通过调节电解质溶液的 pH 值,研究了 pH值对氧化钛纳米管阵列形貌的影响,研究表明水质电解液pH 值控制在3~5时,氧化钛纳米管阵列的形貌更加规则。通过瞬态电流变化、短路电流-开路电压、电化学阻抗谱分析了在 pH 值=4的电解液中制备的氧化钛纳米管阵列的光电性能及电化学性能。研究表明经热处理的锐态型氧化钛纳米管阵列具有较好的光敏特征和光电转换性能,并表现出明显的高频阻低频电容电化学特性。
In this paper,the effect of the electrolyte’s pH value on the microcosmic images of the titania nano-tube arrays was studied.The results indicate that titania nanotube arrays with more regular tube array structure usually formed in electrolyte with pH value 3-5.Current-voltage (I-V),transient photocurrents (I-t)and elec-trochemical impedance spectroscopy (EIS)were measured to test the photoelectronic and the electrochemistry performance of TiO2 nanotube arrays.The results indicate that the titania nanotube arryas has good photoelec-tronic and electrochemistry performance after heat-treated,and appears obvious electrochemistry character with high frequency resistance and low frequency capacitance.
参考文献
[1] | Gong D;Grimes C A;Varghese O K et al.Titanium oxide nanotube arrays prepared by anodic oxidation[J].Journal of Materials Research,2001,16(12):3331-3334. |
[2] | R. Beranek;H. Hildebrand;P. Schmuki .Self-Organized Porous Titanium Oxide Prepared in H_2SO_4/HF Electrolytes[J].Electrochemical and solid-state letters,2003(3):B12-B14. |
[3] | Mor GK;Shankar K;Paulose M;Varghese OK;Grimes CA .Enhanced photocleavage of water using titania nanotube arrays[J].Nano letters,2005(1):191-195. |
[4] | Qingyun Cai;Maggie Paulose;Oomman K. Varghese .The effect of electrolyte composition on the fabrication of self-organized titanium oxide nanotube arrays by anodic oxidation[J].Journal of Materials Research,2005(1):230-236. |
[5] | Tian T;Xiao XF;Liu RF;She HD;Hu XF .Study on titania nanotube arrays prepared by titanium anodization in NH4F/H2SO4 solution[J].Journal of Materials Science,2007(14):5539-5543. |
[6] | 高乾,王树林,蹇敦亮,王海锋.不同制备条件对二氧化钛纳米管阵列及其结构的影响[J].功能材料,2011(03):395-398. |
[7] | Mor GK;Shankar K;Varghese OK;Grimes CA .Photoelectrochemical properties of titania nanotubes[J].Journal of Materials Research,2004(10):2989-2996. |
[8] | Beranek R;Tsuchiya H;Sugishima T;Macak JM;Taveira L;Fujimoto S;Kisch H;Schmuki P .Enhancement and limits of the photoelectrochemical response from anodic TiO2 nanotubes[J].Applied physics letters,2005(24):43114-1-43114-3-0. |
[9] | Ghicov A;Macak JM;Tsuchiya H;Kunze J;Haeublein V;Frey L;Schmuki P .Ion implantation and annealing for an efficient N-doping of TiO2 nanotubes[J].Nano letters,2006(5):1080-1082. |
[10] | Quan X;Yang SG;Ruan XL;Zhao HM .Preparation of titania nanotubes and their environmental applications as electrode[J].Environmental Science & Technology: ES&T,2005(10):3770-3775. |
[11] | Oomman K. Varghese;Dawei Gong;Maggie Paulose;Keat G. Ong;Craig A. Grimes .Hydrogen sensing using titania nanotubes[J].Sensors and Actuators, B. Chemical,2003(1/3):338-344. |
[12] | Gopal K. Mor;Maria A. Carvalho;Ooman K. Varghese .A room-temperature TiO_2-nanotube hydrogen sensor able to self-clean photoactively from environmental contamination[J].Journal of Materials Research,2004(2):628-634. |
[13] | Mor GK;Varghese OK;Paulose M;Ong KG;Grimes CA .Fabrication of hydrogen sensors with transparent titanium oxide nanotube-array thin films as sensing elements[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1):42-48. |
[14] | Macak JM;Barczuk PJ;Tsuchiya H;Nowakowska MZ;Ghicov A;Chojak M;Bauer S;Virtanen S;Kulesza PJ;Schmuki P .Self-organized nanotubular TiO2 matrix as support for dispersed Pt/Ru nanoparticles: Enhancement of the electrocatalytic oxidation of methanol[J].Electrochemistry communications,2005(12):1417-1422. |
[15] | Chen S;Paulose M;Ruan C et al.Electrochemically synthesized CdS nanoparticle-modified TiO2 nanotube-array photoelectrodes:preparation,characterization,and application to photoelectrochemical cells[J].J Pho-tochem Photobiol A:Chem,2006,177(2-3):177-184. |
[16] | Macak JM;Tsuchiya H;Ghicov A;Schmuki P .Dye-sensitized anodic TiO2 nanotubes[J].Electrochemistry communications,2005(11):1133-1137. |
[17] | Balaur E;Macak JM;Taveira L;Schmuki P .Tailoring the wettability of TiO2 nanotube layers[J].Electrochemistry communications,2005(10):1066-1070. |
[18] | Eugeniu Balaur;Jan M.Macak;Hiroaki Tsuchiya;Patrik Schmuki .Wetting behaviour of layers of TiO_2 nanotubes with different diameters[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(42):4488-4491. |
[19] | Tsuchiya H;Macak JM;Muller L;Kunze J;Muller F;Greil P;Virtanen S;Schmuki P .Hydroxyapatite growth on anodic TiO2 nanotubes.[J].Journal of biomedical materials research, Part A,2006(3):534-541. |
[20] | Macak JM;Tsuchiya H;Taveira L;Ghicov A;Schmuki P .Self-organized nanotubular oxide layers on Ti-6Al-7Nb and Ti-6Al-4V formed by anodization in NH4F solutions.[J].Journal of biomedical materials research, Part A,2005(4):928-933. |
[21] | Prida V M;Hernandez-Velez M;Cervera M et al.Magnetic behaviour of arrays of Ni nanowires by electro-deposition into self-aligned titania nanotubes[J].Journal of Magnetism and Magnetic Materials,2005,294(02):e69-e72. |
[22] | Oh SH;Finones RR;Daraio C;Chen LH;Jin SH .Growth of nano-scale hydroxyapatite using chemically treated titanium oxide nanotubes[J].Biomaterials,2005(24):4938-4943. |
[23] | 金路,高振威,怀静,张雪,郭文瑞,周露,陈君红,袁志文,汤宇航,栾敬帅,范海波,马杰.TiO2纳米管阵列的制备工艺对其光催化性能的影响[J].功能材料,2012(20):2872-2875. |
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