酚醛树脂是一种常用的活性炭碳源，其独特的优势使其受到科研工作者的青睐。由于孔结构是影响活性炭性能和应用的主要因素，孔径调控是多孔炭制备过程的关键。常用的孔径调控方法有金属催化，添加造孔剂以及模板法。通过不同的造孔方法制备的酚醛树脂基多孔炭在环保、电化学、医药催化等领域有着广泛的用途。综述了酚醛树脂基多孔炭的制备和常用的孔径调控方法以及近年来主要的应用，并对其以后的研究和应用进行了展望。
As a common precursor of activated carbon,phenolic resin has attracted much attention of researchers due to its unique properties.The pore structure plays an important role in the performance of activated carbon. Therefore,pore size tailoring was crucial in the preparation process.There were lots of pore size tailoring meth-ods of activated carbon,such as metal catalytic method,adding pore-forming agents and template technique. The obtained phenolic resin-based porous carbon with different pore size distribution has extensive applications in fields of environmental protection,electrochemistry,medicine and catalysis.This paper reviews the prepara-tion of phenolic resin-based porous carbon and different pore size tailoring methods as well as its main applica-tions in recent years.The future research and application of phenolic resin-based porous carbon are also high-lighted in this review.
参考文献
| [1] | Tennison S R .Phenolic-resin-derived activated carbons[J].APPLIED CATALYSIS A-GENERAL,1998,173:289-311. |
| [2] | Centeno Teresa A.;Fuertes Antonio B. .Supported carbon molecular sieve membranes based on a phenolic resin[J].Journal of Membrane Science,1999(2):201-211. |
| [3] | T.A. Centeno;J.L. Vilas;A.B. Fuertes .Effects of phenolic resin pyrolysis conditions on carbon membrane performance for gas separation[J].Journal of Membrane Science,2004(1):45-54. |
| [4] | Pelekani C.;Snoeyink VL. .Competitive adsorption between atrazine and methylene blue on activated carbon: the importance of pore size distribution[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(10):1423-1436. |
| [5] | Wu Mingbo .Advance of research in making activated car-bon by chemical activation[J].Carbon Techniques,1999,102(04):19-23. |
| [6] | Gregory P Meisner;Qingyuan Hu .High surface area microporous carbon materials for cryogenic hydrogen storage synthesized using new template-based and activation-based approaches[J].Nanotechnology,2009(20):204023-10. |
| [7] | Yue ZR;Economy J;Bordson G .Preparation and characterization of NaOH-activated carbons from phenolic resin[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2006(15):1456-1461. |
| [8] | Yue ZR;Economy J;Rajagopalan K;Bordson G;Piwoni M;Ding L;Snoeyink VL;Marinas BJ .Chemically activated carbon on a fiberglass substrate for removal of trace atrazine from water[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2006(33):3375-3380. |
| [9] | 刘春玲,文越华,程杰,郭全贵,曹高萍,刘朗,杨裕生.酚醛基活性炭纤维孔结构及其电化学性能研究[J].物理化学学报,2005(07):786-791. |
| [10] | Singh A;Lal D .Microporous Activated Carbon Spheres Prepared from Resole-Type Crosslinked Phenolic Beads by Physical Activation[J].Journal of Applied Polymer Science,2008(5):3283-3291. |
| [11] | Yue Liu;KaixiLi;GuohuaSun .Effect ofprecursorpreoxidationonthestructureofphenolicresin-based activatedcarbonspheres[J].The journal of physics and chemistry of solids,2010(4):453-456. |
| [12] | Qiong Cai;Zheng-Hong Huang;Feiyu Kang .Preparation of activated carbon microspheres from phenolic-resin by supercritical water activation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(4):775-783. |
| [13] | 李颖,黄正宏,康飞宇,李宝华.以超临界和亚临界水活化掺金属化合物的酚醛树脂制备球形活性炭[J].新型炭材料,2010(02):109-113. |
| [14] | 文婕,孙文晶,杨文,王宁,储伟.氧化活性炭在模型油中吸附脱氮性能研究[J].功能材料,2012(13):1770-1773,1777. |
| [15] | 文婕,孙文晶,杨文.氧化改性活性炭吸附脱氮选择性研究[J].功能材料,2013(20):2954-2958. |
| [16] | Nakagawa K;Mukai S R;Tamura K et al.Mesoporous activated carbons from phenolic resins[J].Chemical Engi-neering Research and Design,2007,85(09):1331-1337. |
| [17] | 杨骏兵,凌立成,吕春祥,刘朗.二茂铁的添加对酚醛树脂基球形活性炭活化特性以及孔径分布的影响[J].离子交换与吸附,2000(02):155-161. |
| [18] | 杨骏兵,康飞宇,黄正宏,凌立成,刘朗.从铁状态的变化研究球形活性炭中孔形成的机理[J].离子交换与吸附,2001(02):104-109. |
| [19] | 邹李鸣,黄正宏,康飞宇,杨骏兵.载银酚醛树脂基球形活性炭的研究[J].新型炭材料,2003(03):214-218. |
| [20] | 杨骏兵,康飞宇,黄正宏.过渡族金属对球形活性炭孔结构与吸附性能的影响[J].清华大学学报(自然科学版),2002(05):688-691. |
| [21] | 杨骏兵,康飞宇,黄正宏,梁开明.添加钙对酚醛树脂基球形炭活化特性及孔结构的影响[J].清华大学学报(自然科学版),2002(10):1297-1299. |
| [22] | 郑军,王旭珍,赵宗彬,张海鹰.载铁酚醛树脂基活性炭的制备及H2S脱除性能[J].煤炭转化,2008(03):77-81. |
| [23] | Katsuya Inomata;Yoshinobu Otake .Formation and development of micropores in carbon prepared via catalytic carbonization of phenolic resin containing Fe or Ni compounds[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2011(1):60-65. |
| [24] | Oya A.;Alcanizmonge J.;Linaressolano A.;Yoshida S. .PREPARATION AND PROPERTIES OF AN ANTIBACTERIAL ACTIVATED CARBON FIBER CONTAINING MESOPORES[J].Carbon: An International Journal Sponsored by the American Carbon Society,1996(1):53-57. |
| [25] | Oya A.;Alcanizmonge J.;Linaressolano A.;Yoshida S. .FORMATION OF MESOPORES IN PHENOLIC RESIN-DERIVED CARBON FIBER BY CATALYTIC ACTIVATION USING COBALT[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(8):1085-1090. |
| [26] | 杨骏兵,凌立成,刘朗.利用聚合物共混法对活性炭材料的孔径分布进行控制的原理和方法[J].材料导报,2000(04):48-50,29. |
| [27] | Yang Junbing;Kang Feiyu;Huang Zhenghong et al.Effect of adding polyethylene glycol on the structure and properties of phenolic resin-based carbon spheres[J].Ion Exchange and Adsorption,2001,17(03):193-198. |
| [28] | Jun-Bing Yang;Li-Cheng Ling;Lang Liu;Fei-Yu Kang;Zheng-Hong Huang;Hui Wu .Preparation and properties of phenolic resin-based activated carbon spheres with controlled pore size distribution[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(6):911-916. |
| [29] | Alpha Labiano;Mingzhi Dai;Wen-Shiue Young .Impact of Homopolymer Pore Expander on the Morphology of Mesoporous Carbon Films Using Organic-Organic Self-Assembly[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2012(10):6038-6046. |
| [30] | 夏笑虹,刘洪波,黄衍瑞,杨丽,石磊.己二酸/酚醛树脂共聚炭化制备多孔炭材料及其电性能研究[J].无机材料学报,2011(08):857-862. |
| [31] | Xiaohong Xia;Hongbo Liu;Yuede He;Lei Shi;Hui Chen;Li Yang .Investigation of porous carbon fabricated by polymer blending of phenolic resin and suberic acid[J].Journal of the Iranian Chemical Society,2012(4):544-550. |
| [32] | Choma J;Górka J;Jaroniec M et al.Development of microporosity in mesoporous carbons[J].Topics in Catalysis,2009,53(3-4):283-290. |
| [33] | Choma J;Dziura A;Górka J et al.Adsorption proper-ties of micro-/meso-porous carbons obtained by colloidal templating and post-synthesis KOH activation[J].Ad-sorpt Sci Technol,2011,29(05):457-465. |
| [34] | Jerzy Choma;Anna Zubrowska;Joanna Gorka .Adsorption properties of phenolic resin-based mesoporous carbons obtained by using mixed templates of Pluronic F127 and Brij 58 or Brij 78 polymers[J].Adsorption,2010(4/5):377-383. |
| [35] | Nilantha P. Wickramaratne;Mietek Jaroniec.Phenolic resin-based carbons with ultra-large mesopores prepared in the presence of poly(ethylene oxide)-poly(butylene oxide)-poly(ethylene oxide) triblock copolymer and trimethyl benzene[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:45-51. |
| [36] | Joanna Gorka;Mietefe Jaroniec .Hierarchically porous phenolic resin-based carbons obtained by block copolymer-colloidal silica templating and post-synthesis activation with carbon dioxide and water vapor[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(1):154-160. |
| [37] | Górka J;Zawislak A;Choma J et al.KOH activation of mesoporous carbons obtained by soft-templating[J].CARBON,2008,46:1159-1174. |
| [38] | Sharma, A;Verma, N;Sharma, A;Deva, D;Sankararamakrishnan, N .Iron doped phenolic resin based activated carbon micro and nanoparticles by milling: Synthesis, characterization and application in arsenic removal[J].Chemical Engineering Science,2010(11):3591-3601. |
| [39] | Mekala Bikshapathi;Susovan Mandal;Gyanesh N. Mathur .Modification of Activated Carbon Fiber by Metal Dispersion and Surface Functionalization for the Removal of 2-Chloroethanol[J].Industrial & Engineering Chemistry Research,2011(23):13092-13104. |
| [40] | Minmin Teng;Junlian Qiao;Fengting Li .Electrospun mesoporous carbon nanofibers produced from phenolic resin and their use in the adsorption of large dye molecules[J].Carbon: An International Journal Sponsored by the American Carbon Society,2012(8):2877-2886. |
| [41] | Nilantha P. Wickramaratne;Mietek Jaroniec .Importance of small micropores in CO2 capture by phenolic resin-based activated carbon spheres[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,2013(1):112-116. |
| [42] | Nilantha P. Wickramaratne;Mietek Jaroniec .Activated Carbon Spheres for CO2 Adsorption[J].ACS applied materials & interfaces,2013(5):1849-1855. |
| [43] | C.F. Martin;M.G. Plaza;S. Garcia;J.J. Pis;F. Rubiera;C. Pevida .Microporous phenol-formaldehyde resin-based adsorbents for pre-combustion CO_2 capture[J].Fuel,2011(5):2064-2072. |
| [44] | Akinori Muto;Thallada Bhaskar;Shinichiro Tsuneishi .Activated Carbon Monoliths from Phenol Resin and Carbonized Cotton Fiber for Methane Storage[J].Energy & Fuels,2005(1):251-257. |
| [45] | Yanyan Feng;Wen Yang;Ning Wang;Wei Chu;Daijun Liu .Effect of nitrogen-containing groups on methane adsorption behaviors of carbon spheres[J].Journal of analytical & applied pyrolysis,2014(May):204-210. |
| [46] | Elzbieta Frackowiak;Francois Beguin .Carbon materials for the electrochemical storage of energy in capacitors[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(6):937-950. |
| [47] | A. G. Pandolfe;A. F. Hollenkamp .Carbon properties and their role in supercapacitors[J].Journal of Power Sources,2006(1):11-27. |
| [48] | Daisuke Tashima;Eri Yamamoto;Nanami Kai .Double layer capacitance of high surface area carbon nanospheres derived from resorcinol-formaldehyde polymers[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(14):4848-4857. |
| [49] | Tingwei Cai;Min Zhou;Guangshuai Han;Shiyou Guan .Phenol-formaldehyde carbon with ordered/disordered bimodal mesoporous structure as high-performance electrode materials for supercapacitors[J].Journal of Power Sources,2013(Nov.1):6-11. |
| [50] | Preparation of mesoporous MgO-templated carbons from phenolic resin and their applications for electric double-layer capacitors[J].科学通报（英文版）,2013(09):992-997. |
| [51] | Chang Ma;Yan Song;Jingli Shi.Preparation and one-step activation of microporous carbon nanofibers for use as supercapacitor electrodes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:290-300. |
| [52] | Chang Ma;Yan Song;Jingli Shi;Dongqing Zhang;Ming Zhong;Quangui Guo;Lang Liu.Phenolic-based carbon nanofiber webs prepared by electrospinning for supercapacitors[J].Materials Letters,2012:211-214. |
| [53] | Nilantha P. Wickramaratne;Mietek Jaroniec.Phenolic resin-based carbons with ultra-large mesopores prepared in the presence of poly(ethylene oxide)-poly(butylene oxide)-poly(ethylene oxide) triblock copolymer and trimethyl benzene[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:45-51. |
| [54] | Xia Niu;Long Wan;Zhong Hou;Tianyi Wang;Changshan Sun;Jin Sun;Peng Zhao;Tongying Jiang;Siling Wang .Mesoporous carbon as a novel drug carrier of fenofibrate for enhancement of the dissolution and oral bioavailability.[J].International Journal of Pharmaceutics,2013(1/2):382-389. |
| [55] | Wang, S.;Zhao, Q.;Wei, H.;Wang, J.-Q.;Cho, M.;Cho, H.S.;Terasaki, O.;Wan, Y. .Aggregation-free gold nanoparticles in ordered mesoporous carbons: Toward highly active and stable heterogeneous catalysts[J].Journal of the American Chemical Society,2013(32):11849-11860. |
| [56] | 顾金玲 .基于酚醛树脂活性炭的制备及负载TiO2吸附—光催化性能[D].哈尔滨工业大学,2008. |
| [57] | Broda M;Muller C R .Synthesis of highly efficient,Ca-based,Al2 O3-stabilized,carbon gel-templated CO2 sor-bents[J].Advanced Materials,2012,24(22):3059-3064. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%