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采用共沉淀法制备了氢氧化镍/还原氧化石墨烯复合材料,并以此为电极研究了其超级电容性能.实验发现,六方氢氧化镍纳米片被成功插入到还原氧化石墨烯的层间,这有效抑制了还原氧化石墨烯和氢氧化镍的团聚,提高了电极的稳定性.当氢氧化镍和还原氧化石墨烯的质量比为5.5∶1时,显示了最佳的电化学性能:在-0.1~0.37 V 的电位窗口,1 A/g 的电流密度下,比电容高达1036 F/g;4 A/g 的电流密度下快速循环3000次后,仍然保持70%的比电容.

In this paper,composites of Ni(OH)2/reduced graphene oxides (rGO)were prepared by chemical co-precipitation method,by which Ni(OH)2 hexagonal nanoplates were successfully inserted into the layers of re-duced graphene oxides.As a result,the aggregation of rGO and Ni(OH)2 is efficiently prevented and the stabili-ty of the composites are also improved.The electrochemical performance of Ni(OH)2/rGO is further investiga-ted as electrode materials for supercapacitors.We find that when the mass ratio of Ni(OH)2 to rGO is 5.5∶1, the composites achieve the best electrochemical performance (optimal specific capacitance of 1 036 F/g has been achieved at a current density of 1 A/g).In addition,the value of capacitance retention is above 70% after 3 000 cycles at the current density of 4 A/g.

参考文献

[1] Conway B E.Electrochemical supercapacitors:scientific fundamentals and technological applications[M].Kluw-er:Springer,1 9 9 9
[2] US department of energy .basic research needs for electri-cal energy storage[EB/OL].www.sc.doe.gov/bes/re-ports/abstracts.html#EES2007
[3] 袁美蓉,赵方辉,刘伟强,朱永法,王臣.超级电容器用石墨烯极片的制备和性能[J].功能材料,2013(19):2810-2813,2818.
[4] Chae HK;Siberio-Perez DY;Kim J;Go Y;Eddaoudi M;Matzger AJ .A route to high surface area, porosity and inclusion of large molecules in crystals[J].Nature,2004(6974):523-527.
[5] Lokhande, C.D.;Dubal, D.P.;Joo, O.-S. .Metal oxide thin film based supercapacitors[J].Current applied physics: the official journal of the Korean Physical Society,2011(3):255-270.
[6] Yang GW;Xu CL;Li HL .Electrodeposited nickel hydroxide on nickel foam with ultrahigh capacitance[J].Chemical communications,2008(48):6537-6539.
[7] Jie Chang;Huan Xu;Jing Sun .High pseudocapacitance material prepared via in situ growth of Ni(OH)2 nanoflakes on reduced graphene oxide[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(22):11146-11150.
[8] 朱振峰,程莎,董晓楠.石墨烯的制备和应用[J].功能材料,2013(21):3060-3064,3071.
[9] Zhipeng Sun;Xianmao Lu .A Solid-State Reaction Route to Anchoring Ni(OH)_2 Nanoparticles on Reduced Graphene Oxide Sheets for Supercapacitors[J].Industrial & Engineering Chemistry Research,2012(30):9973-9979.
[10] Xie, J.;Sun, X.;Zhang, N.;Xu, K.;Zhou, M.;Xie, Y. .Layer-by-layer Β-Ni(OH)_2/graphene nanohybrids for ultraflexible all-solid-state thin-film supercapacitors with high electrochemical performance[J].Nano Energy,2013(1):65-74.
[11] Hummers W;Offeman R .Preparation of graphite oxide[J].Journals of American Chemical Society,1958,80:1339-1339.
[12] Li Z Q;Lu C J;Xia Z P et al.X-ray diffraction pat-terns of graphite and turbostratic carbon[J].CARBON,2005,45:1686-1695.
[13] Yong Wang;Qingshan Zhu;Huigang Zhang .Fabrication of β-Ni(OH)_2 and NiO hollow spheres by a facile template-free process[J].Chemical communications,2005(41):5231-5233.
[14] Xu, YX;Bai, H;Lu, GW;Li, C;Shi, GQ .Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets[J].Journal of the American Chemical Society,2008(18):5856-5857.
[15] 彭黎琼,谢金花,郭超,张东.石墨烯的表征方法[J].功能材料,2013(21):3055-3059.
[16] Fu G R;Hu Z A;Xie L J et al.Electrodeposition of nickel hydroxide films on nickel foil and its electrochem-ical performances for supercapacitor[J].International Journal of Electrochemical Science,2009,4:1052-1062.
[17] Shen, J.;Shi, M.;Li, N.;Yan, B.;Ma, H.;Hu, Y.;Ye, M. .Facile synthesis and application of Ag-chemically converted graphene nanocomposite[J].Nano Research,2010(5):339-349.
[18] Wehrens-Dijksma M;Notten P H L .Electrochemical quartz microbalance characterization of Ni(OH)2-based thin film electrodes[J].Electrochimica Acta,2006,51:3609-3621.
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