通过电子背散射衍射(EBSD)和高分辨透射电子显微术(HRTEM)对缺陷闪锌矿晶体 Hg3 In2 Te6(MIT)中的孪晶进行观察。实验发现,大多数基体的应变能比孪晶小,且一些带状孪晶的所有孪晶界均不共格。此外,高密度结构空位的存在并未改变孪生面和孪生方向。上述结果可按照变形孪晶,并考虑高密度结构空位团簇的影响来解释。HRTEM观察显示孪晶界上存在着台阶和孪生位错,符合变形孪晶的特征。
Electron backscattered diffraction (EBSD ) and high-resolution transmission electron microscopy (HRTEM)are used to study the twins in Hg3 In2 Te6 (MIT)crystals with defect zinc-blende structure.The re-sults show that strain energy of the maj ority of matrices was smaller than that of their corresponding twins.All twin boundaries of some band-like twins are incoherent.In addition,the existence of high-density structural va-cancies do not change the twinning plane and the twinning direction.The above results can be explained by de-formation twins with the consideration on the influence of high-density structural vacancy clusters.HRTEM observation shows that steps and twinning dislocations exist at the twin boundaries,which are consistent with deformation twins.
参考文献
[1] | S. YAMANAKA;M. ISHIMARU;A. CHAROENPHAKDEE;H. MATSUMOTO;K. KUROSAKI .Thermoelectric Characterization of (Ga,In)_(2)Te_(3) with Self-Assembled Two-Dimensional Vacancy Planes[J].Journal of Electronic Materials,2009(7):1392-1396. |
[2] | Athorn Vora-ud;Chanchana Thanachayanont;Suwit Jug-suj inda et al.Study on electronic structure ofβ-In2 Te3 thermoelectric material for alternative energy[J].Proce-dia Engineering,2011,8:2-7. |
[3] | CHANG-EUN KIM;KEN KUROSAKI;MANABU ISHIMARU;HIROAKI MUTA;SHINSUKE YAMANAKA .Effect of Vacancy Distribution on the Thermal Conductivity of Ga_(2)Te_(3) and Ga_(2)Se_(3)[J].Journal of Electronic Materials,2011(5):999-1004. |
[4] | Y. Seki;M. Kusakabe;S. Kashide .Dielectric and ac conductivity studiesin as-grown Ga2Te3 crystals with thedefect zinc-blende structure[J].Physica Status Solidi, A. Applied Research,2010(1):203-210. |
[5] | Malik Alexander I;Manuela Vieira;Miguel Fernandes.Near-infrared photodetectors based on a HgInTe-sem-iconductor compound[A].San Jose,1999:433-442. |
[6] | Maslyanchuk O L;Kosyachenko L A;German I I et al.Electrical and optical properties of Hg3 In2 Te6 single crys-tals[J].Physica Status Solidi C,2009,6(05):1154-1157. |
[7] | Ken K;Shinsuke Y.Effect of vacancy distribution on the thermoelectric properties of gallium and indium chalco-genides[M].USA:CRC Press,2012:1-9. |
[8] | Ken Kurosaki;Hideaki Matsumoto;Anek Charoenphakdee;Shinsuke Yamanaka;Manabu Ishimaru;Yoshihiko Hirotsu .Unexpectedly low thermal conductivity in natural nanostructured bulk Ga_(2)Te_(3)[J].Applied physics letters,2008(1):012101-1-012101-3-0. |
[9] | 罗林,介万奇,孙叶,王涛,傅莉.碲铟汞(111)晶面腐蚀坑的研究[J].功能材料,2010(10):1853-1856. |
[10] | Wang LH;Jie WQ;Yang Y;Xu G;Fu L .Etch pits observation and In distribution in mercury indium telluride single crystals[J].Semiconductor Science and Technology,2008(5):55015-1-55015-5-0. |
[11] | Linghang Wang;Wanqi Jie;Yang Yang;Gang Xu;Li Fu .Defect characterization and composition distributions of mercury indium telluride single crystals[J].Journal of Crystal Growth,2008(11):2810-2814. |
[12] | J. Shen;R. Balasubramanian;D. K. Aidun;L. L. Regel;W. R. Wilcox .Deformation behavior of cadmium telluride stressed at elevated temperatures[J].Journal of Materials Engineering and Performance,1998(4):555-563. |
[13] | Luo Dawei;Long jianping;Li Tingju .Research on the small plane dendrite grow mechanism of cast polysilicon[J].Journal of Functional Materials,2013,43(z2):192-197. |
[14] | Kentaro Kutsukake;Takuro Abe;Noritaka Usami .Formation mechanism of twin boundaries during crystal growth of silicon[J].Scripta materialia,2011(6):556-559. |
[15] | L. A. Kosyachenko;I. S. Kabanova;V. M. Sklyarchuk;O. F. Sklyarchuk;I. M. Rarenko .Hg_3In_2Te_6-based photodiodes for fiber optic communication[J].Physica Status Solidi, A. Applied Research,2009(2):351-355. |
[16] | Wang LH;Dong YC;Jie WQ .Growth, structure and electrical properties of mercury indium telluride single crystals[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2007(13):3921-3924. |
[17] | Stuart I. Wright;John Bingert;Thomas A. Mason .Advanced Characterization of Twins Using Automated Electron Backscatter Diffraction[J].Materials Science Forum,2002(Pt.1):511-516. |
[18] | Wright SI.;Larsen RJ. .Extracting twins from orientation imaging microscopy scan data[J].Journal of Microscopy,2002(Pt.3):245-252. |
[19] | Ma Q;Li B;Marin E B et al.Twinning-induced dy-namic recrystallization in a magnesium alloy extruded at 450 degrees C[J].Scripta Materialia,2011,65(09):823-826. |
[20] | Shi-Hoon Choi;Young-Sool Jin .Evaluation of stored energy in cold-rolled steels from EBSD data[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(1/2):149-159. |
[21] | 田彦宝,吉元,王俊忠,张隐奇,关宝璐,郭霞,沈光地.GaAs-AlGaAs外延结构中微区应力的电子背散射衍射分析[J].功能材料,2008(03):515-518,522. |
[22] | Jin Z.;Bieler TR. .BACK-STRESS DISTRIBUTION ALONG A THIN TWIN LAYER IN TIAL[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,1995(0):729-732. |
[23] | Valerie Randle .A METHODOLOGY FOR GRAIN BOUNDARY PLANE ASSESSMENT BY SINGLE-SECTION TRACE ANALYSIS[J].Scripta materialia,2001(12):2789-2794. |
[24] | 盛锋锋,杨建荣.CdZnTe晶体沉淀物特性的研究[J].功能材料,2013(z1):44-47,52. |
[25] | 王东,闵嘉华,梁小燕,孙孝翔,刘伟伟,李辉,张继军,王林军.温度梯度溶液生长法制备x=0.2的Cd_(1-x)Zn_xTe晶体及性能研究[J].功能材料,2012(10):1277-1280. |
[26] | Zhou Yan;Jie Wanqi;He Yihui et al.Study on the Te inclusions migration in CdZnTe single crystals during annealing under Cd/Zn vapors[J].Journal of Function-al Materials,2014,45(07):7135-7138. |
[27] | Jijun Zhang;Wanqi Jie;Linjun Wang;Lijun Luan .Twins in CdMnTe single crystals grown by Bridgman method[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,2010(1):7-12. |
[28] | Wang, C.;Wang, Z.;Li, G.;Meng, Q. .Interaction between the 30° partial dislocation and hex-vacancy in silicon[J].Modern Physics Letters, B. Condensed Matter Physics, Statistical Physics, Applied Physics,2012(24):1250154-1-1250154-8. |
[29] | Luo Lin;Jie Wanqi;Xu Yadong.The effect of structural vacancies on the twins in defect zinc-blende crystal Hg3 In2 Te6 grown by Bridgman method[J].Journal of Crystal Growth,2014 |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%