采用扫描电子显微镜、X 射线衍射仪、透射电子显微镜、小角X射线散射仪对国产的两种高强中模型碳纤维与日本东丽 T800 H 碳纤维的结构进行表征,比较了它们的表面形貌、断面形貌、石墨微晶结构和微孔结构。结果表明,国产的高强中模型碳纤维的表面形貌优于日本 T800H,但在断面形貌、石墨微晶结构和微孔结构等微观结构上仍有一定差距,需从工艺上进行改进。
The micro-structure of three kinds of high-strength and middle-modulus carbon fiber including two homemade carbon fibers and Toray carbon fibers T800 H were characterized by using scanning electron microscope,X-ray diffrac-tometer,transmission electron microscope and small angle X-ray scattering system.Their surface structure,fracture morphology,graphic micro-crystal structure and micro-pore size were compared.The results indicated that the surface structure of two homemade carbon fibers was better than T800 H.But other micro-structure of the homemade high-strength and middle-modulus carbon fibers had some differences with the Toray carbon fiber.The preparation technolo-gy of the homemade carbon fiber need further improvement.
参考文献
[1] | S. CHAND .Review Carbon fibers for composites[J].Journal of Materials Science,2000(6):1303-1313. |
[2] | Kobets L P;Deev I S .Carbon fibers:structure and me-chanical properties[J].Composites Science and Technolo-gy,1998,57(12):1571-1580. |
[3] | Lu Changchun.Increasing productivity of international carbon fiber and its market situation[J].China Textile Leader,2009(03):44-47. |
[4] | Feng Zhihai.Some ideas on requirement and development of China carbon fiber[J].Advanced Materials Industry,2010(09):19-24. |
[5] | He Fu.Be necessary to prepare high property carbon fiber[J].Hi-tech Fiber & Application,2010(02):14-18. |
[6] | 刘福杰,范立东,王浩静,朱珍平.高强度炭纤维微观结构分析及力学性能的比较[J].功能材料,2007(10):1723-1726,1730. |
[7] | He Fu .PAN fiber of high property carbon fiber and dry-jet wet-spinning method[J].Hi-tech Fiber &Application,2004,29(04):6-12. |
[8] | Johnson D J .Structure-property relationships in carbon fibers[J].Journal of Physics D:Applied Physics,1987,20(03):286-291. |
[9] | Dobb M G;Johnson D J;Park C R et al.Compressional behavior of carbon fiber[J].Carbon Techniques,1992,3:17-22. |
[10] | Dobb M G;Guo H;Johnson D J et al.Structure-com-pressional property relations in carbon fibers[J].Car-bon,1995,33(11):1553-1559. |
[11] | 蒋刚,龚伟.装备中碳纤维复合材料湿热老化的SVM研究方法[J].四川兵工学报,2011(01):1-4. |
[12] | He Fu.Carbon fiber and its application technology[M].北京:化学工业出版社,2004 |
[13] | He Fu.Carbon fiber and graphite fiber[M].北京:化学工业出版社,2010 |
[14] | 李登华,吴刚平,吕春祥,李永红,贺福,杨禹,冯志海,汪明,李秀涛,郭玉明.聚丙烯腈基碳纤维及其原丝中的微孔尺寸分布[J].分析测试学报,2010(04):321-326. |
[15] | 盛毅,张彩红,徐耀,吕春祥,吴刚平,吴忠华,李志宏.二维小角X射线散射法研究PAN基炭纤维内部微孔结构[J].新型炭材料,2009(03):270-276. |
[16] | Miyoshi Kaburagi;Yuezhen Bin;Dan Zhu;Masaru Matsuo .Small angle x-ray scattering from voids within fibers during the stabilization and carbonization stages[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(5):915-926. |
[17] | Johnson D J;Tyson C N .Low-angle X-ray diffraction and physical properties of carbon fibers[J].Journal of Physics D:Applied Physics,1970,3(04):527-534. |
[18] | Zhu Yuping.SAXS-theory,test,computation and appli-cation[M].北京:化学工业出版社,2008 |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%