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气凝胶是一种新型的纳米多孔材料,以其孔隙率高、密度低、比表面积大等独特的性能受到人们广泛的关注。这些优异的性能使得气凝胶在声阻抗耦合、高效保温隔热、催化剂及其载体航空航天等方面拥有非常广泛的应用前景。阐述了气凝胶的低成本制备及常压干燥技术,介绍了气凝胶在建筑保温隔热领域的应用现状和发展前景,并且分析了其与主流建筑保温隔热材料的优劣。

Because of its unique properties,such as high porosity,low density,high specific surface area,aero-gels have been widely concerned as a new type of nanoporous materials.These excellent properties allow aero-gels have extensive application prospects in acoustic impedance coupling,efficient thermal insulation,catalyst, aeronautics and astronautics,etc.In this paper,the low-cost preparation of aerogels and ambient pressure dr-ying technology are studies,and the application status and prospects of aerogels in the field of building thermal insulation are introduced,and the advantages and disadvantages of aerogels compared to mainstream building thermal insulation materials are analyzed.

参考文献

[1] Fricke J;Emmerling A .Aerogels-preparation,properties,application[J].Chemistry Spectroscopy and Application of Sol-Gel Glasses Structure and Bonding,1992,77:37-38.
[2] Wang Jue .Lightweight nanoporous material-aerogels[J].Materials Review,1993,2:36-38.
[3] Shen Jun;Wang Jue;Wu Xiang .Aerogels-a type of structure controllable new functional materials[J].Materi-als Science and Engineering,1994,12(03):1-5.
[4] Carlson G;Lewis D;McKinley K et al.Aerogel commer-cialization:technology,markets and costs[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1995,186:372-387.
[5] Smith DM.;Boes U.;Maskara A. .Aerogel-based thermal insulation[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1):254-259.
[6] Fricke J;Emmerling A .Aerogels-recent progress in pro-duction techniques and novel applications[J].Sol-Gel Sci Technol,1998,13:299-303.
[7] Schmidt M.;Schwertfeger F. .Applications for silica aerogel products[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1):364-368.
[8] Herrmann G;Iden R;Mielke M et al.On the way to com-mercial production of silica aerogel[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1995,186:380-387.
[9] Wang Jue;Shen Jun .Investigation and application of or-ganic aerogels and carbon aerogels[J].Materials Review,1994,4:54-57.
[10] Shen Jun;Wang Jue;Wu Xiang et al.Study on structure controlling of silica aerogels[J].Materials Science and Technology,1994,2(04):88-93.
[11] Shen Jun;Wang Jue;Wu Xiang .The structure investiga-tion of silica aerogels via small angle X-ray scattering[J].Journal of Inorganic Materials,1996,11(04):753-756.
[12] Reim M;Reichenauer G;Korner W;Manara J;Arduini-Schuster M;Korder S;Beck A;Fricke J .Silica-aerogel granulate - Structural, optical and thermal properties[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2004(0):358-363.
[13] Gesser H D;Goswami P C .Aerogels and related porous materials[J].Chemical Reviews,1989,89:765-788.
[14] Nicola Husing;Ulrich Schubert .Aerogels-airy materials: chemistry, structure, and properties[J].Angewandte Chemie International Edition,1998(1/2):22-45.
[15] A. Soleimani Dorcheh;M. H. Abbasi .Silica aerogel; synthesis, properties and characterization[J].Journal of Materials Processing Technology,2008(1-3):10-26.
[16] Fei Shi;Lijiu Wang;Jingxiao Liu .Synthesis and characterization of silica aerogels by a novel fast ambient pressure drying process[J].Materials Letters,2006(29/30):3718-3722.
[17] 陈一民,洪晓斌,赵大方,谢凯,肖加余.常压制备玻璃基疏水SiO2气凝胶[J].化工新型材料,2005(08):21-23.
[18] 陈一民,赵大方,谢凯,肖加余.制备条件对疏水SiO2气凝胶结构和性能的影响[J].硅酸盐学报,2005(06):727-731.
[19] Schwertfeger F.;Schmidt M.;Frank D. .Hydrophobic waterglass based aerogels without solvent exchange or supercritical drying[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1):24-29.
[20] Lee C J;Kim G S;Hyun S H .Synthesis of silica aerogels from waterglass via new modified ambiet drying[J].Ma-ter Science,2000,37:2237-2241.
[21] Nayak;Bera .Prepararation of silica aerogel by ambient pressure drying process using rice husk ash as raw mate-rial[J].Transactions of the Indian Ceramic Society,2009,68:91-94.
[22] 侯贵华.稻壳裂解制备SiO2气凝胶的研究[J].无机材料学报,2003(02):407-412.
[23] Deng Zhongsheng;Wang Jue;Wei Jiandong et al.Physi-cal properties of the silica aerogels prepared with polye-thoxydisiloxanes[J].Journal of Sol-Gel Science and Technology,2000,1 9:677-680.
[24] 沈军,王际超,倪星元,王博,王晓栋,张志华.以水玻璃为源常压制备高保温二氧化硅气凝胶[J].功能材料,2009(01):149-151,158.
[25] Wang W Q;Zhang Z H;Zu G Q et al.Low-cost prepara-tion of silica aerogel[P].China:CN102992333A,2013-03-27.
[26] Wang W Q;Zhang Z H;Zu G Q et al.Low-cost prepara-tion of aerogel or fiber composite aerogel in a water con-ditions[P].China:CN103204666A,2013-07-17.
[27] Shen J;Wang W Q;Zhang Z H et al.Low-cost prepara-tion of silica aerogel under pure water system[P].China:CN103496707A,2014-01-08.
[28] ten Brink S. .Convergence of iterative decoding[J].Electronics Letters,1999(10):806-808.
[29] Tewari P H;Lofftus K D;Hunt A J.In structure and chemistry of sol-gel derived transparent silica aerogel[M].New York:Wiley Interscience Publications,1985:17-18.
[30] 史非,王立久,刘敬肖,曾淼.介孔SiO2气凝胶的常压干燥制备研究[J].无机化学学报,2005(11):1632-1636.
[31] Rao AV.;Kulkarni MM.;Amalnerkar DP.;Seth T. .Surface chemical modification of silica aerogels using various alkyl-alkoxy/chloro silanes[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):262-270.
[32] Land VD.;Teeters DC.;Harris TM. .Processing of low-density silica gel by critical point drying or ambient pressure drying[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2001(1/3):11-17.
[33] Lenza RFS.;Vasconcelos WL. .Study of the influence of some DCCAs on the structure of sol-gel silica membranes[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(1/3):216-225.
[34] Rao AV.;Kulkarni MM. .Effect of glycerol additive on physical properties of hydrophobic silica aerogels[J].Materials Chemistry and Physics,2003(3):819-825.
[35] Shajesh, P.;Smitha, S.;Aravind, P.R.;Warrier, K.G.K. .Synthesis, structure and properties of cross-linked R(SiO_(1.5))/SiO_2 (R = 3-glycidoxypropyl) porous organic inorganic hybrid networks dried at ambient pressure[J].Journal of Colloid and Interface Science,2009(2):691-697.
[36] Land VD.;Teeters DC.;Harris TM. .Processing of low-density silica gel by critical point drying or ambient pressure drying[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2001(1/3):11-17.
[37] 吴国友,程璇,余煜玺,张颖.常压干燥制备二氧化硅气凝胶[J].化学进展,2010(10):1892-1900.
[38] Gan Lihua;Chen Longwu;Zhang Yuxing .Preparation of silica aerogels by non-surpercritical drying[J].Acta Physico-Chimica Sinica,2003,1 9(06):504-508.
[39] YOUNG-GEUN KWON;SE-YOUNG CHOI;EUL-SON KANG .Ambient-dried silica aerogel doped with TiO_(2) powder for thermal insulation[J].Journal of Materials Science,2000(24):6075-6079.
[40] Schwertfeger F.;Schmidt M.;Frank D. .Hydrophobic waterglass based aerogels without solvent exchange or supercritical drying[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1):24-29.
[41] Zhang G;Liu M .Prepararation of nanostructured tin ox-ide using a sol-gel process based on tin terrachloride and ethylene glycol[J].Mater Science,1999,34:3213-3219.
[42] 何蕊,刘振法.新型碳气凝胶的制备及表征[J].河北科技大学学报,2013(01):26-29.
[43] Einarsrud MA.;Nilsen E. .Strengthening of water glass and colloidal sol based silica gels by aging in TEOS[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1/2):122-128.
[44] Rolison DR.;Dunn B. .Electrically conductive oxide aerogels: new materials in electrochemistry [Review][J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2001(4):963-980.
[45] Haereid S;Dahle M;Lima S et al.Preparation and prop-erties of monolithic silica xerogels from TEOS-based al-cogels aged in silane solutions[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1995,186:96-103.
[46] Haereid S;Nilsen E;Einarsrud M A .Properties of silica gels aged in TEOS[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1996,204(03):228-234.
[47] Haereid S;Anderson J;Einarsrud M A et al.Thermal and temporal aging of TMOS-based aerogel precursors in water[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1995,185(03):221-226.
[48] Fang He;Hailei Zhao;Xuanhui Qu;Cuijuan Zhang;Weihua Qiu .Modified aging process for silica aerogel[J].Journal of Materials Processing Technology,2009(3):1621-1626.
[49] Schwertfeger F.;Schmidt M.;Frank D. .Hydrophobic waterglass based aerogels without solvent exchange or supercritical drying[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1):24-29.
[50] Prakash S S;Brinker C J;Hurd A J .Silica aerogel films at ambient pressure[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1995,190(03):264-275.
[51] Deshpande R;Hua D W;Smith D M et al.Pore structure evolution in silica gel during aging/drying.Ⅲ.Effects of sur-face tension[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1992,144:32-44.
[52] Sharad D. Bhagat;Yong-Ha Kim;Kuen-Hack Suh .Superhydrophobic silica aerogel powders with simultaneous surface modification, solvent exchange and sodium ion removal from hydrogels[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2008(1/3):504-509.
[53] Jyoti L. Gurav;A. Venkateswara Rao;A. Parvathy Rao .Physical properties of sodium silicate based silica aerogels prepared by single step sol-gel process dried at ambient pressure[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):397-402.
[54] Shlyakhtina A;Oh YJ .Transparent SiO2 aerogels prepared by ambient pressure drying with ternary azeotropes as components of pore fluid[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2008(15/16):1633-1642.
[55] Shen J;Zhang Z H;Wu G M et al.Preparation and char-acterization of silica aerogels derived from ambient pres-sure[J].Mater Sci Techno,2006,22(06):798-802.
[56] Zhou B;Shen J;Wu YH;Wu GM;Ni XY .Hydrophobic silica aerogels derived from polyethoxydisiloxane and perfluoroalkylsilane[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2007(5/8):1291-1294.
[57] 沈军,汪国庆,王珏,邓忠生.SiO2气凝胶的常压制备及其热传输特性[J].同济大学学报(自然科学版),2004(08):1106-1110.
[58] Ni Xingyuan;Zhang Zhihua;Huang Yaodong et al.Prep-aration of nanoporous SiO 2 aerogels at ambient pressure[J].Journal of Functional Materials,2004,35:2761-2763.
[59] Zu Guoqing;Shen Jun;Ni Xingyuan et al.Preparation of elastic aerogels at ambient presurre[J].Journal of Func-tional Materials,2011,42(01):151-154.
[60] Huang Dongxia .Effect of building outside window on building energy efficiency[J].Energy and Environment,2008,2(04):99-100.
[61] Wang H;Wu H J;Ding Y F .Advance in the study and appplication of aerogels as translucent insulation materi-als in building energy-saving glass[J].Building Energy Efficient,2010,230(04):35-37.
[62] M. Reim;A. Beck;W. Korner;R. Petricevic;M. Glora;M. Weth;T. Schliermann;J. Fricke;Ch. Schmidt;F. J. Potter .Highly insulating aerogel glazing for solar energy usage[J].Solar Energy,2002(1):21-29.
[63] K. Balkis Ameen;K. Rajasekar;T. Rajasekharan .The effect of heat-treatment on the physico-chemical properties of silica aerogel prepared by sub-critical drying technique[J].Journal of Sol-Gel Science and Technology,2008(1):9-15.
[64] Bahaj A S;James P A;Jentsch M F .Potential of energing glazing technologies for highly glazed buildings in hot arid climates[J].Energy and Buildings,2008,40(05):720-731.
[65] Buratti C;Moretti E .Glazing systems with silica aerogel for energy saving in buildings[J].Applied Energy,2012,98:396-403.
[66] 董文辉.SiO2纳米孔超级绝热材料[J].中国非金属矿工业导刊,2006(02):10-13.
[67] Wang Jun .Aerogel new plate[J].Insulation Materials and Building Energy Saving,2004,9(07):40-44.
[68] Aegerter M A;Leventis N;Koebel M M.Aerogels Hand-book[M].Berlin:Springer-Verlag New York Inc,2011:864-876.
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