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微生物水泥是在节能减排大环境下而研发的一种新型生物水泥.利用 X 射线衍射(XRD)、透射电镜(TEM)和红外光谱(IR)分别对微生物水泥基材料的成分、形貌、微观结构进行了研究.TEM分析表明,微生物水泥基材料内部微观结构与化学法浇注的砂颗粒内部微观结构不同.微生物矿化形成的方解石可以胶结松散颗粒,而化学法形成的方解石与松散颗粒之间存在孔隙,不能胶结松散颗粒;IR 分析表明,微生物水泥基材料中的Si-O 键和C-O 键频率均发生红移,而化学法浇注的砂颗粒中 Si-O 键和 C-O 键频率未发生改变,另外,化学法浇注的砂颗粒中 Si-O键与单纯石英砂中的Si-O 键频率相同.

Microbe cement was a new kind of biological cement due to the ever increasing awareness of environ-mental protection.The composition, morphology and microstructure were researched by X-ray diffraction (XRD),transmission electron microscope (TEM)and infra-red spectra (IR).TEM results showed that the mi-crostructure of microbe cementitious materials was different with that by chemical methods.The calcite pro-duced by microbial could bind loose particles and that produced by chemical methods could not bind particles.IR results indicated that the frequency of Si-O and C-O took up the extent of the red shifts.However,the fre-quency of Si-O and C-O could not change.Moreover,the frequency of Si-O at quartz sand by chemical method and at pure quartz sand was the same.

参考文献

[1] 荣辉,钱春香.微生物水泥基材料特征[J].科学通报,2012(09):770-775.
[2] Qian C X;Pan Q F;Wang R X .Cementation of sand grains based on carbonate precipitation induced by micro-organism[J].Science China Technological Sciences,2010,53:2198-2206.
[3] Le Metayer-Levrel G;Castanier S;Orial G et al.Appli-cations of bacterial carbonatogenesis to the protection and regeneration of limestones in buildings and historic patri-mony[J].Sedimentary Geology,1999,126:25-34.
[4] Nemati M;Voordouw G .Modification of porous media permeability, using calcium carbonate produced enzymatically in situ[J].Enzyme and Microbial Technology,2003(5):635-642.
[5] DeJong JT;Fritzges MB;Nusslein K .Microbially induced cementation to control sand response to undrained shear[J].Journal of geotechnical and geoenvironmental engineering,2006(11):1381-1392.
[6] Jason T.DeJong;Brina M.Mortensen;Brian C.Martinez .Bio-mediated soil improvement[J].Ecological engineering: The Journal of Ecotechnology,2010(2):197-210.
[7] Whiffin V S .Microbial CaCO3 precipitation for the pro-duction of biocement[D].Western Australia:Murdoch University,2004.
[8] Whiffin V S;Van Paassen L A;Harkes M P .Microbial carbonate precipitation as a soil improvement technique[J].Geomicrobiology Journal,2007,24:417-423.
[9] Volodymyr Ivanov;Jian Chu .Applications of microorganisms to geotechnical engineering for bioclogging and biocementation of soil in situ[J].Reviews in Environmntal Science and Biotechnology,2008(2):139-153.
[10] Ferriis F G;Setehmeir L G .Bacteriogenic mineral plug-ging[P].US Patent:5143155,1992-9-1.
[11] M. Nemati;E.A. Greene;G. Voordouw .Permeability profile modification using bacterially formed calcium carbonate: comparison with enzymic option[J].Process biochemistry,2005(2):925-933.
[12] Willem De Muynck;Nele De Belie;Willy Verstraete .Microbial carbonate precipitation in construction materials: A review[J].Ecological engineering: The Journal of Ecotechnology,2010(2):118-136.
[13] Willem De Muynck;Kim Verbeken;Nele De Belie .Influence of urea and calcium dosage on the effectiveness of bacterially induced carbonate precipitation on limestone[J].Ecological engineering: The Journal of Ecotechnology,2010(2):99-111.
[14] Willem De Muynck;Dieter Debrouwer;Nele De Belie .Bacterial carbonate precipitation improves the durability of cementitious materials[J].Cement and Concrete Research,2008(7):1005-1014.
[15] Qian Chunxiang;Wang Jianyun;Wang Ruixing;Cheng Liang .Corrosion protection of cement-based building materials by surface deposition of CaCO_3 by Bacillus pasteurii[J].Materials science & engineering. C, Biomimetic materials, sensors and systems,2009(4):1273-1280.
[16] Santhosh K.Ramachandran;V.Ramakrishnan;Sookie S.Bang .Remediation of concrete using micro-organisms[J].ACI materials journal,2001(1):3-9.
[17] Ferris F G;Phoenix V;Fujita Y et al.Kinetics of cal-cite precipitation induced by ureolytic bacteria at 10 to 20℃ in artificial groundwater[J].Geochimica et Cosmo-chimica Acta,2003,67:1701-1722.
[18] Fujita Y;Ferris F G;Lawson R D et al.Calcium car-bonate precipitation by ureolytic subsurface bacteria[J].Geomicrobiology Journal,2000,17:305-318.
[19] Warren L A;Maurice P A;Parmar N et al.Microbially mediated calcium carbonate precipitation:Implications for interpreting calcite precipitation and for solid-phase capture of inorganic contaminants[J].Geomicrobiology Journal,2001,18:93-115.
[20] Sonal Chaturvedi;Ram Chandra;Vibhuti Rai .Isolation and characterization of Phragmites australis(L.)rhizosphere bacteria from contaminated site for bioremediation of colored distillery effluent[J].Ecological engineering: The Journal of Ecotechnology,2006(3):202-207.
[21] MarkA.Simon;James S.Bonner;Cheryl A.Page;R.Todd Townsend;Danica C.Mueller;Chris B.Fuller;Robin L.Autenrieth .Evaluation of two commercial bioaugmentation products for enhanced removal of petroleum from a wetland[J].Ecological engineering: The Journal of Ecotechnology,2004(4/5):263-277.
[22] 王瑞兴,钱春香,吴淼,成亮.微生物矿化固结土壤中重金属研究[J].功能材料,2007(09):1523-1526,1530.
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