碳量子点(CQDs,C-dots or CDs)是一种新型的碳纳米材料,尺寸在10 nm以下,具有良好的水溶性、化学惰性、低毒性、易于功能化和抗光漂白性、光稳定性等优异性能,是碳纳米家族中的一颗闪亮的明星。自从2006年[1]报道了碳量子点(CQDs)明亮多彩的发光现象后,世界各地的研究小组开始对 CQDs 进行了深入的研究。最近几年的研究报道了各种方法制备的CQDs在生物医学、光催化、光电子、传感等领域中都有重要的应用价值。这篇综述主要总结了关于 CQDs的最近的发展,介绍了 CQDs 的合成方法、表面修饰、掺杂、发光机理、光电性质以及在生物医学、光催化、光电子、传感等领域的应用。
Carbon quantum dots (CQDs,C-dots or CDs),a new type of carbon materials,less than 10 nm in size,have a lot of excellent performance,such as superior solubility in water,chemical inertness,low toxicity, easy functionalization,resistance to photobleaching and good photostability,having attracted widespread atten-tion as a rising star in nanocarbon family in recent years.Since the phenomenon of bright colorful light from car-bon quantum dots was reported in 2006,research groups around the world have begun to investigate the carbon quantum dots.CQDs produced from various synthetic strategies find their wide values in more and more fields, especially in biomedicine,optoeletronics,catalysis and sensors.In this review,we describe the recent progress in the field of CQDs,focusing on their synthetic methods,size control,modification strategies,photoelectric properties,luminescent mechanism,and applications in biomedicine,optoelectronics,catalysis and sensor is-sues.
参考文献
| [1] | Ya-Ping Sun;Bing Zhou;Yi Lin;Wei Wang;K.A.Shiral Fernando .Quantum-Sized Carbon Dots for Bright and Colorful Photoluminescence[J].Journal of the American Chemical Society,2006(24):7756-7757. |
| [2] | Xu X Y;Ray R;Gu Y L et al.Electrophoretic analysis and purification of fluorescent single-walled carbon nano-tube ragments[J].Journal of the American Chemical Society,2004,126(40):12735-12737. |
| [3] | Haipeng Liu;Tao Ye;Chengde Mao .Fluorescent Carbon Nanoparticles Derived from Candle Soot[J].Angewandte Chemie,2007(34):6473-6475. |
| [4] | Lei Tian;Debraj Ghosh;Wei Chen .Nanosized Carbon Particles From Natural Gas Soot[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(13):2803-2809. |
| [5] | Jigang Zhou;Christina Booker;Ruying Li .An Electrochemical Avenue to Blue Luminescent Nanocrystals from Multiwalled Carbon Nanotubes (MWCNTs)[J].Journal of the American Chemical Society,2007(4):744-745. |
| [6] | Haitao Li;Xiaodie He;Zhenhui Kang .Water-Soluble Fluorescent Carbon Quantum Dots and Photocatalyst Design[J].Angewandte Chemie,2010(26):4430-4434. |
| [7] | Li, X.;Wang, H.;Shimizu, Y.;Pyatenko, A.;Kawaguchi, K.;Koshizaki, N. .Preparation of carbon quantum dots with tunable photoluminescence by rapid laser passivation in ordinary organic solvents[J].Chemical communications,2011(3):932-934. |
| [8] | Sheng-Liang Hu;Kai-Yang Niu;Jing Sun .One-step synthesis of fluorescent carbon nanoparticles by laser irradiation[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(4):484-488. |
| [9] | Ya-Ping Sun;Bing Zhou;Yi Lin;Wei Wang;K.A.Shiral Fernando .Quantum-Sized Carbon Dots for Bright and Colorful Photoluminescence[J].Journal of the American Chemical Society,2006(24):7756-7757. |
| [10] | Zhu, H;Wang, XL;Li, YL;Wang, ZJ;Yang, F;Yang, XR .Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence properties[J].Chemical communications,2009(34):5118-5120. |
| [11] | Songnan Qu;Xiaoyun Wang;Qipeng Lu .A Biocompatible Fluorescent Ink Based on Water-Soluble Luminescent Carbon Nanodots[J].Angewandte Chemie,2012(49):12215-12218. |
| [12] | Sahu S;Behera B;Maiti T K et al.Simple one-step synthesis of highly luminescent carbon dot from orange j uice:application as excellent bio-imaging agents[J].Chemical Communications,2012,48(70):8835-8837. |
| [13] | Jumeng Wei;Xin Zhang;Yingzhuo Sheng .Simple one-step synthesis of water-soluble fluorescent carbon dots from waste paper[J].New Journal of Chemistry,2014(3):906-909. |
| [14] | Jia G;Wang HF;Yan L;Wang X;Pei RJ;Yan T;Zhao YL;Guo XB .Cytotoxicity of carbon nanomaterials: Single-wall nanotube, multi-wall nanotube, and fullerene[J].Environmental Science & Technology: ES&T,2005(5):1378-1383. |
| [15] | 碳纳米材料/树状大分子复合材料研究进展[J].功能材料,2014(13):13001-13005. |
| [16] | Niu J J;Gao H;Wang L T et al.Facile synthesis and optical properties of nitrogen-doped carbon dots[J].New Journal of Chemistry,2014,38(04):1522-1527. |
| [17] | Chuanfu Wang;Xia Wu;Xiangping Li .Upconversion fluorescent carbon nanodots enriched with nitrogen for light harvesting[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(31):15522-15525. |
| [18] | Sunita Dey;Pallellappa Chithaiah;Sunita Belawadi;Kanishka Biswas;C.N.R. Rao .New methods of synthesis and varied properties of carbon quantum dots with high nitrogen content[J].Journal of Materials Research,2014(3):383-391. |
| [19] | Dong S;Rui B;Zhang P H.Hair fiber as a pre-cursor for synthesizing of sulfur-and nitrogen-co-doped carbon dot with tunable luminescence properties[J].Car-bon,2013(64):424-426. |
| [20] | Zhou J;Shan X Y;Ma J J et al.Facile synthesis of P-doped carbon quantum dots with highly efficient photo-luminescence[J].RSC Adv,2014,4(11):5465-5468. |
| [21] | Zhang, H.;Ming, H.;Lian, S.;Huang, H.;Li, H.;Zhang, L.;Liu, Y.;Kang, Z.;Lee, S.-T. .Fe_2O_3/carbon quantum dots complex photocatalysts and their enhanced photocatalytic activity under visible light[J].Dalton transactions: An international journal of inorganic chemistry,2011(41):10822-10825. |
| [22] | Ma S;Xue J;Zhou Y et al.A facile route for the prep-aration of ZnO/C composites with high photocatalytic activity and adsorption capacity[J].Cryst Eng Comm,2014,16(21):4478-4484. |
| [23] | Haitao Li;Xiaodie He;Zhenhui Kang .Water-Soluble Fluorescent Carbon Quantum Dots and Photocatalyst Design[J].Angewandte Chemie,2010(26):4430-4434. |
| [24] | Jing Wang;Minmin Gao;Ghim Wei Ho .Bidentate-complex-derived TiO2/carbon dot photocatalysts: in situ synthesis, versatile heterostructures, and enhanced H2 evolution[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,2014(16):5703-5709. |
| [25] | Jie Zong;Xiaoling Yang;Adrian Trinchi .Photoluminescence enhancement of carbon dots by gold nanoparticles conjugated via PAMAM dendrimers[J].Nanoscale,2013(22):11200-11206. |
| [26] | Zheng, LY;Chi, YW;Dong, YQ;Lin, JP;Wang, BB .Electrochemiluminescence of Water-Soluble Carbon Nanocrystals Released Electrochemically from Graphite[J].Journal of the American Chemical Society,2009(13):4564-4566. |
| [27] | Xu, Y.;Wu, M.;Feng, X.-Z.;Yin, X.-B.;He, X.-W.;Zhang, Y.-K. .Reduced carbon dots versus oxidized carbon dots: Photo- and electrochemiluminescence investigations for selected applications[J].Chemistry: A European journal,2013(20):6282-6288. |
| [28] | Xiaofang Jia;Jing Li;Erkang Wang .One-pot green synthesis of optically pH-sensitive carbon dots with upconversion luminescence[J].Nanoscale,2012(18):5572-5575. |
| [29] | 赵腾腾,刘平,陈小红,刘新宽,李伟,马凤仓,何代华.Cu/CNTs 复合粉末制备工艺研究[J].功能材料,2014(07):7143-7147. |
| [30] | Tang, L.;Ji, R.;Cao, X.;Lin, J.;Jiang, H.;Li, X.;Teng, K.S.;Luk, C.M.;Zeng, S.;Hao, J.;Lau, S.P. .Deep ultraviolet photoluminescence of water-soluble self-passivated graphene quantum dots[J].ACS nano,2012(6):5102-5110. |
| [31] | Haitao Li;Xiaodie He;Zhenhui Kang .Water-Soluble Fluorescent Carbon Quantum Dots and Photocatalyst Design[J].Angewandte Chemie,2010(26):4430-4434. |
| [32] | Sheng-Liang Hu;Kai-Yang Niu;Jing Sun .One-step synthesis of fluorescent carbon nanoparticles by laser irradiation[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(4):484-488. |
| [33] | Fang, Y.;Guo, S.;Li, D.;Zhu, C.;Ren, W.;Dong, S.;Wang, E. .Easy synthesis and imaging applications of cross-linked green fluorescent hollow carbon nanoparticles[J].ACS nano,2012(1):400-409. |
| [34] | Sheila N. Baker;Gary A. Baker .Luminescent Carbon Nanodots: Emergent Nanolights[J].Angewandte Chemie,2010(38):6726-6744. |
| [35] | Wang L;Zhu S J;Wang H Y et al.Common origin of green luminescence in carbon nanodots and graphene quantum dots[J].ACS Nano,2014,8(03):2541-2547. |
| [36] | S. C. Ray;Arindam Saha;Nikhil R. Jana .Fluorescent Carbon Nanoparticles: Synthesis, Characterization, and Bioimaging Application[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(43):18546-18551. |
| [37] | Yang, ST;Cao, L;Luo, PGJ;Lu, FS;Wang, X;Wang, HF;Meziani, MJ;Liu, YF;Qi, G;Sun, YP .Carbon Dots for Optical Imaging in Vivo[J].Journal of the American Chemical Society,2009(32):11308-11309. |
| [38] | Sheng-Tao Yang;Xin Wang;Haifang Wang .Carbon Dots as Nontoxic and High-Performance Fluorescence Imaging Agents[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(42):18110-18114. |
| [39] | Cao L;Wang X;Meziani MJ;Lu FS;Wang HF;Luo PJG;Lin Y;Harruff BA;Veca LM;Murray D .Carbon dots for multiphoton bioimaging[J].Journal of the American Chemical Society,2007(37):11318-11319. |
| [40] | Lu Q;Moore J M;Huang C;el al .RNA polvmer trans-location with single-walled carbon nanotubes[J].Nano Letters,2004,4(12):2473-2477. |
| [41] | LIU LiQin,LI YuanFang,ZHAN Lei,LIU Yue,HUANG ChengZhi.One-step synthesis of fluorescent hydroxyls-coated carbon dots with hydrothermal reaction and its application to optical sensing of metal ions[J].中国科学:化学（英文版）,2011(08):1342-1347. |
| [42] | Zhu, S.;Zhang, J.;Qiao, C.;Tang, S.;Li, Y.;Yuan, W.;Li, B.;Tian, L.;Liu, F.;Hu, R.;Gao, H.;Wei, H.;Zhang, H.;Sun, H.;Yang, B. .Strongly green-photoluminescent graphene quantum dots for bioimaging applications[J].Chemical communications,2011(24):6858-6860. |
| [43] | Qin Li;Tymish Y. Ohulchanskyy;Ruili Liu .Photoluminescent Carbon Dots as Biocompatible Nanoprobes for Targeting Cancer Cells in Vitro[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(28):12062-12068. |
| [44] | Felix Neugart;Andrea Zappe;Fedor Jelezko .Dynamics of Diamond Nanoparticles in Solution and Cells[J].Nano letters,2007(12):3588-3591. |
| [45] | Pengju G. Luo;Sushant Sahu;Sheng-Tao Yang .Carbon "quantum" dots for optical bioimaging[J].Journal of Materials Chemistry, B. materials for biology and medicine,2013(16):2116-2127. |
| [46] | Liang Q H;Ma W J;Shi Y et al.Easy synthesis of highly fluorescent carbon quantum dots from gelatin and their luminescent properties and applications[J].CARBON,2013,60:421-423. |
| [47] | Yang Z;Li Z H;Xu M H et al.Controllable synthesis of fluorescent carbon dots and their detection application as nanoprobes[J].Nano-Micro Letters,2013,5(04):247-249. |
| [48] | Manav Saxena;Sabyasachi Sarkar .Fluorescence imaging of human erythrocytes by carbon nanoparticles isolated from food stuff and their fluorescence enhancement by blood plasma[J].Materials express: an international journal on multidisciplinary materials research,2013(3):201-209. |
| [49] | Fang, Y.;Guo, S.;Li, D.;Zhu, C.;Ren, W.;Dong, S.;Wang, E. .Easy synthesis and imaging applications of cross-linked green fluorescent hollow carbon nanoparticles[J].ACS nano,2012(1):400-409. |
| [50] | Haitao Li;Ruihua Liu;Yang Liu .Carbon quantum dots/Cu2O composites with protruding nanostructures and their highly efficient (near) infrared photocatalytic behavior[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(34):17470-17475. |
| [51] | Lawrence K .Core-shell functionalised carbon nanoparti-cles:synthesis,electrochemistry,and fluorescence[D].University of Bath,2013. |
| [52] | Somen Mondal;Tarasankar Das;Prasun Ghosh .Exploring the Interior of Hollow Fluorescent Carbon Nanoparticles[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2013(8):4260-4267. |
| [53] | Xin Wang;Li Cao;Fushen Lu;Mohammed J. Meziani;Heting Li;Gang Qi;Bing Zhou;Barbara A. Harruff;Fabien Kermarrec;Ya-Ping Sun .Photoinduced electron transfers with carbon dots[J].Chemical communications,2009(25):3774-3776. |
| [54] | Ming, H.;Ma, Z.;Liu, Y.;Pan, K.;Yu, H.;Wang, F.;Kang, Z. .Large scale electrochemical synthesis of high quality carbon nanodots and their photocatalytic property[J].Dalton transactions: An international journal of inorganic chemistry,2012(31):9526-9531. |
| [55] | Shen J;Zhu Y;Yang X et al.One-pot hydrothermal sythesis of graphene quantum dots suface-passivated by polyethylene clycol and their photoelectric conversion un-der near-infrared light[J].New Journal of Chemistry,2012,36(01):96-98. |
| [56] | Zhang, Y.-Q.;Ma, D.-K.;Zhang, Y.-G.;Chen, W.;Huang, S.-M. .N-doped carbon quantum dots for TiO_2-based photocatalysts and dye-sensitized solar cells[J].Nano Energy,2013(5):545-552. |
| [57] | 张亚,杨兵初,周聪华,王丽丽,童思超.碳球模板剂对TiO_2光阳极微结构及其光电性能影响研究[J].功能材料,2012(19):2716-2719. |
| [58] | 吴春芳,魏杰.量子点敏化太阳能电池研究进展中出现的问题及其解决方案[J].功能材料,2013(01):1-7. |
| [59] | Wang, F.;Chen, Y.-H.;Liu, C.-Y.;Ma, D.-G. .White light-emitting devices based on carbon dots' electroluminescence[J].Chemical communications,2011(12):3502-3504. |
| [60] | Schreuder, MA;Xiao, K;Ivanov, IN;Weiss, SM;Rosenthal, SJ .White Light-Emitting Diodes Based on Ultrasmall CdSe Nanocrystal Electroluminescence[J].Nano letters,2010(2):573-576. |
| [61] | Gupta, V.;Chaudhary, N.;Srivastava, R.;Sharma, G.D.;Bhardwaj, R.;Chand, S. .Luminscent graphene quantum dots for organic photovoltaic devices[J].Journal of the American Chemical Society,2011(26):9960-9963. |
| [62] | 胡长奇,张方辉.高显色白光LED的制备与研究分析[J].功能材料,2013(03):432-434,441. |
| [63] | Songnan Qu;Xingyuan Liu;Xiaoyang Guo;Minghui Chu;Ligong Zhang;Dezhen Shen .Amplified Spontaneous Green Emission and Lasing Emission From Carbon Nanoparticles[J].Advanced functional materials,2014(18):2689-2695. |
| [64] | Mueller M L;Yan X;Mccuire J A et al.Triplet states and electronic relaxation in photoexcited craphene quan-tum dots[J].Nano Letters,2010,10(07):2678-2680. |
| [65] | Zhou, L.;Lin, Y.;Huang, Z.;Ren, J.;Qu, X. .Carbon nanodots as fluorescence probes for rapid, sensitive, and label-free detection of Hg ~(2+) and biothiols in complex matrices[J].Chemical communications,2012(8):1147-1149. |
| [66] | Demchenko A P;Dekaliuk M O .Novel fluorescent car-bonic nanomaterials for sensing and imaging[J].Meth-ods and Applications in Fluorescence,2013,1(04):042001. |
| [67] | Goncalves H M R;Duarte A J;Esteves D A et al.Op-tical fiber sensor for Hg(Ⅱ)based on carbon dots[J].Biosensors and Bioelectronics,2010,26(04):1302-1306. |
| [68] | Goncalves, H;Jorge, PAS;Fernandes, JRA;da Silva, JCGE .Hg(II) sensing based on functionalized carbon dots obtained by direct laser ablation[J].Sensors and Actuators, B. Chemical,2010(2):702-707. |
| [69] | Baruan U;Gogoi N;Majumdar G.Capped fluo-rescent carbon dots for detection of hemin:role of num-ber of -OH groups of capping agent in fluorescence quenching[J].The Scientific World Journal,2013:2013. |
| [70] | Lu W;Qin X;Liu S et al.Economical,green synthesis of fluorescent carbon nanoparticles and their use as probes for sensitive and selective detection of mercury(Ⅱ)ions[J].Analytical Chemistry,2012,84(12):5351-5354. |
| [71] | Yongqiang Dong;Ruixue Wang;Geli Li;Congqiang Chen;Yuwu Chi;Guonan Chen .Polyamine-Functionalized Carbon Quantum Dots as Fluorescent Probes for Selective and Sensitive Detection of Copper Ions[J].Analytical chemistry,2012(14):6220-6224. |
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