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采用光诱导液相沉积(LIP)的方法制备了Ni、Cu 薄膜,并进一步讨论了沉积温度等相关因素对薄膜成分与形貌的影响.采用 X 射线衍射仪(XRD)和扫描电子显微镜(SEM)、四探针测试仪等分别对薄膜的成分、形貌、电阻率、非均匀性等进行表征.结果显示,制备的 Cu 膜电阻率为1.87×10-8Ω??m,非均匀性为2.64%.此外,将制备的 Ni/Cu 工艺应用于制备晶硅电池的栅线电极,用 I-V 测试仪测试电池参数,填充因子高达77.8%.

Nickel films and copper films were fabricated by the method of light-induced plating (LIP),and the influence of some technological factors (deposition temperature,deposition time ect.)on films were studied.To characterize the composition,morphology,resistivity and ununiformity of the films,X-ray diffraction (XRD), scanning electron microscopy (SEM)and four-probe tester were used.The results indicated that the copper film’s resistivity was 1.87×10 -8 Ω??m and the ununiformity was 2.64%.What’s more,in this paper,Ni/Cu films deposition technique was also introduced in developing the crystalline silicon solar cell.Then the electrical parameters of solar cell were investigated by measuring light I-V solar cell measurements,and FF was 77.8%.

参考文献

[1] Mette A;Schetter C;Wissen D.Increasing the effi-ciency of screen-printed silicon solar cells by light-induced silver plating[A].USA,2006:1056-1059.
[2] Hyung Lee, J.;Hyun Lee, Y.;Yong Ahn, J.;Jeong, J.-W. .Analysis of series resistance of crystalline silicon solar cell with two-layer front metallization based on light-induced plating[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2011(1):22-25.
[3] Bartsch J;Radtke V;Savio C.Progress in under-standing the current paths and deposition mechanisms of light-induced plating and implications for the process[A].Hamburg,2009:1469-1474.
[4] 周春兰,刘维,王文静,李海玲,赵雷,刁宏伟.应用于太阳电池的单晶硅上化学镀镍工艺[J].太阳能学报,2010(05):625-629.
[5] Paunovic M .Electrochemical aspects of electroless deposi-tion of metals[J].Plating,1968,55(11):1161.
[6] Bartsch J;Radtke V;Schetter C et al.Electrochemical methods to analyse the light-induced plating process[J].Journal of Applied Electrochemistry,2010,40(4):757-765.
[7] Mustapha Boubatra;Amor Azizi;Guy Schmerber .The influence of pH electrolyte on the electrochemical deposition and properties of nickel thin films[J].Ionics,2012(4):425-432.
[8] 张国庆;刘冰;姚素薇 等.在半导体硅上电沉积及激光诱导电沉积镍薄膜[J].天津大学学报,1998,31(1):29-34.
[9] Schmid P E;Ho P S;F?ll H et al.Effects of variations of silicide characteristics on the Schottky-barrier height of silicide-silicon interfaces[J].Physical Review B,1983,28(8):4593.
[10] John P K;Rastogi A C;Tong B Y et al.Phase trans-formations at a nickel-silicon interface under transient annealing[J].Canadian Journal of Physics,1987,65(8):1037-1043.
[11] Bandopadhyay S;Gangopadhyay U;Mukhopadhyay K et al.Nickel silicide contact for silicon solar cells[J].Bulletin of Materials Science,1992,15(5):473-479.
[12] 马春雨,张庆瑜.沉积温度对ZrO2薄膜结构及表面形貌的影响[J].真空科学与技术学报,2006(z1):119-123.
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