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通过利用光学显微镜对ZTS晶体(100)面的台阶推移过程进行实时观察,对不同溶液供应速度及不同过饱和度下的台阶生长动力学进行了研究.结果表明,随着溶液供应速度S的增大,台阶平均推移速率先增大后减小.溶液供应速度S≈1.2rnL/min时,台阶平均推移速率达到最大.而在静止的生长溶液中,台阶平均推移速率随着过饱和度σ的增大呈非线性增大,同时确定了生长死区σd和台阶平均推移速率急剧增大时的临界过饱和度值σ*,并计算了不同过饱和度阶段的台阶动力学系数和台阶活化能.

参考文献

[1] Ushasree P M;Jayavel R;Subramanian C et al.Growth of zinc thiourea sulfate(ZTS) single crystals:a potential semiorganic NLO material[J].Journal of Crystal Growth,1999,197:216-220.
[2] Ushasree P M;Jayavel R;Ramasamy P .Influence of pH on the characteristics of zinc tris (thiourea) sulfate (ZTS) single crystals[J].Materials Chemistry and Physics,1999,61:270-274.
[3] Meenakshisundaram S;Parthiban S;Sarathi N;Kalavathy R;Bhagavannarayana G .Effect of organic dopants on ZTS single crystals[J].Journal of Crystal Growth,2006(2):376-381.
[4] Sweta Moitra;Tanusree Kar .Growth and characterization of nonlinear optical crystal zinc tris (thiourea) sulphate in presence of L-arginine[J].Optical materials,2007(3):508-512.
[5] N.R. Dhumane;S.S. Hussaini;V.G. Dongre;Mahendra D. Shirsat .Influence Of Glycine On The Nonlinear Optical (nlo) Properties Of Zinc (tris) Thiourea Sulfate (zts) Single Crystal[J].Optical materials,2008(2):328-332.
[6] C. Krishnan;P. Selvarajan;T.H. Freeda .Growth And Studies Of Pure And Potassium Iodide-doped Zinc Tris-thiourea Sulphate (zts) Single Crystals[J].Journal of Crystal Growth,2008(1):141-146.
[7] C. Krishnan;P. Selvarajan;S. Pari .Synthesis, growth and studies of undoped and sodium chloride-doped Zinc Tris-thiourea Sulphate (ZTS) single crystals[J].Current applied physics: the official journal of the Korean Physical Society,2010(2):664-669.
[8] Meenakshisundaram, S.P.;Parthiban, S.;Kalavathy, R.;Madhurambal, G.;Bhagavannarayana, G.;Mojumdar, S.C. .Thermal and optical properties of ZTS single crystals in the presence of 1,10-phenanthroline (Phen): Crystalline perfection studies[J].Journal of thermal analysis and calorimetry,2010(3):831-837.
[9] 石航,李明伟,程旻,潘翠连,吴伟军.硫脲硫酸锌晶体(100)面台阶生长动力学实时研究[J].功能材料,2011(12):2141-2145.
[10] 潘翠连,李明伟,程旻,王永宝,邱言锋.L-丙氨酸掺杂下ZTS晶体(100)面台阶动力学实时研究[J].人工晶体学报,2012(03):588-593,598.
[11] 王永宝,李明伟,程旻,潘翠连,宋洁.L-精氨酸掺杂下ZTS溶液的稳定性研究[J].人工晶体学报,2011(06):1460-1466.
[12] 傅肃嘉 .解释温度对固体溶解度影响应注意的问题[J].大学化学,1986,3:29-32.
[13] Schwoebel R L;Shipsey E J .Step motion on crystal surfaces[J].Journal of Applied Physics,1966,37(10):3682-3686.
[14] 王晓丁,李明伟,曹亚超,刘玉姗.KDP晶体生长的溶液流动和物质输运计算[J].人工晶体学报,2010(01):88-94.
[15] Cabrera N;Vermilyea D A.Growth and perfection of crystals[M].New York:wiley,1958:393-410.
[16] Sangwal K.;Wojcik K.;Borc J. .In situ study of the kinetics of displacement of growth steps on {010} faces of potassium acid phthalate single crystals grown from aqueous solutions[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,2003(7/8):684-696.
[17] Rashkovich LN.;Kronsky NV. .INFLUENCE OF FE3+ AND AL3+ IONS ON THE KINETICS OF STEPS ON THE (1 0 0) FACES OF KDP[J].Journal of Crystal Growth,1997(3/4):434-441.
[18] 宋洁;李明伟;程旻.ZTS晶体(100)面相变界面微观形貌的实时AFM研究[M].武汉:中国工程热物理学会,2011
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