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采用射频磁控溅射方法分别在石英玻璃和TCO玻璃上制备了不同厚度的CdS薄膜,研究了CdS薄膜厚度对薄膜结构和光学性质的影响.在不同厚度的CdS/TCO衬底上,进一步制备成CdTe薄膜太阳电池.结果表明,CdS薄膜厚度的增加有利于薄膜的生长与结晶;110 nm的薄膜具有禁带宽度为2.41 eV的最大值;测试电池性能,得到CdS厚度为110 nm的电池具有11.42%的最高转换效率.

参考文献

[1] Romeo N.;Tedeschi R.;Canevari V.;Bosio A..Growth of polycrystalline CdS and CdTe thin layers for high efficiency thin film solar cells[J].Materials Chemistry and Physics,20002/3(2/3):201-206.
[2] M. Hadrich;N. Lorenz;H. Metzner;U. Reislohner;S. Mack;M. Gossla;W. Witthuhn.CdTe–CdS solar cells — Production in a new baseline and investigation of material properties[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,200715(15):5804-5807.
[3] Uda H.;Yonezawa H.;Ohtsubo Y.;Kosaka M.;Sonomura H..Thin CdS films prepared by metalorganic chemical vapor deposition[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,20031/2(1/2):219-226.
[4] Jae-Hyeong Lee;Dong-Jin Lee.Effects of CdCl2 treatment on the properties of CdS films prepared by r.f. magnetron sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,200715(15):6055-6059.
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