欢迎登录材料期刊网

材料期刊网

高级检索

采用溶胶-凝胶法对 TiO2进行 Ce 及 Zn 单一和共掺杂改性.以金葡萄球菌、大肠杆菌和白念珠菌为菌种,研究组分对材料的可见光抗菌活性影响.运用X射线衍射(XRD)、透射电子显微镜(TEM)、比表面仪(BET)、傅里叶变换红外光谱(FT-IR)和紫外-可见漫反射光谱(UV-Vis-DRS)等测试手段对样品的结构进行表征.实验结果表明,掺杂改性抗菌剂中适量Ce组分的作用,在于通过抑制抗菌剂的晶粒长大和拓展光响应范围等方面,增进抗菌剂的光催化性能.掺杂抗菌剂中适量 Zn 组分的作用在于提高材料的光催化抗菌性能.Zn、Ce 共掺杂 TiO2纳米材料表现出良好的协同抗菌效果,协同效应因子(SEF)>0.

Ce and/or Zn doped TiO2 nano-materials were prepared by sol-gel.The antibacterial activity of the as-prepared materials under visible light irradiation was evaluated on candida albicans,escherichia coli and staphy-lococcus.X-ray diffraction (XRD),transmission electron microscopy (TEM),brunauer-emmett-teller surface area (BET)analysis,Fourier transform infrared spectroscopy (FT-IR)and UV-Vis diffuse reflectance spectra (DRS)methods were employed to characterize the as-prepared materials.It has been shown that the role of proper amount of Ce in doped materials played as to inhibit grain growth and extend the light response to the visible region have a favorable effect on the photocatalysis.The role of proper amount of Zn in doped materials played as to enhance the photocatalytic antibacterial activity of as-prepared materials.Zinc and cerium co-doped TiO2 nano-materials exhibit significant synergistic antibacterial effect and the synergistic effect factor was grea-ter than 0 .

参考文献

[1] Xiangxin Xue;Yuzheng Wang;He Yang .Preparation and characterization of boron-doped titania nano-materials with antibacterial activity[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013(Jan.1):94-99.
[2] 王昱征,薛向欣,杨合.锌铈共掺杂二氧化钛纳米材料制备与表征及其抗菌性能的研究[J].无机材料学报,2013(01):117-122.
[3] Mai Lixiang;Wang Dawei;Zhang Sheng et al.Synthesis and bactericidal ability of Ag/TiO2 composite films de-posited on titanium plare[J].Applied Surface Science,2010,257(03):974-978.
[4] Li RX.;Yabe S.;Yamashita M.;Momose S.;Yoshida S.;Yin S.;Sato T. .UV-shielding properties of zinc oxide-doped ceria fine powders derived via soft solution chemical routes[J].Materials Chemistry and Physics,2002(1/3):39-44.
[5] Hu,H.;Zhang,W.;Qiao,Y.;Jiang,X.;Liu,X.;Ding,C. .Antibacterial activity and increased bone marrow stem cell functions of Zn-incorporated TiO 2 coatings on titanium[J].Acta biomaterialia,2012(2):904-915.
[6] H. Qizhuang;Y. Jing;Min Hui .Studies on the spectra and antibacterial properties of rare earth dinuclear complexes with L-phenylalanine o-phenanthroline[J].Materials Letters,2006(3):317-320.
[7] 孙丰波,余雁,江泽慧,任海青,王戈,刘杏娥.竹材的纳米TiO_2改性及抗菌防霉性能研究[J].光谱学与光谱分析,2010(04):1056-1060.
[8] 叶勤,吴奎,阮广富.反应溅射掺碳二氧化钛(TiO2-xCx)薄膜可见光激发的亲水性和光催化特性研究[J].功能材料,2006(10):1572-1574.
[9] 周文芳,朱忠其,张瑾,赵宗彦,柳清菊.微波化学法合成可见光响应氮掺杂纳米TiO2光催化剂[J].功能材料,2009(02):212-215.
[10] 周武艺,曹庆云,唐绍裘,刘英菊.硫掺杂纳米TiO2的掺杂机理及可见光催化活性的研究[J].无机材料学报,2006(04):776-782.
[11] 颜欣,刘中清,李丹丹,李纲.铜掺杂TiO2纳米管阵列的制备与光催化还原性能[J].功能材料,2010(07):1278-1281.
[12] 柳清菊,吴兴惠,刘强,何愿华.TiO2/Fe2O3复合光催化超亲水性薄膜的研究[J].功能材料,2003(02):224-225,228.
[13] 黄东升,陈朝凤,李玉花,曾人杰.铁、氮共掺杂二氧化钛粉末的制备及光催化活性[J].无机化学学报,2007(04):738-742.
[14] 薛向欣,王辉,杨合,李述贤.热处理时间对钒掺杂钛高炉渣材料性能的影响[J].东北大学学报(自然科学版),2010(01):84-87.
[15] 吴俊明,王亚平,杨汉培,范以宁,许波连.Ce及N共掺杂改性TiO_2光催化性能及Ce组分的作用[J].无机化学学报,2010(02):203-210.
[16] Weishuang Ni;Songping Wu;Qun Ren.Silanized TiO2 nanoparticles and their application in toner as charge control agents: Preparation and characterization[J].Chemical engineering journal,2013:272-277.
[17] Tijing L D;Ruelo M T;Amarjargal A et al.Antibacteri-al and auperhydrophilic electrospun polyurethane nano-composite fibers containing tourmaline nanoparticles[J].Chemical Engineering Journal,2012,197(15):41-48.
[18] 田泽,郑焘,朱平武,苏碧桃,雷自强.太阳光活性的ZnTiO3/TiO2纳米复合催化材料的制备及其表征[J].无机化学学报,2012(02):269-274.
[19] 雷雪飞,薛向欣.Cr(Ⅵ)-乙酸复合体系中硫酸盐掺杂的含钛高炉渣光催化还原Cr(Ⅵ)[J].过程工程学报,2008(05):901-907.
[20] 闫加磊,孙妍,石亮,周宜君,陈慧英.羧甲基壳聚糖/Ce^3+掺杂TiO2复合抗菌材料的研究[J].功能材料,2011(11):2060-2063.
[21] YANG Yunhua,DAI Guangjian,TAN Shaozao,LIU Yingliang,SHI Qingshan,OUYANG Yousheng.Structure and synergetic antibacterial effect of zinc and cerium carried sodium zirconium phosphates[J].稀土学报(英文版),2011(04):308-312.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%