以碳纳米管为增强相,WC-10Co硬质合金为基体,采用湿法球磨工艺将多壁碳纳米管(Multi walled carbon nanotubes,MWCNTs)和WC-10Co硬质合金粉料充分混合,通过真空烧结制成CNTs增强的WC-10Co硬质合金试样.采用SEM观测MWCNT在硬质合金基体中的分布和烧结后硬质合金微观结构.SEM显示碳纳米管嵌插在WC晶粒之间,抑制WC晶粒生长,使WC晶粒得到细化.试样横向断裂强度达到1 780 MPa,对比未增强试样提高了7.8%.
参考文献
[1] | Shi, XL;Yang, H;Wang, S;Shao, GQ;Duan, XL.Fabrication and properties of WC-10Co cemented carbide reinforced by multi-walled carbon nanotubes[J].Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing,20081/2(1/2):489-495. |
[2] | Nicolas Keller;Barbara Pietruszka;Valerie Keller.A new one-dimensional tungsten carbide nanostructured material[J].Materials Letters,200613/14(13/14):1774-1777. |
[3] | 李延俊;廖立;谢克难;孟祉含.超细WC-Co硬质合金粉末的制备及其致密化研究[J].功能材料,2013(8):1102-1105. |
[4] | 林晨光.中国超细晶粒WC-Co硬质合金研究进展[J].稀有金属,2004(04):762-766. |
[5] | Xiaosong Zhou;Yejun Qiu;Jie Yu;Jing Yin;Shang Gao.Tungsten carbide nanofibers prepared by electrospinning with high electrocatalytic activity for oxygen reduction[J].International journal of hydrogen energy,201113(13):7398-7404. |
[6] | Dong Jin Ham;Raman Ganesan;Jae Sung Lee.Tungsten Carbide Microsphere As An Electrode For Cathodic Hydrogen Evolution From Water[J].International journal of hydrogen energy,200823(23):6865-6872. |
[7] | T. Hayashi;M. Endo.Carbon nanotubes as structural material and their application in composites[J].Composites, Part B. Engineering,20118(8):2151-2157. |
[8] | Cha SI.;Hong SH..Microstructures of binderless tungsten carbides sintered by spark plasma sintering process[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20031/2(1/2):381-389. |
[9] | Zhu Baojun;Qu Xuanhui;Tao Ying.Powder injection molding of WC-8 percent Co tungsten cemented carbide[J].International Journal of Refractory Metals & Hard Materials,20025/6(5/6):389-394. |
[10] | Pei Kang Shen;Shibin Yin;Zihui Li;Chan Chen.Preparation and performance of nanosized tungsten carbides for electrocatalysis[J].Electrochimica Acta,201027(27):7969-7974. |
[11] | Y. Morisada;Y. Miyamoto.SiC-coated carbon nanotubes and their application as reinforcements for cemented carbides[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20041/2(1/2):57-61. |
[12] | 张法明;沈军;孙剑飞;郭舒.纳米WC-Co硬质合金的微观组织特征[J].有色金属,2005(1):4-7,15. |
[13] | 朱运锋;叶金文;刘颖;朱军;马世卿;张蛟.(V,Ti)(C,N)固溶体粉末对WC-8%Co硬质合金性能的影响[J].功能材料,2013(15):2239-2243. |
[14] | Kaushik Ghosh;Mukul Kumar;Takahiro Maruyama.Tailoring the field emission property of nitrogen-doped carbon nanotubes by controlling the graphitic/pyridinic substitution[J].Carbon: An International Journal Sponsored by the American Carbon Society,20101(1):191-200. |
[15] | Huafeng Wang;Zhenhua Li;Kaushik Ghosh.Synthesis of double-walled carbon nanotube films and their field emission properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,201010(10):2882-2889. |
[16] | K. Shinke;K. Ando;T. Koyama;T. Takai;S. Nakaji;T. Ogino.Properties of various carbon nanomaterial surfaces in bilirubin adsorption[J].Colloids and Surfaces, B. Biointerfaces,20101(1):18-21. |
[17] | Kaushik Ghosh;Mukul Kumar;Takahiro Maruyama.Micro-structural, electron-spectroscopic and field-emission studies of carbon nitride nanotubes grown from cage-like and linear carbon sources[J].Carbon: An International Journal Sponsored by the American Carbon Society,20096(6):1565-1575. |
[18] | Ando, K;Shinke, K;Yamada, S;Koyama, T;Takai, T;Nakaji, S;Ogino, T.Fabrication of carbon nanotube sheets and their bilirubin adsorption capacity[J].Colloids and Surfaces. B, Biointerfaces,20092(2):255-259. |
[19] | Y. Morisada;Y. Miyamoto.SiC-coated carbon nanotubes and their application as reinforcements for cemented carbides[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20041/2(1/2):57-61. |
[20] | Faming Zhang;Jun Shen;Jianfei Sun.The effect of phosphorus additions on densification, grain growth and properties of nanocrystalline WC-Co composites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20041/2(1/2):96-103. |
[21] | Xiaoliang Shi;Hua Yang;Peng Sun.Synthesis of multi-walled carbon nanotube-tungsten carbide composites by the reduction and carbonization process[J].Carbon: An International Journal Sponsored by the American Carbon Society,20079(9):1735-1742. |
[22] | Shixian Zhao;Xiaoyan Song;Chongbin Wei.Effects of WC particle size on densification and properties of spark plasma sintered WC-Co cermet[J].International Journal of Refractory Metals & Hard Materials,20096(6):1014-1018. |
[23] | 辜萍;王宇;李广海.碳纳米管的力学性能及碳纳米管复合材料研究[J].力学进展,2002(4):563-578. |
[24] | 武玺旺;肖建中;夏风;胡永刚;彭周.碳纳米管的分散方法与分散机理[J].材料导报,2011(9):16-19. |
[25] | Hilding J.;Grulke EA.;Zhang ZG.;Lockwood F..Dispersion of carbon nanotubes in liquids [Review][J].Journal of Dispersion Science and Technology,20031(1):1-41. |
[26] | Schaefer D.;Brown JM.;Anderson DP.;Zhao J.;Chokalingam K.;Tomlin D. Ilavsky J..Structure and dispersion of carbon nanotubes[J].Journal of Applied Crystallography,20033 Pt.1(3 Pt.1):553-557. |
[27] | 张正富;黄莉玲;彭金辉;谭竹峰;袁明健;张华明;李芳.WC-Co硬质合金硬度和冲击韧度影响因素的变量搜索试验[J].金属热处理,2011(5):83-89. |
[28] | 颜杰;唐楷;黄新;汪建昌;姜宁.硬质合金生产中的增氧反应及其影响[J].硬质合金,2006(4):218-221. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%