以二苄基胺、NaOH 和 CS2为原料，四氢呋喃作溶剂合成二苄基二硫代氨基甲酸钠，再与四甲基氯化铵反应，合成了新型的离子盐促进剂———二苄基二硫代氨基甲酸四甲基铵。通过红外(FT-IR)、核磁(1 H NMR)、质谱(MS)及元素分析等分析方法确定了产物的结构。为了研究新型促进剂的性能，实验将合成的二苄基二硫代氨基酸四甲基铵、二硫化四甲基秋兰姆(TMTD)分别添加到天然橡胶中制成胶片，对其进行溶胀指数(SI )和力学性能测试，结果表明合成的二苄基二硫代氨基酸四甲基铵具有优异的促进性能，是一种性能优异绿色环保的天然橡胶促进剂。
Sodium dibenzylcarbamodithioate can be synthesized by dibenzylamine,NaOH and CS2 as starting ma-terials,THF as solvent.Then the sodium dibenzylcarbamodithioate was used to react with tetramethylammoni-um chloride to get novel ionic salt accelerator—tetramethylammonium dibenzylcarbamodithioate.The structure of the compound was confirmed by Fourier transform infrared (FT-IR)spectroscopy,nuclear magnetic reso-nance(NMR)spectroscopy,mass (MS)spectroscopy and elemental analysis techniques.In order to study the properties of the novel accelerator-tetramethylammonium dibenzylcarbamodithioate and TMTD were added to the natural rubber latex,and made a kind of different Rubber diaphragms,and swell index(SI ),mechanical properties were also determined.The results indicated that,tetramethylammonium dibenzylcarbamodithioate which has good properties of accelerant was a kind of excellent natural rubber accelerator of green environmental protection.
参考文献
| [1] | Robert W L;DwightT W C .Minimizing nrosaminesuing serically hydered tiuram sulfides/thiocarbamates[J].Rubber Chemistry and Technology,1994,67(02):299-313. |
| [2] | Li Shujuan;Fan Shanying.Summary of rubber products N-nitrosamines research[J].Rubber Technology Mar-ket,2007(15):6-9. |
| [3] | 吕百龄.橡胶促进剂的发展趋势[J].精细与专用化学品,2003(23):3-5. |
| [4] | Mosch A;Giese U;Schuster R H .Investigation of the accelerated sulfur vulcanization of polydienes I reaction products of vulcanization of NR with CBS/S[J].Kaut-schuk Gummi Kunststoffe,2003,56(04):184-189. |
| [5] | Bai Peng;Liang Xizheng;Zhao Sujuan et al.TBSI envi-ronmentally friendly application accelerator in rubber[J].World Rubber Industry,2011,38(07):10-16. |
| [6] | Stevenson A;Virdi R S .Rubber composition containing dibenzyl thiuram sulfide[P].USP:A1,5254635,1993-10-19. |
| [7] | Wang Zhiqiang;Wang Fei;Qian Juanjuan .Application and market progress of environmentally friendly rubber accelerator TBzTD of[J].Chain RubberR,2010,26(19):34-38. |
| [8] | 谷金翠,谭海生,何映平,廖小雪,李加广,贾友钢.促进剂ZBEC对天然胶乳胶膜的硫化及力学性能的影响[J].特种橡胶制品,2012(01):9-12. |
| [9] | Martyn J. Earle;Kenneth R. Seddon .Ionic liquids. Green solvents for the future[J].Pure and Applied Chemistry,2000(7):1391-1398. |
| [10] | T.Welton .Ionic liquids in Green Chemistry[J].Green chemistry,2011(2):225-225. |
| [11] | Robin D. Rogers;Kenneth R. Seddon .Ionic liquids--solvents of the future?[J].Science,2003(5646):792-793. |
| [12] | 雷佑安,曾繁涤,丁明洁.碳纳米管有机离子盐合成和有规组装[J].功能材料,2011(09):1623-1626. |
| [13] | Juliusz Pernak;Filip Walkiewicz;Magdalena Maciejewska .Ionic Liquids as Vulcanization Accelerators[J].Industrial & Engineering Chemistry Research,2010(10):5012-5017. |
| [14] | Maciejewska M;Zaborski M;Kordala R et al.Ionic liquids as accelerators in elastomer vulcanization[J].Przemysl Chemiczny,2010,89(11):1470-1474. |
| [15] | Magdalena Maciejewska;Filip Walkiewicz;Marian Zaborski .Novel Ionic Liquids as Accelerators for the Sulfur Vulcanization of Butadiene-Styrene Elastomer Composites[J].Industrial & Engineering Chemistry Research,2013(25):8410-8415. |
| [16] | Magdalena Przybyszewska;Marian Zaborski .Effect of Ionic Liquids and Surfactants on Zinc Oxide Nanoparticle Activity in Crosslinking of Acrylonitrile Butadiene Elastomer[J].Journal of Applied Polymer Science,2010(1):155-164. |
| [17] | Yang Qingzhi.Modern rubber technology[M].北京:中国石化出版社,1997 |
| [18] | HG/T 3870-2008.Rubber,vulcanized-Determination method of swelling index[S]. |
| [19] | GB/T528-2009.Rubber,vulcanized or thermoplastic-De-termination of tensile stress-strain properties[S]. |
| [20] | GB/T531-1999.Rubber,vulcanized or thermoplastic-De-termination of hardness[S]. |
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