铅合金由于在硫酸体系中稳定性好而广泛应用于湿法冶金电沉积工序。铅合金的耐腐蚀性能不仅影响生产成本,还会影响阴极产品质量,因此耐腐蚀性能是评价铅合金优劣的关键因素。简要综述了铅合金的晶粒尺寸,二次相形貌及分布和轧制对其腐蚀行为的影响。总结了具有理想耐腐蚀性能的铅合金的微观结构的特征,并对铅合金晶界工程和微区腐蚀行为研究提出了展望。
Lead alloys have been widely applied in hydrometallurgical electrowinning industry due to their high stability in H2 SO4 system.Their corrosion resistance not only affects the cost,but also determines the quality of cathode product.Hence,corrosion resistance is a critical factor to evaluate the performance of lead alloys. The effects of grain size,morphology and distribution of second phases,and rolling process on their corrosion behavior are briefly reviewed.The microstructure feature of lead alloys with ideal corrosion resistance is sum-marized,and the prospects of grain boundary engineering and micro-analysis of localized corrosion behavior of lead alloys are also proposed.
参考文献
[1] | M. Clancy;CJ. Bettles;A. Stuart.The influence of alloying elements on the electrochemistry of lead anodes for electrowinning of metals: A review[J].Hydrometallurgy,2013:144-157. |
[2] | H.T. Yang;H.R. Liu;Z.C. Guo.Electrochemical behavior of rolled Pb-0.8%Ag anodes[J].Hydrometallurgy,2013:144-150. |
[3] | Tj andrawan V .The role of manganse in the electrowinning of copper and zinc[D].Perth:Murdoch University,2010. |
[4] | Huaiwei Zhang;Yong Li;Jikun Wang .The influence of nickel ions on the long period electrowinning of zinc from sulfate electrolytes[J].Hydrometallurgy,2009(1/2):127-130. |
[5] | Ivanov I.;Stefanov Y. .Insoluble anodes used in hydrometallurgy Part I. Corrosion resistance of lead and lead alloy anodes[J].Hydrometallurgy,2000(2):109-124. |
[6] | Matthew Tunnicliffe;Farzad Mohammadi;Akram Alfantazi .Polarization Behavior of Lead-Silver Anodes in Zinc Electrowinning Electrolytes[J].Journal of the Electrochemical Society,2012(4):C170-C180. |
[7] | 李宁,黎德育,翟淑芳,仓知三夫,周德瑞.铅阳极的制造方法与性能[J].材料工程,2000(10):36-39. |
[8] | Yu P;O’Keefe T J .Evaluation of lead anode reactions in acid sulfate electrolytesⅡ.manganese reactions[J].Journal of the Electrochemical Society,2002,149(05):A558-A569. |
[9] | Pavlov D;Iordanov N .Growth processes of the anodic crystalline layer on potentiostatic oxidation of lead in sul-furic acid[J].Journal of the Electrochemical Society,1970,117(09):1103-1109. |
[10] | Pavlov D;Dinev Z .Mechanism of the electrochemical oxi-dation of lead to lead dioxide electrode in H2 SO4 solution[J].Journal of the Electrochemical Society,1980,127(04):855-863. |
[11] | Pavlov D .The lead-acid battery lead dioxide active mass:a gel-crystal system with proton and electron conductivi-ty[J].Journal of the Electrochemical Society,1992,139(11):3075-3080. |
[12] | Monahov B;Pavlov D .Hydrated structures in the anodic layer formed on lead electrodes in H2 SO4 solution[J].Journal of Applied Electrochemistry,1993,23(12):1244-1250. |
[13] | Pavlov D;Zanova S;Papazov G .Photoelectrochemical properties of the lead electrode during anodic oxidation in sulfuric acid solution[J].Journal of the Electrochemical Society,1977,124(10):1522-1528. |
[14] | Newnham R H .Corrosion rates of lead based anodes for zinc electrowinning at high current densities[J].Journal of Applied Electrochemistry,1992,22(02):116-124. |
[15] | Ramachandran P;Naganathan K;Balakrishnan K et al.Effect of pretreatment on the anodic behaviour of lead al-loys for use in electrowinning operations[J].Journal of Applied Electrochemistry,1980,10(05):623-626. |
[16] | Ivanov I.;Stefanov Y. .Insoluble anodes used in hydrometallurgy Part II. Anodic behaviour of lead and lead-alloy anodes[J].Hydrometallurgy,2000(2):125-139. |
[17] | Rashkov S T;Stefanov Y;Noncheva Z et al.Investiga-tion of the processes of obtaining plastic treatment and electrochemical behaviour of lead alloys in their capacity as anodes during the electroextraction of zinc Ⅱ.electro-chemical formation of phase layers on binary Pb-Ag and Pb-Ca,and ternary Pb-Ag-Ca alloys in a sulphuric-acid electrolyte for zinc electroextraction[J].Hydrometallur-gy,1996,40(03):319-334. |
[18] | 黄晓旭.金属强度的尺寸效应[J].金属学报,2014(02):137-140. |
[19] | Daniel M. Rosa;Jose E. Spinelli;Wislei R. Osorio .Effects of cell size and macrosegregation on the corrosion behavior of a dilute Pb-Sb alloy[J].Journal of Power Sources,2006(1):696-705. |
[20] | Wislei R. Osorio;Daniel M. Rosa;Amauri Garcia .The roles of cellular and dendritic microstructural morphologies on the corrosion resistance of Pb-Sb alloys for lead acid battery grids[J].Journal of Power Sources,2008(1):595-603. |
[21] | Leandro C. Peixoto;Wislei R. Osorio;Amauri Garcia .Microstructure and electrochemical corrosion behavior of a Pb-1 wt%Sn alloy for lead-acid battery components[J].Journal of Power Sources,2009(2):391-395. |
[22] | Wislei R. Osorio .Comparison of electrochemical performance of as-cast Pb-1 wt.% Sn and Pb-1 wt.% Sb alloys for lead-acid battery components[J].Journal of Power Sources,2010(6):1726. |
[23] | K.D. Ralston;N. Birbilis .Effect of Grain Size on Corrosion A Review[J].Corrosion: The Journal of Science and Engineering,2010(7):075005:1-075005:13. |
[24] | Wenqing Zhang;Aiju Li;Hongyu Chen;Bingyan Lan;Ke Pan;Tianren Zhang;Mingxue Fang;Sanyuan Liu;Wei Zhang .The effect of rare earth metals on the microstructure and electrochemical corrosion behavior of lead calcium grid alloys in sulfuric acid solution[J].Journal of Power Sources,2012(Apr.1):145-152. |
[25] | Petrova M;Noncheva Z;Dobrev T et al.Investigation of the processes of obtaining plastic treatment and elec-trochemical behaviour of lead alloys in their capacity as anodes during the electroextraction of zinc Ⅰ.behaviour of Pb-Ag,Pb-Ca and Pb-Ag-Ca alloys[J].Hydrometal-lurgy,1996,40(03):293-318. |
[26] | Prengaman R D .Challenges from corrosion-resistant grid al-loys in lead acid battery manufacturing[J].Journal of Power Sources,2001,95(01):224-233. |
[27] | Li Dangguo;Zhou Genshu;Yao Liang .Mechanical prop-erties and corrosion performance of a novel Pb-Ca-RE al-loy[J].Corrosion science and protection technology,2006,18(02):95-97. |
[28] | 杨习文,唐有根,舒宏,申建斌.添加富铈稀土对低锑合金结构及电化学性能的影响[J].中国有色金属学报,2006(10):1817-1822. |
[29] | Mao Weimin;Zhu Jingchuan;Li Jian.The struc-ture and properties of metallic materials[M].Beij ing:Tsinghua Unviersity Press,2008:252. |
[30] | Rand D A J;Boden D P;Lakshmi C S et al.Manufac-turing and operational issues with lead-acid batteries[J].Journal of Power Sources,2002,107(02):280-300. |
[31] | C. Camurri;C. Carrasco;O. Prat .Study of precipitation hardening in lead calcium tin anodes for copper electrowinning[J].Materials Science and Technology: MST: A publication of the Institute of Metals,2010(2):210-214. |
[32] | H. Li;W.X. Guo;H.Y. Chen;D.E. Finlow;H.W. Zhou;C.L. Dou;G.M. Xiao;S.G. Peng;W.W. Wei;H. Wang .Study on the microstructure and electrochemical properties of lead-calcium-tin-aluminum alloys[J].Journal of Power Sources,2009(1):111-118. |
[33] | Yan-Bao Zhou;Chun-Xiao Yang;Wei-Fang Zhou .Comparison of Pb-Sm-Sn and Pb-Ca-Sn alloys for the positive grids in a lead acid battery[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2004(1/2):108-111. |
[34] | Yan-Bao Zhou;Hou-Tian Liu;Wen-Bin Cai .A Lead-Tin-Rare Earth Alloy for VRLA Batteries[J].Journal of the Electrochemical Society,2004(7):A978-A982. |
[35] | Hou-Tian Liu;Xin-Hua Zhang;Yan-bao Zhou .The anodic films on lead alloys containing rare-earth elements as positive grids in lead acid battery[J].Materials Letters,2003(29):4597-4600. |
[36] | Hong Bo .The properties of lead-based rare earth alloy anode for zinc electrodeposition[D].Changsha:Central South University,2010. |
[37] | Jiang Liangxing .Foundamentals and key techniques for preparation and application of composite porous lead-al-loy anode in hydrometallurgy[D].Changsha:Central South University,2012. |
[38] | Zhong X C;Gui J F;Yu X Y et al.Influence of alloying element Nd on the electrochemcial behavior of Pb-Ag an-ode in H2 SO4 solution[J].Acta Physico-Chimica Sinica,2014,30(03):492-499. |
[39] | 洪波,蒋良兴,吕晓军,倪恒发,赖延清,李劼,刘业翔.Nd对锌电积用Pb-Ag合金阳极性能的影响[J].中国有色金属学报,2012(04):1126-1131. |
[40] | Wislei R.Osorio;Emmanuelle S. Freitas;Leandro C. Peixoto;JoseE. Spinelli;Amauri Garcia .The effects of tertiary dendrite arm spacing and segregation on the corrosion behavior of a Pb-Sb alloy for lead-acid battery components[J].Journal of Power Sources,2012(Jun.1):183-190. |
[41] | Matthew Tunnicliffe;Farzad Mohammadi;Akram Alfantazi .Polarization Behavior of Lead-Silver Anodes in Zinc Electrowinning Electrolytes[J].Journal of the Electrochemical Society,2012(4):C170-C180. |
[42] | Monahov B;Pavlov D;Petrov D .Influence of Ag as al-loy additive on the oxygen evolution reaction on Pb/PbO2 electrode[J].Journal of Power Sources,2000,85(01):59-62. |
[43] | N.E. Bagshaw .Lead alloys: past, present and future[J].Journal of Power Sources,1995(1):25-30. |
[44] | Wislei R. Osorio;Daniel M. Rosa;Amauri Garcia .Electrolyte features and microstructure affecting the electrochemical performance of a Pb-Sb alloy for lead-acid battery components[J].Electrochimica Acta,2011(24):8457-8462. |
[45] | Osório W R;Rosa D M;Garcia A .Electrochemical be-haviour of a Pb-Sb alloy in 0.5 mol/L NaCl and 0.5 mol/L H2 SO4 solutions[J].Materials and Design,2012,34:660-665. |
[46] | Wislei R. Osorio .Comparison of electrochemical performance of as-cast Pb-1 wt.% Sn and Pb-1 wt.% Sb alloys for lead-acid battery components[J].Journal of Power Sources,2010(6):1726. |
[47] | Cao J;Zhao H;Cao F et al.The influence of F-doping on the activity of PbO2 film electrodes in oxygen evolu-tion reaction[J].Electrochimica Acta,2007,52(28):7870-7876. |
[48] | Mattesco P;Bui N;Simon P et al.Effect of polarisati-on mode,time and potential on the properties of the pas-sive layer on lead-tin alloys[J].Journal of Power Sources,1997,64(01):21-27. |
[49] | Taguchi M;Hirasawa T;Wada K .Corrosion behavior of Pb-Sn and Pb-2mass% Sn-Sr alloys during repetitive current application[J].Journal of Power Sources,2006,158(02):1456-1462. |
[50] | Lupi C;Pilone D .New lead alloy anodes and organic de-polariser utilization in zinc electrowinning[J].Hydro-metallurgy,1997,44(03):347-358. |
[51] | Tripathy B C;Das S C;Hefter G T et al.Zinc electro-winning from acidic sulfate solutions:part Ⅰ:effects of sodium lauryl sulfate[J].Journal of Applied Electro-chemistry,1997,27(06):673-678. |
[52] | 何捍卫,胡岳华,周科朝,熊翔.铜在甲胺-铁氰化钾化学机械抛光液中的腐蚀与钝化[J].功能材料,2004(03):392-394. |
[53] | M.A. Kiani;M.F. Mousavi;S. Ghasemi;M. Shamsipur;S.H. Kazemi .Inhibitory effect of some amino acids on corrosion of Pb-Ca-Sn alloy in sulfuric acid solution[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2008(4):1035-1045. |
[54] | Lehockey E M;Palumbo G;Lin P et al.On the rela-tionship between grain boundary character distribution and intergranular corrosion[J].Scripta Materialia,1997,36(10):1211-1218. |
[55] | E.M. Lehockey;D. Limoges;G. Palumbo .On improving the corrosion and growth resistance of positive Pb-acid battery grids by grain boundary engineering[J].Journal of Power Sources,1999(1/2):79-83. |
[56] | Lee DS.;Ryoo HS.;Hwang SK. .A grain boundary engineering approach to promote special boundaries in Pb-base alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2003(1/2):106-111. |
[57] | Xia Shuang;Zhou Bangxing;Chen Wenjie.Evolu-tion of grain boundary character distributions in Pb alloy during high temperature annealing[J].Acta Metallurgica |
[58] | 张欣,王卫国,郭红,姜英.固溶和预时效Pb合金冷轧退火后的晶界特征分布[J].金属学报,2007(05):454-458. |
[59] | 张欣,王卫国,郭红,姜英.固溶和预时效Pb合金冷轧退火后的晶界特征分布[J].金属学报,2007(05):454-458. |
[60] | Schmachtel, S;Pust, SE;Kontturi, K;Forsen, O;Wittstock, G .New oxygen evolution anodes for metal electrowinning: investigation of local physicochemical processes on composite electrodes with conductive atomic force microscopy and scanning electrochemical microscopy[J].Journal of Applied Electrochemistry,2010(3):581-592. |
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