层状锰基氧化物 Li [Lix (MnM)1-x ]O 2(M=Ni,Co,Cr…)正极材料具有比容量高的优点,引起了研究者的广泛关注。结合课题组的研究工作,综述了这一领域的最新研究进展。重点对层状锰基氧化物正极材料的结构、电化学性能,特别是对其独特充放电机制和电化学性能的改善进行了总结和探讨。最后总结了高容量层状锰基氧化物正极材料目前存在的主要问题以及未来的研究重点。
Layered Mn-based oxides Li[Lix (MnM)1-x ]O2 (M=Ni,Co,Cr……)have attracted much attention due to their high reversible capacity.In the paper,we review the latest development in these areas,both from our group and others.The structure,synthesis methods and electrochemical properties of Li[Lix (MnM)1-x ]O2 are summarized.Especially,the charge/discharge mechanism and improvement to their electrochemical proper-ties are focused here.At last,the major problems in layered Mn-based oxides was discussed.
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