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通过添加表面活性剂制备了 Cu-H2 O 和ZrO2-H2 O 纳米流体,研究了十二烷基苯磺酸钠、十六烷基三甲基溴化铵和辛基苯基聚氧乙烯醚等表面活性剂对Cu-H2 O 和ZrO2-H2 O 纳米流体分散稳定性的影响;并利用分子动力学方法计算出不同表面活性剂分子与Cu/ZrO2颗粒表面的相互作用能。结果发现添加表面活性剂可较大程度地提升纳米流体的稳定性,而尤以添加十二烷基苯磺酸钠的效果最为明显,计算结果也显示十二烷基苯磺酸钠分子与Cu/ZrO2间的吸附作用最强。此外,还模拟了 SDBS 与 Cu-H2 O 纳米流体中Cu颗粒的吸附行为。

Cu-H2 O and ZrO2-H2 O nanofluids were prepared with surfactants and the impacts of different surfac-tants,such as sodium dodecyl benzene sulfonate,cetyl trimethyl ammonium bromide and octyl phenyl polyoxy-ethylene ether,on the stability of Cu-H2 O and ZrO2-H2 O nanofluids was also studied.Moreover,the interac-tion energies between various surfactants and the surface of Cu/ZrO2 particles were calculated with the method of molecular dynamics simulation.It was shown that the addition of surfactants,especially for sodium dodecyl benzene sulfonate,to nanofluids would enhance the stability of the nanofluids to a large extent.Meanwhile,the result was that the adsorption between sodium dodecyl benzene sulfonate molecules and Cu/ZrO2 was strongest. Furthermore,the adsorption behavior between sodium dodecyl benzene sulfonate and Cu particles in the Cu-H2 O nanofluid was simulated as well.

参考文献

[1] M. Silambarasan;S. Manikandan;K. S. Rajan .Viscosity and thermal conductivity of dispersions of sub-micron TiO_2 particles in water prepared by stirred bead milling and ultrasonication[J].International Journal of Heat and Mass Transfer,2012(25/26):7991-8002.
[2] Weerapun Duangthongsuk;Somchai Wongwises .An experimental study on the heat transfer performance and pressure drop of TiO_2-water nanofluids flowing under a turbulent flow regime[J].International Journal of Heat and Mass Transfer,2010(1/3):334-344.
[3] S. M. Fotukian;M. Nasr Esfahany .Experimental study of turbulent convective heat transfer and pressure drop of dilute CuO/water nanofluid inside a circular tube[J].International Communications in Heat and Mass Transfer: A Rapid Communications Journal,2010(2):214-219.
[4] Kleinstreuer C;Feng Yu .Experimental and theoretical studies of nanofluid thermal conductivity enhancement:a review[J].Nanoscale Research Letters,2011,6(1):1-13.
[5] 刘少光,赵琪,李志章,郦剑,张升才,吴进明,胡小海.N2保护对TiAl3和Cr3C2复合涂层组织结构及高温冲蚀性能的影响[J].功能材料,2008(01):166-169.
[6] 凌智勇,朱爱军,丁建宁,范真,程广贵,傅鹏飞.层流状态下纳米流体的对流传热特性[J].功能材料,2010(06):948-951.
[7] 李泽梁,李俊明,王补宣,胡海滔.SDBS对氧化铜纳米颗粒悬浮液粘度的影响[J].工程热物理学报,2003(05):849-851.
[8] 凌智勇,张体峰,丁建宁,程广贵,邹涛,朱爱军.Cu-水纳米流体的稳定性及其粘度的实验研究[J].功能材料,2011(z3):481-483.
[9] Chen Zongqi;Wang Guangxin;Xu Guiying.Colloid and Interface Chemistry[M].北京:高等教育出版社,2001:223-252.
[10] Cui Zhenggang.Fundamental of surfactants,colloids and interface chemistry[M].Beij ing:Chemistry Industry Press,2013:38-39.
[11] 朱冬生,李新芳,王先菊,李华,高进伟.氧化铝-水纳米流体的制备及其分散性研究[J].化工新型材料,2007(09):45-47.
[12] Xu Qianghui;Zan Cheng;Jiang Haifeng et al.Disper-sion stability analysis ofα-Fe2 03-water-based nanofluid[J].Journal of Engineering Thermophysics,2013,34(011):2006-2010.
[13] 宋其圣,郭新利,苑世领,刘成卜.十二烷基苯磺酸钠在SiO2表面聚集的分子动力学模拟[J].物理化学学报,2009(06):1053-1058.
[14] Xuan Yimin;Li qiang.Nanofluids energy transfer theory and application[M].北京:科学出版社,2010:20.
[15] Chen Zhenglong;Xu Weiren;Tang Lida.Theory and practice of molecular simulation[M].Beij ing:Chemistry Industry Press,2007:156.
[16] Frenkel D;Smit B.Understanding molecular simula-tion:from algorithms to applications[M].Pennsylvania:Academic press,2001
[17] Zhang Zhijie.Physical chemistry of materials[M].Bei-jing:Chemistry Industry Press,2006:165.
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