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研究了中国低活化马氏体(CLAM)钢 TIG焊接接头(焊缝和热影响区)在500℃静态饱和氧浓度液态铅铋共晶体(LBE)中的腐蚀行为.未热处理的焊接接头腐蚀时间为200和400 h,回火处理的焊接接头腐蚀时间为400 h.研究发现,钢中有明显的元素的溶解,所有试样表面均形成了具有保护作用的双氧化层,外氧化层为疏松多孔的 Fe3 O 4,内氧化层为致密的 Fe-Cr 尖晶石,没有发现 Pb、Bi 渗透进基体材料.回火处理可有效提高焊接接头的耐腐蚀性能,焊缝耐蚀性低于热影响区.

The corrosion behavior of China Low Activation Martensitic (CLAM)steel TIG weldment(weld zone and heat affected zone)in stagnant lead bismuth eutectic saturated by oxygen at 500 ℃ was studied in this paper. The corrosion time of as-welded CLAM steel was 200 and 400 h,while the as-tempered CLAM steel was ex-posed for 400 h.The results show that dissolution of steel components was observed.A protective double layer oxide film which consists of a loose and porous Fe3 O 4 outer layer and a dense Fe-Cr spinel inner layer was formed on surface of all the samples.No penetration of Pb,Bi into the matrix was found.The post-weld tempe-ring process can improve corrosion resistance effectively.The corrosion resistance of heat affected zone was supe-rior to weld zone.

参考文献

[1] Hosemann P;Hawley M;Koury D;Swadener JG;Welch J;Johnson AL;Mori G;Li N .Characterization of oxide layers grown on D9 austenitic stainless steel in lead bismuth eutectic[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2008(3):323-330.
[2] 许咏丽,龙斌.ADS结构材料在液态Pb-Bi合金中的腐蚀[J].原子能科学技术,2003(04):325-333.
[3] 吴宜灿,黄群英,柏云清,高胜,朱志强,陈雅萍,凌新圳,刘静,祝玲琳,王改英,赵连晋,周涛,陈红丽,FDS团队.液态铅铋回路设计研制与材料腐蚀实验初步研究[J].核科学与工程,2010(03):238-243.
[4] J. Van den Bosch;A. Almazouzi .Compatibility of martensitic/austenitic steel welds with liquid lead bismuth eutectic environment[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2009(3):504-509.
[5] 李华杰,武会宾,唐荻.中国低活化马氏体钢组织性能及强化机理[J].北京科技大学学报,2011(02):166-171.
[6] 高胜,章毛连,朱志强,黄群英,李春京,李艳芬,宋勇,邓铁如,孔明光,吴宜灿,FDS团队.中国低活化马氏体钢CLAM在液态锂铅中腐蚀的初步实验研究[J].核科学与工程,2007(01):51-54.
[7] Chen X Z;Shen Z;Li P et al.Compatibility of CLAM steel weldments with static LiPb alloy at 500 ℃[J].Fu-sion Engineering and Design,2012,87(9):1565-1569.
[8] Martin FJ;Soler L;Hernandez F;Gomez-Briceno D .Oxide layer stability in lead-bismuth at high temperature[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2004(2):194-198.
[9] O. Yeliseyeva;V. Tsisar;G. Benamati .Influence of temperature on the interaction mode of T91 and AISI 316L steels with Pb-Bi melt saturated by oxygen[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2008(6):1672-1683.
[10] Schroer C;Voss Z;Wedemeyer O;Novotny J;Konys J .Oxidation of steel T91 in flowing lead-bismuth eutectic (LBE) at 550 degrees C[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2006(1/3):189-197.
[11] Hosemann P;Hawley ME;Koury D;Welch J;Johnson AL;Mori G;Li N;Maloy SA .Nanoscale characterization of HT-9 exposed to lead bismuth eutectic at 550 degrees C for 3000 h[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2008(3):211-215.
[12] Fazio C.;Martini C.;Palombarini G.;Benamati G. .Compatibility tests on steels in molten lead and lead-bismuth[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2001(0):243-248.
[13] Martinelli L;Balbaud C F;Terlain A et al.Oxidation mechanism of an Fe-9Cr-1Mo steel by liquid Pb-Bi eu-tectic alloy at 470 ℃(Part Ⅱ)[J].Corrosion Science,2008,50(9):2537-2548.
[14] 乔建生,黄依娜,万发荣.CLAM钢TIG焊后的热处理工艺研究[J].核科学与工程,2009(03):239-246.
[15] Johnson AL;Parsons D;Manzerova J;Perry DL;Koury D;Hosterman B;Farley JW .Spectroscopic and microscopic investigation of the corrosion of 316/316L stainless steel by lead-bismuth eutectic (LBE) at elevated temperatures: importance of surface preparation[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2004(2/3):88-96.
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