以醋酸铜、醋酸锌、氯化亚锡及硫脲为前驱体,油胺为溶剂,采用微波辅助合成 Cu2 ZnSnS4(CZTS)纳米晶；所得样品的物相、结构、形貌以及光学性能分别用 X 射线衍射仪、高分辨透射电子显微镜、拉曼光谱仪和紫外-可见分光光度计来表征；结果表明：微波加热13 min可合成高质量的锌黄锡矿结构的Cu2 ZnSnS4纳米颗粒,CZTS 微球平均直径约为23．68 nm；所得样品的禁带宽度经估算约为1．52 eV,与薄膜太阳能电池所需的最佳禁带宽度相近.
Nanocrystals of copper zinc tin sulfide (CZTS,Cu2 ZnSnS4 )were prepared by the microwave-assisted method using copper acetate,zinc acetate,tin chloride and thiourea as precursors and oleylamin as the solvent. The samples were characterized by X-ray diffraction (XRD),High-resolution transmission electron microscope (TEM),Raman spectroscope and UV-Vis-NIR spectroscope.The results indicated that the kesterite structure of CZTS nanoparticles can be synthesized in 1 3 min via microwave heating.The CZTS are of the microsphere shape,the average diameter of 23.68 nm and the near-optimum optical band gap of 1.52 eV.
参考文献
| [1] | Zou Chao;Zhang Lijie;Lin Desheng et al.Facile synthe-sis of Cu2 ZnSnS4 nanocrystals[J].Cryst Eng Comm,2011,13:3310-3313. |
| [2] | Kazuo Jimbo;Ryoichi Kimura;Tsuyoshi Kamimura;Satoru Yamada;Win Shwe Maw;Hideaki Araki;Koichiro Oishi;Hironori Katagiri .Cu2ZnSnS4-type thin film solar cells using abundant materials[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(15):5997-5999. |
| [3] | Katagiri H.;Washio T.;Shinohara H.;Kurumadani T.;Miyajima S.;Saitoh K. .Development of thin film solar cell based on Cu2ZnSnS4 thin films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1/4):141-148. |
| [4] | 江丰,沈鸿烈,金佳乐,王威.Cu2ZnSnS4薄膜光电性能及其太阳电池的制备和研究[J].功能材料,2012(15):2040-2044. |
| [5] | Sheng Xia .Synthesis of CuInS2 and Cu2 ZnSnS4 nanostruc-tures in polyalcohol and fabrication of corresponding thin films based an inks[D].Doctoral Dissertation of Zhejinang University,2012. |
| [6] | Yan-Li Zhou;Wen-Hui Zhou;Yan-Fang Du;Mei Li;Si-Xin Wu .Sphere-like kesterite Cu_2ZnSnS-4 nanoparticles synthesized by a facile solvothermal method[J].Materials Letters,2011(11):1535-1537. |
| [7] | M.Cao;Y. Shen .A mild solvothermal route to kesterite quaternary Cu_2ZnSnS_4 nanoparticles[J].Journal of Crystal Growth,2011(1):1117-1120. |
| [8] | Rath, T.;Haas, W.;Pein, A.;Saf, R.;Maier, E.;Kunert, B.;Hofer, F.;Resel, R.;Trimmel, G..Synthesis and characterization of copper zinc tin chalcogenide nanoparticles: Influence of reactants on the chemical composition[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2012:87-94. |
| [9] | Prashant K. Sarswat;Michael L. Free .Demonstration of a sol–gel synthesized bifacial CZTS photoelectrochemical cell[J].Physica status solidi, A. Applications and materials science ePSS,2011(12):2861-2864. |
| [10] | Liu, Y.;Ge, M.;Yue, Y.;Sun, Y.;Wu, Y.;Chen, X.;Dai, N. .Colloidal Cu2ZnSnS4 nanocrystals generated by a facile route using ethylxanthate molecular precursors[J].physica status solidi(RRL): rapid research letterse,2011(3):113-115. |
| [11] | Guo, Q.;Ford, G.M.;Yang, W.-C.;Walker, B.C.;Stach, E.A.;Hillhouse, H.W.;Agrawal, R. .Fabrication of 7.2% efficient CZTSSe solar cells using CZTS nanocrystals[J].Journal of the American Chemical Society,2010(49):17384-17386. |
| [12] | Seung Wook Shin;Jun Hee Han;Chan Yeong Park.A facile and low cost synthesis of earth abundant element Cu_2ZnSnS_4 (CZTS) nanocrystals: Effect of Cu concentrations[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2012:192-197. |
| [13] | Prashant K. Sarswat;Michael L Free .An investigation of rapidly synthesized Cu_2ZnSnS_4 nanocrystals[J].Journal of Crystal Growth,2013(Jun.1):87-94. |
| [14] | Cheng Guangxu.The principle and application of Raman bril-louin scattering[M].Beingjing:Science Press,2001:97-98. |
| [15] | Fernandes, P.A.;Salomé, P.M.P.;Cunha, A.F.D. .A study of ternary Cu_2SnS_3 and Cu_3SnS _4 thin films prepared by sulfurizing stacked metal precursors[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2010(21):215403-1-215403-11. |
| [16] | Elizabeth K. Michael;Danielle Norcini;Sridhar Komarneni .Nanocomposite synthesis and characterization of Kesterite, Cu_2ZnSnS_4(CZTS) for photovoltaic applications[J].CERAMICS INTERNATIONAL,2013(7):7935-7941. |
| [17] | 杜长坤,周书才,陈登明,符春林.Mg2（Si,Sn）热电固溶体微波合成研究[J].功能材料,2011(z4):777-780. |
| [18] | 郭莉,王丹军,李东升,付峰,韦庆婷,王继武.联柱状ZnO微晶的微波合成及其光催化活性[J].功能材料,2009(03):478-482. |
| [19] | 张美娟,刘晶冰,宗恺,汪浩,孙玉绣,严辉.Cu2ZnSnS4纳米晶微球的制备及其表征[J].无机化学学报,2013(02):333-337. |
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