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石墨烯作为一种新型的碳纳米材料,具有独特的物理化学性质如高的机械强度、良好的稳定性、超大的比表面积及极强的表面化学活性等,使得石墨烯成为一种得天独厚的吸附材料。综述了石墨烯及其复合材料的制备方法,并对其在去除水中重金属离子的研究进展与吸附机理方面进行了综述,最后对石墨烯及其复合材料的后续研究方向进行了展望。

Graphene was a new type of carbon nanomaterials,which has unique physical and chemical properties, including high mechanical strength,good stability,strong superficial chemical activity and large surface area. These characteristics make graphene be a unique adsorption material.This article mainly summarized the syn-thesis of graphene and graphene composites.Moreover,the main research progress and adsorption mechanism for the removal of heavy metal ions from water were all summarized.Finally,the further research directions of graphene were prospected.

参考文献

[1] Jian-Rong Li;Ryan J. Kuppler;Hong-Cai Zhou .Selective gas adsorption and separation in metal-organic frameworks[J].Chemical Society Reviews,2009(5):1477-1504.
[2] Emanuele Ostuni;Robert G. Chapman;R. Erik Holmlin .A Survey of Structure-Property Relationships of Surfaces that Resist the Adsorption of Protein[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(18):5605-5620.
[3] Zacaria Reddad;Claire Gerente;Yves Andres;Pierre Le Cloirec .Adsorption of several metal ions onto a low-cost biosorbent: kinetic and equilibrium studies[J].Environmental Science & Technology: ES&T,2002(9):2067-2073.
[4] Fein J B;Daughney C J;Yee N et al.A chemical equilibrium model for metal adsorption onto bacterial surfaces[J].Geochimica et Cosmochimica Acta,1997,61(16):3319-3328.
[5] A. M. Liu;K. Hidajat;S. Kawi;D. Y. Zhao .A new class of hybrid mesoporous materials with functionalized organic monolayers for selective adsorption of heavy metal ions[J].Chemical communications,2000(13):1145-1146.
[6] Zhu Tao;Dai Yazhong;Wan Yandong et al.Coal gas mercury removal by adsorption[J].Environmental Engi-neering,2012,30:228-231.
[7] Wu Jiaan;Bao Xingchen;Fu Ya et al.Prepartion of gra-phene oxide-nial/layered double hydroxide-carbon fibers composite material and electrosorption 2,6-dichlorophenol in aqueous solution[J].Journal of Functional Materials,2013,20(05):32-38.
[8] M. Madhava Rao;D.K. Ramana;K. Seshaiah;M.C. Wang;S.W. Chang Chien .Removal of some metal ions by activated carbon prepared from Phaseolus aureus hulls[J].Journal of hazardous materials,2009(2/3):1006-1013.
[9] Susmita Sen Gupta;Krishna G. Bhattacharyya .Adsorption of heavy metals on kaolinite and montmorillonite: a review[J].Physical chemistry chemical physics: PCCP,2012(19):6698-6723.
[10] Kim Y;Yi J .Advances in environmental technologies via the application of mesoporous materials[J].Journal of Industrial and Engineering Chemistry,2004,10(01):41-51.
[11] Novoselov K S;Geim A K;Morozov S et al.Electric field effect in atomically thin carbon films[J].SCIENCE,2004,306(5696):666-669.
[12] 郑晓雨,苏方远,杨全红,康飞宇.石墨烯在锂系二次电池中的应用:进展与展望[J].功能材料,2013(19):2741-2748.
[13] Acik M;Chabal Y J;Abe S et al.Selected topics in ap-plied physics technology,physics,and modeling of gra-phene devices[J].Journal of Applied Physics,2011,50(07):106-113.
[14] Sanchez VC;Jachak A;Hurt RH;Kane AB .Biological interactions of graphene-family nanomaterials: an interdisciplinary review.[J].Chemical research in toxicology,2012(1):15-34.
[15] Yanwu Zhu;Shanthi Murali;Weiwei Cai;Xuesong Li;Ji Won Suk;Jeffrey R. Potts;Rodney S. Ruoff .Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J].Advanced Materials,2010(35):3906-3924.
[16] Daniel R. Dreyer;Sungjin Park;Christopher W. Bielawski .The chemistry of graphene oxide[J].Chemical Society Reviews,2010(1):228-240.
[17] Huang, X.;Yin, Z.;Wu, S.;Qi, X.;He, Q.;Zhang, Q.;Yan, Q.;Boey, F.;Zhang, H. .Graphene-based materials: Synthesis, characterization, properties, and applications[J].Small,2011(14):1876-1902.
[18] Meyer J C;Geim A K;Katsnelson M I et al.The structure of suspended graphene sheets[J].NATURE,2007,446(7131):60-63.
[19] Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191.
[20] Li X S;Cai W W;An J H et al.Large-area synthesis of high-quality and uniform graphene films on copper foils[J].SCIENCE,2009,324(5932):1312-1314.
[21] Ashish Kumar Mishra;S. Ramaprabhu.Functionalized graphene sheets for arsenic removal and desalination of sea water[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2011:39-45.
[22] A. Santhana Krishna Kumar;Shruti Singh Kakan;N. Rajesh.A novel amine impregnated graphene oxide adsorbent for the removal of hexavalent chromium[J].Chemical engineering journal,2013:328-337.
[23] Ma H L;Zhang Y;Hu Q H et al.Chemical reduction and removal of Cr(Ⅵ)from acidic aqueous solution by ethylenediamine-reduced graphene oxide[J].Journal of Materials Chemistry,2012,22(13):5914-5916.
[24] Zhang Y;Ma H L;Peng J et al.Cr(Ⅵ)removal from a-queous solution using chemically reduced and functionalized graphene oxide[J].Journal of Materials Science,2012,48(05):1883-1889.
[25] Bhunia, P.;Kim, G.;Baik, C.;Lee, H. .A strategically designed porous iron-iron oxide matrix on graphene for heavy metal adsorption[J].Chemical communications,2012(79):9888-9890.
[26] Yueming Ren;Ni Yan;Qing Wen.Graphene/δ-MnO2 composite as adsorbent for the removal of nickel ions from wastewater[J].Chemical engineering journal,2011:1-7.
[27] Luo X;Wang C;Wang L et al.Nanocomposites of gra-phene oxide-hydrated zirconium oxide for simultaneous removal of As(Ⅲ)and As(Ⅴ)from water[J].CHEMICAL ENGINEERING JOURNAL,2013,220(03):98-106.
[28] Hao, L.;Song, H.;Zhang, L.;Wan, X.;Tang, Y.;Lv, Y..SiO _2/graphene composite for highly selective adsorption of Pb(II) ion[J].Journal of Colloid and Interface Science,2012:381-387.
[29] Li, N.;Zheng, M.;Chang, X.;Ji, G.;Lu, H.;Xue, L.;Pan, L.;Cao, J. .Preparation of magnetic CoFe_2O_4-functionalized graphene sheets via a facile hydrothermal method and their adsorption properties[J].Journal of Solid State Chemistry,2011(4):953-958.
[30] MICHAEL ARKAS;ROZA ALLABASHI;DIMITRIS TSIOURVAS;EVA-MARIA MATTAUSCH;REINHARD PERFLER .Organic/Inorganic Hybrid Filters Based on Dendritic and Cyclodextrin "Nanosponges" for the Removal of Organic Pollutants from Water[J].Environmental Science & Technology: ES&T,2006(8):2771-2777.
[31] Berto S;Bruzzoniti M;Cavalli R et al.Synthesis of new ionicβ-cyclodextrin polymers and characterization of their heavy metals retention[J].Journal of Inclusion Phenomena and Molecular Recognition in Chemistry,2007,57(1-4):631-636.
[32] Galia A;Navarre EC;Scialdone O;Ferreira M;Filardo G;Tilloy S;Monflier E .Complexation of phosphine ligands with peracetylated beta-cyclodextrin in supercritical carbon dioxide: Spectroscopic determination of equilibrium constants[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2007(10):2573-2578.
[33] Song W;Hu J;Zhao Y et al.Efficient removal of co-balt from aqueous solution usingβ-cyclodextrin modified graphene oxide[J].RSC Adv,2013,3(24):9514-9521.
[34] Li, L.;Fan, L.;Sun, M.;Qiu, H.;Li, X.;Duan, H.;Luo, C..Adsorbent for chromium removal based on graphene oxide functionalized with magnetic cyclodextrin-chitosan[J].Colloids and Surfaces, B. Biointerfaces,2013:76-83.
[35] Madadrang C J;Kim H Y;Gao G et al.Adsorption behavior of EDTA-graphene oxide for Pb(Ⅱ)removal[J].ACS Ap-plied Materials &Interfaces,2012,4(03):1186-1193.
[36] He Y Q;Zhang N N;Wang X D .Adsorption of gra-phene oxide/chitosan porous materials for metal ions[J].Chinese Chem L,2011,22(07):859-862.
[37] Blindauer CA;Harrison MD;Robinson AK;Parkinson JA;Bowness PW;Sadler PJ;Robinson NJ .Multiple bacteria encode metallothioneinsand SmtA-like zinc fingers.[J].Molecular Microbiology,2002(5):1421-1432.
[38] Yang T;Liu L H;Liu J W et al.Cyanobacterium met-allothionein decorated graphene oxide nanosheets for highly selective adsorption of ultra-trace cadmium[J].Journal of Materials Chemistry,2012,22(41):21909-21916.
[39] Wei C;German S;Basak S et al.Reduction of hexava-lent chromium in aqueous solutions by polypyrrole[J].Journal of the Electrochemical Society,1993,140(04):L60-L62.
[40] Li S;Lu X;Xue Y et al.Fabrication of polypyrrole/graphene oxide composite nanosheets and their applica-tions for Cr(Ⅵ)removal in aqueous solution[J].PloS One,2012,7(08):e43328.
[41] Mallikarjuna N. Nadagouda;Alicia B. Castle;Richard C. Murdock .In vitro biocompatibility of nanoscale zerovalent iron particles (NZVI) synthesized using tea polyphenols[J].Green chemistry,2010(1):114-122.
[42] Jabeen H;Chandra V;Jung S et al.Enhanced Cr(Ⅵ)removal using iron nanoparticle decorated graphene[J].Nanoscale,2011,3(09):3583-3585.
[43] Wang, Q.;Ohare, D. .Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets[J].Chemical Reviews,2012(7):4124-4155.
[44] Application of layered double hydroxides for removal of oxyanions: A review[J].Water research: A journal of the international water association,2008(6/7):p.1343-1368.
[45] Li F;Duan X.Applications of layered double hydroxides[M].Springer:In Layered double hydroxides,2006
[46] Yuan X;Wang Y;Wang J et al.Calcined graphene/MgAl-layered double hydroxides for enhanced Cr(Ⅵ)removal[J].CHEMICAL ENGINEERING JOURNAL,2013,221(04):204-213.
[47] Toshiyuki Hibino;Hitoshi Ohya .Synthesis of crystalline layered double hydroxides: Precipitation by using urea hydrolysis and subsequent hydrothermal reactions in aqueous solutions[J].Applied clay science,2009(3):178-184.
[48] Gollavelli G;Chang C C;Ling Y C .Facile synthesis of smart magnetic graphene for safe drinking water:heavy metal removal and disinfection control[J].ACS Chem Eng,2013,1(05):462-472.
[49] Wu W;Yang Y;Zhou H et al.Highly efficient removal of Cu(Ⅱ)from aqueous solution by using graphene oxide[J].Water Air and Soil Pollution,2012,224(01):1372-1380.
[50] Sibel Tunali;Tamer Akar .Zn(Ⅱ) biosorption properties of Botrytis cinerea biomass[J].Journal of hazardous materials,2006(1/3):137-145.
[51] Sitko, R.;Turek, E.;Zawisza, B.;Malicka, E.;Talik, E.;Heimann, J.;Gagor, A.;Feist, B.;Wrzalik, R. .Adsorption of divalent metal ions from aqueous solutions using graphene oxide[J].Dalton transactions: An international journal of inorganic chemistry,2013(16):5682-5689.
[52] Huang, Z.-H.;Zheng, X.;Lv, W.;Wang, M.;Yang, Q.-H.;Kang, F. .Adsorption of lead(II) ions from aqueous solution on low-temperature exfoliated graphene nanosheets[J].Langmuir: The ACS Journal of Surfaces and Colloids,2011(12):7558-7562.
[53] Suman Thakur;Gautam Das;Prasanta Kumar Raul .Green One-Step Approach to Prepare Sulfur/Reduced Graphene Oxide Nanohybrid for Effective Mercury Ions Removal[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2013(15):7636-7642.
[54] 杜声玖,王蜀霞,刁凯迪,廖中伟.B原子吸附石墨烯的结构和性质[J].重庆理工大学学报:自然科学,2012(07):105-109.
[55] Li W;Gao S;Wu L et al.High-density three-dimension graphene macroscopic obj ects for high-capacity removal of heavy metal ions[J].Sci Rep,2013,3(10):2125-2131.
[56] Chandra, V.;Kim, K.S. .Highly selective adsorption of Hg~(2+) by a polypyrrole-reduced graphene oxide composite[J].Chemical communications,2011(13):3942-3944.
[57] Musico Y L F;Santos C M;Dalida M L P et al.Im-proved removal of lead(Ⅱ)from water using a polymer-based graphene oxide nanocomposite[J].J Mater Chem A,2013,1(11):3789-3796.
[58] 边缘修饰对石墨烯纳米带电子和磁性性质的影响[J].重庆理工大学学报(自然科学版),2014(07):86-91.
[59] Li Xinbao;Gu Wei;Cao Yong .Research progress in gra-phene composites adsorption heavy matal ions from water[J].Journal of Functional Materials,2013,44(01):5-11.
[60] Sun Y;Wang Q;Chen C et al.Interaction between Eu(Ⅲ)and graphene oxide nanosheets investigated by batch and extended X-ray absorption fine structure spec-troscopy and by modeling techniques[J].Environmental Science and Technology,2012,46(11):6020-6027.
[61] Zhao, G.;Wen, T.;Yang, X.;Yang, S.;Liao, J.;Hu, J.;Shao, D.;Wang, X. .Preconcentration of U(vi) ions on few-layered graphene oxide nanosheets from aqueous solutions[J].Dalton transactions: An international journal of inorganic chemistry,2012(20):6182-6188.
[62] Pan, N.;Guan, D.;He, T.;Wang, R.;Wyman, I.;Jin, Y.;Xia, C. .Removal of Th~(4+) ions from aqueous solutions by graphene oxide[J].Journal of Radioanalytical and Nuclear Chemistry: An International Journal Dealing with All Aspects and Applications of Nuclear Chemistry,2013(3):1999-2008.
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