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  4. 超点阵R-Mg-Ni基合金结构和储氢特性研究现状?

功能材料, 2015, (10): 10007-10012. doi: 10.3969/j.issn.1001-9731.2015.10.002

超点阵R-Mg-Ni基合金结构和储氢特性研究现状?

陈子亮 1, , 李永涛 2, , 张庆安 3,

1.安徽工业大学 材料科学与工程学院,安徽 马鞍山,243000

2.安徽工业大学 材料科学与工程学院,安徽 马鞍山,243000

3.安徽工业大学 材料科学与工程学院,安徽 马鞍山,243000

基金项目:   国家自然科学基金资助项目(51271002)   安徽工业大学研究生创新研究基金资助项目(2012009)   国家青年自然科学基金资助项目(51301002)  

关键词： R-Mg-Ni基合金 , 超点阵 , 结构特点 , 储氢特性

Research status in structure and hydrogen storage features of superlattice R-Mg-Ni-based alloys

Keywords： R-Mg-Ni-based alloy , superlattice , structural characteristic , hydrogen storage feature

由 Laves 型[A2 B4]和 CaCu5型[AB5]亚单元以一定比率沿c 轴有序堆垛而成的超点阵 R-Mg-N i基储氢合金(R＝稀土元素、Ca元素)，因具有储氢容量高、可逆性好以及动力学与热力学行为温和可控等优势被认为是新一代镍氢电池最理想的候选负极材料。本文介绍了超点阵 R-Mg-N i 基合金的结构特点和储氢特性，着重阐述了结构、Mg 元素及氢化行为三者之间的关系，并指出了这类合金在储氢机制方面需要进一步探究的关键性问题。

R-Mg-Ni-based (R=rare earth elements,Ca element)superlattice alloys,which are made up of Laves-type [A2 B4 ]and CaCu5-type [AB5 ]cells stacked along the c axis,possess the controllable kinetic/thermody-namics properties as well as the high hydrogen storage capacity and good reversibility,so they are considered as the most ideal negative materials for new generation Ni/MH battery.The present situation of research of struc-ture characteristics and hydrogen storage features of R-Mg-Ni-based superlattice alloys are reviewed.Especially, this paper focuses on describing the relationship among the structure,Mg element and hydrogenation behavior of R-Mg-Ni-based superlattice alloys.Finally,the key issues related to the hydrogen storage mechanism which nee-ded to be solved in future were further pointed out.

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