PZT 掺杂改性研究进展及其机理探究

功能材料, 2015, (4): 4009-4015. doi: 10.3969/j.issn.1001-9731.2015.04.002

PZT 掺杂改性研究进展及其机理探究

刘喆 ^1, , 邢志国 ^2, , 王海斗 ^3, , 徐滨士 ^4, , 金国 ^5,

1.哈尔滨工程大学材料科学与化学工程学院表/界面科学与技术研究所，哈尔滨 150001; 装甲兵工程学院装备再制造技术国防科技重点实验室，北京 100072

2.装甲兵工程学院装备再制造技术国防科技重点实验室,北京,100072

3.装甲兵工程学院装备再制造技术国防科技重点实验室,北京,100072

4.装甲兵工程学院装备再制造技术国防科技重点实验室,北京,100072

5.哈尔滨工程大学材料科学与化学工程学院表/界面科学与技术研究所,哈尔滨,150001

基金项目: 国家重点基础研究发展计划(973计划)资助项目(2011CB013405) 国家自然科学基金资助项目(51275526) 北京市自然科学基金资助项目(3142019)

关键词：锆钛酸铅 , 掺杂改性机理 , 研究进展 , 压电性能 , 铁电性能

Current investigation of doping modification of PZT

Keywords： PZT , mechanism of modification , research progress , piezoelectric property , ferroelectric properties

PZT 作为典型的钙钛矿结构，该结构为掺杂改性提供了较大的自由度。介绍了 PZT 压电材料掺杂改性的研究现状，简明扼要的分析了等价掺杂、高价掺杂、低价掺杂以及复合掺杂对压电材料各项性能的影响。并从掺杂离子对晶体结构和电畴结构影响两方面探讨了 PZT 掺杂改性的机理，进而为复合掺杂改性提供理论基础。

As one of a typical perovskite structure.PZT provide a wide flexibility for doping modification.The paper have introduced the current investigation of PZT-doping modification and briefly analyzed the variation of property which affected by equivalent doping,donor doping,acceptor doping and multiple doping respectively The theory of doping modification has been discussed by two aspects:crystal structure and domain structure effected by doping,which will provide theoretical base of doping.

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