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利用铜模吸铸法制备出直径为3mm的(Fe0.46Co0.36Ni0.04Zr0.14)100-xTax(x=0,4,8,12)非晶合金复合材料柱状试样,通过X射线衍射(XRD)、选区电子衍射(SAED)、振动样品磁强计(VSM)、微机控制电子式万能力学试验机和扫描电镜(SEM)研究了不同Ta含量对合金的磁性能和压缩力学性能的影响.结果表明,随着Ta含量的增加,合金中不断有晶体相Co2Zr、Co2Ta0.5Zr0.5析出,合金的矫顽力Hc呈现出减小的趋势,而合金的饱和磁化强度Ms、抗压强度σbc和弹性应变εe则呈现出先增加后减小的趋势.当x=4时,合金的Ms、σbc和εe均达到最大值,分别为137.70A·m2/kg、1814MPa和4.583%.说明选取合适的Ta含量能够明显改善(Fe0.46Co0.36Ni0.04Zr0.14)100-xTax非晶合金复合材料的磁性能和力学性能.

(Fe0. 46Co0. 36Ni0. 04Zr0. 14)100-xTax(x=0, 4, 8, 12 )amorphous alloy composites rods were prepared by copper mold suction casting.Influences of Ta addition on magnetic properties and mechanical properties of (Fe0.46 Co0.3 6 Ni0.04 Zr0.1 4 )1 00-x Tax amorphous alloy composites were investigated by the means of X-ray diffraction (XRD),selected area electron diffraction(SAED),vibrating sample magnetometer(VSM),the compute con-trolled electronic mechanical testing system and scanning electron microscope (SEM).The results show that some crystal phase Co2 Zr,Co2 Ta0.5 Zr0.5 were separated constantly out with the increase of Ta content,coercivity H c was decreasing and saturation magnetization M s ,compressive strengthσbc ,elastic strainεe were increasing firstly,then decreasing with the increase of Ta content.M s ,σbc,εe reached the maximum value which are 137.70 A·m2/kg,1 814 MPa and 4.583% when x =4.It shows that the suitable Ta content can obviously improve the magnetic and mechanical properties of (Fe0.46 Co0.3 6 Ni0.04 Zr0.1 4 )1 00-x Tax amorphous alloy.

参考文献

[1] Shen BL;Inoue A .Soft magnetic properties of bulk nanocrystalline Fe-Co-B-Si-Nb-Cu alloy with high saturated magnetization of 1.35 T[J].Journal of Materials Research,2004(9):2549-2552.
[2] Akihisa Inoue;Yoshiyuki Shinohara;Jin Seon Gook .Thermal and Magnetic Properties of Bulk Fe-Based Glassy Alloys Prepared by Copper Mold Casting[J].Materials Transactions, JIM,1995(12):1427-1433.
[3] Inoue A;Shen B L;Chang C T .Fe and Co-based bulk glassy alloys with ultrahigh strength of over 4 000 MPa[J].INTERMETALLICS,2006,14(8/9):936-944.
[4] Inoue A;Zhang T;Takeuehi A .Bulk amorphous alloys with high mechanical strength and good soft magnetic properties in Fe-TM-B(TM = Ⅳ-Ⅷ group transition metal)system[J].APPI Phys Lett,1997(71):464-466.
[5] Wang W H;Pan M X;Zhao D Q et al.Enhanced of the soft magnetic properties of FeCoZrMoW bulk metallic glass by microalloying[J].Phys:Condens Mater,2004,1 6(16):307-311.
[6] Poon SJ.;Shiflet GJ.;Guo FQ.;Ponnambalam V. .Glass formability of ferrous- and aluminum-based structural metallic alloys[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(1/2):1-9.
[7] 朱满,李俊杰,坚增运,常芳娥.Fe71Nb6B23非晶薄带的非等温晶化动力学研究[J].稀有金属材料与工程,2012(10):1730-1734.
[8] Ma Liqun;Wang Limin;Zhang Tao .Effect of Zr and Nb elements on glass forming ability of Fe-B alloy[J].ACTA METALLURGICA SINICA,1999,35(06):631-633.
[9] 孙剑飞,黄永江,邢大伟,颜鑫,王刚,沈军.Zr-Cu-Ni-Ta-Al块体非晶合金复合材料的合成及力学性能[J].稀有金属材料与工程,2007(07):1153-1156.
[10] Qikui Man;Huaijun Sun;Yaqiang Dong;Baolong Shen;Hisamichi Kimura;Akihoro Makino;Akihisa Inoue .Enhancement of glass-forming ability of CoFeBSiNb bulk glassy alloys with excellent soft-magnetic properties and superhigh strength[J].Intermetallics,2010(10):1876-1879.
[11] Cohen M H;Grest G S .Liquid-glass transition,a free-volume approach[J].Physical Review B:Condensed Matter,1979(20):1077-1098.
[12] 董丽荣,张立文,左彬,于万秋,华中.Nb添加对Fe-Y-B合金非晶形成能力和磁性能的影响[J].电子元件与材料,2013(06):53-56.
[13] Shen Guidi;Li Jianping;Zhou Chuanwei .Fe-based a-morphous soft magnetic alloy and Its crystallization[J].Journal of Nanjing University of Science and Technolo-gy,1998,22(06):543-547.
[14] Jiles D C .Recent advances and future direction in mag-netic materials[J].ACTA MATERIALIA,2003,5 1(51):5907-5939.
[15] Yan Mi;Peng Xiaoling.Magnetic Foundation And Mag-netic Materials[M].Hangzhou:Zhejiang University Press,2006:114-115.
[16] Zhou Shouzen .Pinning of domain wall and coercivity[J].Instrumental Materials,1980,3(03):64-72.
[17] C. T. Liu;L. Heatherly .Test environments and mechanical properties of Zr-Base bulk amorphous alloys[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,1998(7):1811-1820.
[18] Caron, A.;Zhang, Q.S.;Minkow, A.;Zadorozhnyy, V.A.;Fukuhara, M.;Fecht, H.-J.;Louzguine-Luzgin, D.V.;Inoue, A..Mesostructural effects on the mechanical properties of Zr-based bulk metallic glasses[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2012:57-62.
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