欢迎登录材料期刊网

材料期刊网

高级检索

采用自主研发的碱性铜抛光液,使用前稀释50倍加入不同剂量 H2 O2配制成碱性铜精抛液。实验结果表明,随着 H2 O2含量的增加,铜的静态腐蚀速率(CuDR)、抛光速率(CuPR)以及阻挡层 Ta/TaN 均有小幅度的降低,但在 MIT854布线片上精抛实验结果表明,碟形坑随着 H2 O2含量的增加逐渐降低,加入5%(体积分数)H2 O2的精抛液,在粗抛实现初步平坦化后,精抛去除残余铜的过程中,能够实现不同线条尺寸的完全平坦化,碟形坑在工业要求范围内。研究结果表明,H2 O2含量的增加对速率影响不明显,但有利于铜布线片的平坦化。此规律对提高 CMP 全局平坦化具有极重要的作用。

The alkaline copper slurry which was made by out own,diluted (X50)as the copper clearing slurry and add different concentration H2 O2 into the slurry before used.Experiment results show that as the H2 O2 concentration increase,the dissolution rate and polish rate of copper,also the barrier films such as Ta/TaN re-moval rate have small decrease.But the experiment on the MIT854 pattern wafer in copper clearing step re-sults,the dishing values reduce with the H2 O2 concentration increase.The copper clearing slurry with 5vol%H2 O2 ,after achieved initial planarization,follow the copper clearing step for copper residue removal,the pat-tern wafer can achieved completely planarization of different linewidths,the dishing values can meet the indus-trial requirements.These rules paly an important role to achieve global planarization of CMP.

参考文献

[1] V. Nguyen;H. VanKranenburg;P. Woerlee .Dependency of dishing on polish time and slurry chemistry in Cu CMP[J].Microelectronic engineering,2000(1/4):403-410.
[2] 岳红维,王胜利,刘玉岭,王辰伟,尹康达,郑伟艳,串利伟.碱性抛光液中H2O2对铜布线CMP的影响[J].微纳电子技术,2012(08):553-556.
[3] 郑伟艳,刘玉岭,王辰伟,串利伟,魏文浩,岳红维,曹冠龙.低压下碱性铜抛光液对300mm多层铜布线平坦化的研究[J].功能材料,2012(24):3472-3474.
[4] Viet H. Nguyen;Roel Daamen;Romano Hoofman .Impact of different slurry and polishing pad choices on the planarization efficiency of a copper CMP process[J].Microelectronic engineering,2004(1/4):95-99.
[5] 李湘,刘玉岭,王辰伟,尹康达.双氧水在碱性抛光液中的稳定性研究[J].半导体技术,2012(11):850-854.
[6] Chenwei Wang;Jiaojiao Gao;Jianying Tian;Xinhuan Niu;Yuling Liu .Chemical mechanical planarization of barrier layers by using a weakly alkaline slurry[J].Microelectronic engineering,2013(Aug.):71-75.
[7] 唐心亮,刘玉岭,王辰伟,牛新环,高宝红.碱性Cu布线抛光液速率特性及平坦化性能的研究[J].功能材料,2012(20):2804-2806.
[8] Christopher M S;Dipankar R .Electrochemical character-ization of surface complexes formed on Cu and Ta insuc-cinic acid based solutions used for chemical mechanical planarization[J].Applied Surface Science,2012,256:2583-2595.
[9] S.E. Rock;D.J. Crain;C.M. Pettit;D. Roy .Surface-complex films of guanidine on tantalum nitride electrochemically characterized for applications in chemical mechanical planarization[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2012(7):2892-2900.
[10] H.S. Lee;H.D. Jeong;D.A. Dornfeld .Semi-empirical material removal rate distribution model for SiO_2 chemical mechanical polishing (CMP) processes[J].Precision Engineering,2013(2):483-490.
[11] Jiao Y;Sampurno Y A;Zhuang Y et al.Tribological,thermal,and kinetic characterization of 300 mm copper chemical mechanical planarization process[J].Japanese Journal of Applied Physics,2011,50:05EC02.
[12] Mahadevaiyer Krishnan;Jakub W. Nalaskowski;Lee M. Cook .Chemical Mechanical Planarization: Slurry Chemistry, Materials, and Mechanisms[J].Chemical Reviews,2010(1):178-204.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%