara Reddy .Structural and optical studies on dc reactive magnetron sputtered Cu_2O films[J].Materials Letters,2006(13/14):1617-1621. |
| [8] | Jin-Yi Chen;Pei-Jiang Zhou;Jia-Lin Li .Depositing Cu2O of different morphology on chitosan nanoparticles by an electrochemical method[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2007(4):623-629. |
| [9] | Xu HL;Wang WZ;Zhu W .Shape evolution and size-controllable synthesis of Cu2O octahedra and their morphology-dependent photocatalytic properties[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(28):13829-13834. |
| [10] | Fang Luo;Di Wu;Lei Gao;Suoyuan Lian;Enbo Wang;Zhenhui Kang;Yang Lan;Lin Xu .Shape-controlled synthesis of Cu_2O nanocrystals assisted by Triton X-100[J].Journal of Crystal Growth,2005(4):534-540. |
| [11] | Li M;Wu W B;Liu K F et al.Three-dimensional assembly and electrical properties of Cu2O/ZnO heterojunction via an electrochemical superfiling method[J].Electrochimica Acta,2012,71:100-105. |
| [12] | Weichman F L;Reyes J M .Optical absorption of Cu2O in the near infrared and the role of metallic inclusions[J].Canadia Journal of Physics,1980,58(03):325-333. |
| [13] | 胡飞,江毅,梁建.p型Cu2O 半导体薄膜的电化学沉积研究[J].人工晶体学报,2009(04):952-956. |
| [14] | 陈志钢,唐一文,贾志杰,张丽莎,李家麟,余颖.导电玻片上氧化亚铜膜的电沉积和表征[J].无机材料学报,2005(02):367-372. |
| [15] | Y. Tang;Z. Chen;Z. Jia .Electrodeposition and characterization of nanocrystalline cuprous oxide thin films on TiO_2 films[J].Materials Letters,2005(4):434-438. |
| [16] | Xia, Y.;Liu, B.;Zhong, S.;Li, C. .X-ray photoelectron spectroscopic studies of black silicon for solar cell[J].Journal of Electron Spectroscopy and Related Phenomena,2012(11/12):589-592. |
| [17] | 孙芳 .电沉积氧化亚铜薄膜及其性能研究[D].长春:吉林大学,2008. |
| [18] | Lijuan Wan;Zhiqiang Wang;Zaisan Yang;Wenjun Luo;Zhaosheng Li;Zhigang Zou .Modulation of dendrite growth of cuprous oxide by electrodeposition[J].Journal of Crystal Growth,2010(21):3085-3090. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%