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以香豆素为母体设计合成了一个新型荧光淬灭香豆素类衍生物探针,并研究了其识别能力和结合方式等.研究发现,该探针对 Cu2+具有很高选择性、灵敏性,以及较高的荧光淬灭率(达95.2%).并且当Cu2+浓度在3×10-6~1.5×10-5 mol/L范围内,该探针的荧光强度和离子浓度具有较好的线性关系.

A novel coumarin-based fluorescence quenching probe has been designed and synthesized.After stud-ying its recognition capability and bonding mode,we discovered that the probe could high selectively and sensi-tively detect Cu2+ in solution as well as having a high fluorescence quenches rate which was up to 9 5 .2%.Addi-tionally,there was a good linearity between the fluorescence intensity of the probe and the concentration of cop-per ion,when the concentration of Cu2+ was in the range of 3-1 5μmol/L.

参考文献

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