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通过对 L-丙氨酸掺杂下 ZTS(100)、(010)及(001)面法向生长速度的研究发现,各晶面法向生长速度随过饱和度的增加而线性增加;随掺杂浓度的增加,(100)面的法向生长速度先增大后减小,而(010)及(001)面的法向生长速度先减小,接着增大,然后又减小。分析表明(100)面以位错生长机制为主,(010)及(001)面以连续生长机制为主。利用光学显微镜在侵蚀后的(100)面观察到矩形位错蚀坑,蚀坑密度为33~308 mm-2;掺杂浓度为1%(摩尔分数)时,蚀坑密度最小。

Via studying the normal growth rates of the (100),(010)and (001)faces of ZTS crystal under differ-ent doping concentrations of L-alanine,we found that the normal growth rate of ZTS crystal increased linearly with the increase of supersaturation.With increase of doping concentration,L-alanine addition led to an initial increase and then a decrease of the normal growth rate of the (100)face.However,L-alanine doping led to a de-crease first,followed by an increase and then a decrease again of the normal growth rates of the (0 1 0 )and (001)faces.The growth of (100)face was featured mainly by the dislocation mechanism,and the growth of (010)and (001)faces are,however,featured by the continuous growth model as supported by the experimental results.Well-defined dislocation pits of rectangular shape were observed on the chemical etching (100)face of ZTS crystal by using optical microscopy.The dislocation density of (100)face was 33-308 mm-2 .Study results indicated that dislocation density could be minimized when L-alanine concentration was set at 1 mol%.

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