负极材料是目前制约水系锂离子电池的关键因素。钒酸盐材料因为较高的比容量和合适的脱嵌锂电位被广泛用于水系锂离子电池的负极。结合研究结果,对钒酸盐材料在水系锂离子电池领域的研究现状进行了综述,重点对相关材料的晶体结构、电化学性能和容量衰减机制进行了分析,提出了进一步改善水系锂离子电池电化学性能的措施。
Anode materials have become the key factor restricting the development of aqueous lithium-ion battery (ALIB).Due to their high specific capacities and suitable lithium insertion/extraction potentials,vanadate ma-terials have been widely utilized as anode materials for ALIB.This paper reviewed the current research progress of ALIB on the basis of research results in our group and the emphasis was placed on their crystal structure, charge-discharge mechanism, synthesis methods and electrochemical properties. Meanwhile, improvement measures were put forward to further better the electrochemical properties of vanadate materials in ALIB.
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