总结了近年来金属氧化物形貌控制上取得的成就，从气敏材料、锂离子电池、超级电容器、生物传感材料、催化剂等方面的应用阐述了金属氧化物形貌对其性能的影响，说明了金属氧化物形貌控制的重要性。同时，还介绍了不同形貌材料的制备方法如物理法、模板法、无模板法等，总结了几种典型形貌的制备过程和形成机理，并概述了一般的形貌调控手段。
In recent years,metal oxide morphology control has made great achievements.It’s vital to control the morphology of metal oxide to improve its performance,which was proved from the application of sensing mate-rial,lithium-ion batteries,super capacitors,bio-sensing materials,catalysts,etc.In this paper,the process of the preparation of several typical morphologies and its formation principle was summed up,and an overview of the control methods for general morphology was introduced.
参考文献
| [1] | A.V.Emeline;G.V.Kataeva;A.V.Panasuk;V.K.Ryabchuk;N.V.Sheremetyeva;N.Serpone.Effect of Surface Photoreactions on the Photocoloration of a Wide Band Gap Metal Oxide:Probing Whether Surface Reactions Are Photocatalytic[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,200511(11):5175-5180. |
| [2] | Lee, MJ;Han, S;Jeon, SH;Park, BH;Kang, BS;Ahn, SE;Kim, KH;Lee, CB;Kim, CJ;Yoo, IK;Seo, DH;Li, XS;Park, JB;Lee, JH;Park, Y.Electrical Manipulation of Nanofilaments in Transition-Metal Oxides for Resistance-Based Memory[J].Nano letters,20094(4):1476-1481. |
| [3] | Josef Macht;Enrique Iglesia.Structure and function of oxide nanostructures:catalytic consequences of size and composition[J].Physical chemistry chemical physics: PCCP,200835(35):5331-5343. |
| [4] | Henk J. Bolimk;Eugenio Coronado;Javier Orozco;Michele Sessolo.Efficient Polymer Light-emitting Diode Using Air-stable Metal Oxides As Electrodes[J].Advanced Materials,20091(1):79-82. |
| [5] | Rupesh S. Devon;Ranjit A. Patil;Jin-Han Lin;Yuan-Ron Ma.One-Dimensional Metal-Oxide Nanostructures: Recent Developments in Synthesis, Characterization, and Applications[J].Advanced functional materials,201216(16):3326-3370. |
| [6] | Li WY;Xu LN;Chen J.Co3O4 nanomaterials in lithium-ion batteries and gas sensors[J].Advanced functional materials,20055(5):851-857. |
| [7] | Sumanta Kumar Meher;G. Ranga Rao.Ultralayered Co3O4 for High-Performance Supercapacitor Applications[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201131(31):15646-15654. |
| [8] | Hoa Nguyen;Sherif A. El-Safty.Meso- and Macroporous Co3O4 Nanorods for Effective VOC Gas Sensors[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201117(17):8466-8474. |
| [9] | Park, JS;Shen, XP;Wang, GX.Solvothermal synthesis and gas-sensing performance of Co3O4 hollow nanospheres[J].Sensors and Actuators. B, Chemical,20092(2):494-498. |
| [10] | K.V. Gurav;U.M. Patil;S.W. Shin.Morphology evolution of ZnO thin films from aqueous solutions and their application to liquefied petroleum gas (LPG) sensor[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2012:1-7. |
| [11] | Gurav, K.V.;Deshmukh, P.R.;Lokhande, C.D..LPG sensing properties of Pd-sensitized vertically aligned ZnO nanorods[J].Sensors and Actuators, B. Chemical,20112(2):365-369. |
| [12] | Navale SC;Gosavi SW;Mulla IS.Controlled synthesis of ZnO from nanospheres to micro-rods and its gas sensing studies[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,20085(5):1315-1319. |
| [13] | Sahay PP;Nath RK.Al-doped ZnO thin films as methanol sensors[J].Sensors and Actuators, B. Chemical,20082(2):654-659. |
| [14] | Zhen Wen;Liping Zhu;Weimin Mei.A facile fluorine-mediated hydrothermal route to controlled synthesis of rhombus-shaped Go3O4 nanorod arrays and their application in gas sensing[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201325(25):7511-7518. |
| [15] | Te-Yu Wei;Chun-Hung Chen;Kuo-Hsin Chang.Cobalt Oxide Aerogels of Ideal Supercapacitive Properties Prepared with an Epoxide Synthetic Route[J].Chemistry of Materials: A Publication of the American Chemistry Society,200914(14):3228-3233. |
| [16] | Chuan Lin;James A. Ritter;Branko N. Popov.Characterization of sol-gel-derived cobalt oxide xerogels as electrochemical capacitors[J].Journal of the Electrochemical Society,199812(12):4097-4103. |
| [17] | Changzhou Yuan;Xiaogang Zhang;Linhao Su.Facile synthesis and self-assembly of hierarchical porous NiO nano/micro spherical superstructures for high performance supercapacitors[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200932(32):5772-5777. |
| [18] | Wei Wei;Zhenzhong Yang.Template Synthesis of Hierarchically Structured Composites[J].Advanced Materials,200815(15):2965-2969. |
| [19] | Kalyanjyoti Deori;Sanjeev Kumar Ujjain;Raj Kishore Sharma.Morphology Controlled Synthesis of Nanoporous Co3O4 Nanostructures and Their Charge Storage Characteristics in Supercapacitors[J].ACS applied materials & interfaces,201321(21):10665-10672. |
| [20] | Xiaoling Xiao;Xiangfeng Liu;Hu Zhao;Dongfeng Chen;Fengzhen Liu;Junhui Xiang;Zhongbo Hu;Yadong Li.Facile Shape Control of Co_3O_4 and the Effect of the Crystal Plane on Electrochemical Performance[J].Advanced Materials,201242(42):5762-5766. |
| [21] | Wang, Xi;Wu, Xing-Long;Guo, Yu-Guo;Zhong, Yeteng;Cao, Xinqiang;Ma, Ying;Yao, Jiannian.Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres[J].Advanced functional materials,201010(10):1680-1686. |
| [22] | 雷晓玲;代海;冯开忠;任卫安;文晓刚.MnO2纳米材料的可控制备和催化性能研究[J].功能材料,2013(13):1940-1942. |
| [23] | Abazari, Reza;Mahjoub, Ali Reza;Sanati, Soheila.A facile and efficient preparation of anatase titania nanoparticles in micelle nanoreactors: morphology, structure, and their high photocatalytic activity under UV light illumination[J].RSC Advances,201499(99):56406-56414. |
| [24] | Li, Y;Liu, XY;Yuan, HY;Xiao, D.Glucose biosensor based on the room-temperature phosphorescence of TiO2/SiO2 nanocomposite[J].Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices,200912(12):3706-3710. |
| [25] | Liu JP;Guo CX;Li CM;Li YY;Chi QB;Huang XT;Liao L;Yu T.Carbon-decorated ZnO nanowire array: A novel platform for direct electrochemistry of enzymes and biosensing applications[J].Electrochemistry communications,20091(1):202-205. |
| [26] | 贾向东;陆峰;刘燕;朱俊杰.花状氧化锌纳米晶的制备及其电化学传感研究[J].无机化学学报,2011(6):1150-1154. |
| [27] | Vabbina, Phani Kiran;Kaushik, Ajeet;Pokhrel, Nimesh;Bhansali, Shekhar;Pala, Nezih.Electrochemical cortisol immunosensors based on sonochemically synthesized zinc oxide 1D nanorods and 2D nanoflakes[J].Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices,2015:124-130. |
| [28] | Jianshuai Mu;Li Zhang;Min Zhao.Catalase Mimic Property of Co3O4 Nanomaterials with Different Morphology and Its Application as a Calcium Sensor[J].ACS applied materials & interfaces,201410(10):7090-7098. |
| [29] | Liang Li;Takeshi Sasaki;Yoshiki Shimizu.Controlled Cobalt Oxide from Two-Dimensional Films to One-Dimensional Nanorods and Zero-Dimensional Nanoparticles: Morphology-Dependent Optical Carbon Monoxide Gas-Sensing Properties[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200936(36):15948-15954. |
| [30] | Xi Wang;Wei Tian;Tianyou Zhai.Cobalt(II,III) oxide hollow structures: fabrication, properties and applications[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201244(44):23310-23326. |
| [31] | 何琴;黄保军;李颖颖;法文君.生物模板法制备微纳米二氧化锡[J].化工新型材料,2012(5):151-153. |
| [32] | Kim JW;Choi SH;Lillehei PT;Chu SH;King GC;Watt GD.Cobalt oxide hollow nanoparticles derived by bio-templating[J].Chemical communications,200532(32):4101-4103. |
| [33] | 江学良;杨浩;王维;杜银;任军.CeO 2纳米空心球的制备与光催化性能研究[J].功能材料,2014(9):9108-9112. |
| [34] | 刘名扬;赵景红;邹明强;刘达.不同形貌纳米SnO2的可控合成及催化发光传感器[J].高等学校化学学报,2011(5):1112-1117. |
| [35] | Lichaojia;Wei ping Cai.Micro/Nanostructured Ordered Porous Films and Their Structurally Induced Control of the Gas Sensing Performances[J].Advanced functional materials,201021(21):3765-3773. |
| [36] | G. Korotcenkov;A. Cerneavschi;V. Brinzari A. Vasiliev;M. Ivanov;A. Cornet;J. Morante;A. Cabot;J. Arbiol.In_2O_3 films deposited by spray pyrolysis as a material for ozone gas sensors[J].Sensors and Actuators, B. Chemical,20042/3(2/3):297-303. |
| [37] | Guo PF;Pan HB.Selectivity of Ti-doped In2O3 ceramics as an ammonia sensor[J].Sensors and Actuators, B. Chemical,20062(2):762-767. |
| [38] | Yongzheng Shao;Jing Sun;Lian Gao.Hydrothermal Synthesis of Hierarchical Nanocolumns of Cobalt Hydroxide and Cobalt Oxide[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200916(16):6566-6572. |
| [39] | Chun-Jiang Jia;Ling-Dong Sun;Zheng-Guang Yan;Li-Ping You;Feng Luo;Xiao-Dong Han;Yu-Cheng Pang;Ze Zhang;Chun-Hua Yan.Single-Crystalline Iron Oxide Nanotubes[J].Angewandte Chemie,200528(28):4328-4333. |
| [40] | Corinne Coudun;Jean-Francois Hochepied.Nickel Hydroxide "Stacks of Pancakes" Obtained by the Coupled Effect of Ammonia and Template Agent[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,200513(13):6069-6074. |
| [41] | Ding YS;Xu LP;Chen CH;Shen XF;Suib SL.Syntheses of nanostructures of cobalt hydrotalcite like compounds and Co3O4 via a microwave-assisted reflux method[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200822(22):8177-8183. |
| [42] | Guoxiu Wang;Xinglong Gou;Josip Horvat.Facile Synthesis and Characterization of Iron Oxide Semiconductor Nanowires for Gas Sensing Application[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200839(39):15220-15225. |
| [43] | Yang, JH;Sasaki, T.Morphological Control of Single Crystalline Co3O4 Polyhedrons: Selective and Nonselective Growth of Crystal Planes Directed by Differently Charged Surfactants and Solvents[J].Crystal growth & design,20103(3):1233-1236. |
| [44] | Yoshikawa H;Hayashida K;Kozuka Y;Horiguchi A;Awaga K;Bandow S;Iijima S.Preparation and magnetic properties of hollow nano-spheres of cobalt and cobalt oxide: Drastic cooling-field effects on remnant magnetization of antiferromagnet[J].Applied physics letters,200422(22):5287-5289. |
| [45] | Wang, M.;Gao, Y.;Dai, L.;Cao, C.;Guo, X..Influence of surfactants on the morphology of SnO _2 nanocrystals prepared via a hydrothermal method (Conference Paper)[J].Journal of Solid State Chemistry,2012:49-56. |
| [46] | Zhuo Wang;Xue-feng Qian;Jie Yin;Zi-kang Zhu.Large-Scale Fabrication of Tower-like,Flower-like,and Tube-like ZnO Arrays by a Simple Chemical Solution Route[J].Langmuir: The ACS Journal of Surfaces and Colloids,20048(8):3441-3448. |
| [47] | 林志贤;张永爱;覃华芳;郭太良.ZnO纳米材料制备及其场发射性能的研究[J].功能材料,2010(2):288-291. |
| [48] | Xu JS;Xue DF;Zhu YC.Room temperature synthesis of curved ammonium copper molybdate nanoflake and its hierarchical architecture[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,200635(35):17400-17405. |
| [49] | S.D. Shinde;G.E.Patil;D.D. Kajale.Synthesis of ZnO nanorods by spray pyrolysis for H_2S gas sensor[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2012:109-114. |
| [50] | Jun Lu;Qing Peng;Zhongying Wang.Hematite nanodiscs exposing (001) facets: synthesis, formation mechanism and application for Li-ion batteries[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201317(17):5232-5237. |
| [51] | Geneva R. Peterson;Fernando Hung-Low;Cenk Gumeci.Preparation-Morphology-Performance Relationships in Cobalt Aerogels as Supercapacitors[J].ACS applied materials & interfaces,20143(3):1796-1803. |
| [52] | Gash AE;Satcher JH;Simpson RL.Monolithic nickel(II)-based aerogels using an organic epoxide: the importance of the counterion[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,20040(0):145-151. |
| [53] | Gash AE.;Satcher JH.;Poco JF.;Hrubesh LW.;Simpson RL.;Tillotson TM..Use of epoxides in the sol-gel synthesis of porous iron(III) oxide monoliths from Fe(III) salts[J].Chemistry of Materials,20013(3):999-1007. |
| [54] | Gash AE.;Satcher JH.;Hrubesh LW.;Simpson RL.;Tillotson TM..New sol-gel synthetic route to transition and main-group metal oxide aerogels using inorganic salt precursors[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,20011/3(1/3):22-28. |
| [55] | Laberty-Robert C;Long JW;Lucas EM;Pettigrew KA;Stroud RM;Doescher MS;Rolison DR.Sol-gel-derived ceria nanoarchitectures: Synthesis, characterization, and electrical properties[J].Chemistry of Materials: A Publication of the American Chemistry Society,20061(1):50-58. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%