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生物炭以其优良的污染物吸附效果受到关注,但不易从溶液中分离的难题限制了其应用。通过与磁性介质结合,将生物炭磁化,使其能够在磁场作用下实现固液分离,是解决该问题的有效方法。综述了磁性生物炭复合材料的结构类型及制备方法,分析了影响产物属性的浸渍比率、热解温度、保留时间等因素,并重点介绍了在重金属离子和有机污染物治理中的应用。最后对磁性生物炭发展趋势及该研究领域存在的问题进行了探讨。

Biochar has become a rising concern due to its good effect of pollutants adsorption,but the poor ad-sorbent-water separation limits its practical application.Magnetizing biochar by binding of the magnetic medium is an effective method to solve this problem,which could realize the solid-liquid separation under the magnetic field.The structure types and preparation methods of magnetic biochar composite materials are summarized in this paper.The factors influencing properties of final product are analyzed,such as pyrolytic temperature,resi-dence time,and mass ratio of magnetic precursors to biomass feedstock.Applications of such magnetic carbon materials in treatment of heavy metals and organic pollutants are introduced in detail.Some discussions are also carried out on the limitation and development tendency in this research area.

参考文献

[1] Gaosheng Zhang;Jiuhui Qu;Huijuan Liu;Adrienne T. Cooper;Rongcheng Wu.CuFe2O4/activated carbon composite: A novel magnetic adsorbent for the removal of acid orange II and catalytic regeneration[J].Chemosphere: Environmental toxicology and risk assessment,20076(6):1058-1066.
[2] Le Zeng;Xiaomei Li;Jindun Liu.Adsorptive removal of phosphate from aqueous solutions using iron oxide tailings[J].Water research: A journal of the international water association,20045(5):1318-1326.
[3] Loyo, RLD;Nikitenko, SI;Scheinost, AC;Simonoff, M.Immobilization of selenite on Fe3O4 and Fe/Fe3C ultrasmall particles[J].Environmental Science & Technology,20087(7):2451-2456.
[4] Lim, SF;Zheng, YM;Chen, JP.Organic Arsenic Adsorption onto a Magnetic Sorbent[J].Langmuir: The ACS Journal of Surfaces and Colloids,20099(9):4973-4978.
[5] 李力;刘娅;陆宇超;梁中耀;张鹏;孙红文.生物炭的环境效应及其应用的研究进展[J].环境化学,2011(8):1411-1421.
[6] Zhang, M.;Gao, B.;Varnoosfaderani, S.;Hebard, A.;Yao, Y.;Inyang, M..Preparation and characterization of a novel magnetic biochar for arsenic removal[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2013:457-462.
[7] Chen, B.;Chen, Z.;Lv, S..A novel magnetic biochar efficiently sorbs organic pollutants and phosphate[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,20112(2):716-723.
[8] D. Harikishore Kumar Reddy;Seung-Mok Lee.Magnetic biochar composite: Facile synthesis, characterization, and application for heavy metal removal[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2014:96-103.
[9] Shouwei Zhang;Meiyi Zeng;Jiaxing Li.Porous magnetic carbon sheets from biomass as an adsorbent for the fast removal of organic pollutants from aqueous solution[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201412(12):4391-4397.
[10] Liu, ZG;Zhang, FS.Nano-zerovalent iron contained porous carbons developed from waste biomass for the adsorption and dechlorination of PCBs[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,20107(7):2562-2564.
[11] Zhou, Lincheng;Ma, Junjun;Zhang, He;Shao, Yanming;Li, Yanfeng.Fabrication of magnetic carbon composites from peanut shells and its application as a heterogeneous Fenton catalyst in removal of methylene blue[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2015Jan.1(Jan.1):490-498.
[12] Wei Wang;Xuejiang Wang;Xin Wang;Lianzhen Yang;Zhen Wu;Siqing Xia;Jianfu Zhao.Cr(Ⅵ) removal from aqueous solution with bamboo charcoal chemically modified by iron and cobalt with the assistance of microwave[J].环境科学学报(英文版),2013(09):1726-1735.
[13] Su YuhFan;Cheng YuLing;Shih YangHsin.Removal of trichloroethylene by zerovalent iron/activated carbon derived from agricultural wastes.[J].Journal of Environmental Management,2013:361-366.
[14] Yanmei Zhou;Bin Gao;Andrew R. Zimmerman;Hao Chen;Ming Zhang;Xinde Cao.Biochar-supported zerovalent iron for removal of various contaminants from aqueous solutions[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2014:538-542.
[15] Dinesh Mohan;Hemant Kumar;Ankur Sarswat.Cadmium and lead remediation using magnetic oak wood and oak bark fast pyrolysis bio-chars[J].Chemical engineering journal,2014:513-528.
[16] Mohan, Dinesh;Singh, Prachi;Sarswat, Ankur;Steele, Philip H.;Pittman, Charles U., Jr..Lead sorptive removal using magnetic and nonmagnetic fast pyrolysis energy cane biochars[J].Journal of Colloid and Interface Science,2015:238-250.
[17] Ngarmkam, Worawan;Sirisathitkul, Chitnarong;Phalakornkule, Chantaraporn.Magnetic composite prepared from palm shell-based carbon and application for recovery of residual oil from POME[J].Journal of Environmental Management,20113(3):472-479.
[18] Tahereh Rohani Bastami;Mohammad H. Entezari.Activated carbon from carrot dross combined with magnetite nanoparticles for the efficient removal of p-nitrophenol from aqueous solution[J].Chemical engineering journal,2012:510-519.
[19] Nethaji, S.;Sivasamy, A.;Mandal, A.B..Preparation and characterization of corn cob activated carbon coated with nano-sized magnetite particles for the removal of Cr(VI)[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2013:94-100.
[20] Baig, Shams Ali;Zhu, Jin;Muhammad, Niaz;Sheng, Tiantian;Xu, Xinhua.Effect of synthesis methods on magnetic Kans grass biochar for enhanced As(III, V) adsorption from aqueous solutions[J].Biomass & Bioenergy,2014:299-310.
[21] 孟冠华;李爱民;张全兴.活性炭的表面含氧官能团及其对吸附影响的研究进展[J].离子交换与吸附,2007(1):88-94.
[22] Zhengang Liu;Fu-Shen Zhang;Ryo Sasai.Arsenate removal from water using Fe3O4-loaded activated carbon prepared from waste biomass[J].Chemical engineering journal,20101(1):57-62.
[23] N.M. Mubarak;A. Kundu;J.N. Sahu;E.C. Abdullah;N.S. Jayakumar.Synthesis of palm oil empty fruit bunch magnetic pyrolytic char impregnating with FeCl_3 by microwave heating technique[J].Biomass & Bioenergy,2014:265-275.
[24] C.O. Ania;J.B. Parra;J.A. Menendez;J.J. Pis.Microwave-assisted regeneration of activated carbons loaded with pharmaceuticals[J].Water research: A journal of the international water association,200715(15):3299-3306.
[25] 赵希强;宋占龙;王涛;李龙之;马春元.微波技术用于热解的研究进展[J].化工进展,2008(12):1873-1877,1881.
[26] 陆海楠;胡学玉;刘红伟.不同裂解条件对生物炭稳定性的影响[J].环境科学与技术,2013(8):11-14.
[27] Wang, Shengsen;Gao, Bin;Zimmerman, Andrew R.;Li, Yuncong;Ma, Lena;Harris, Willie G.;Migliaccio, Kati W..Removal of arsenic by magnetic biochar prepared from pinewood and natural hematite[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2015:391-395.
[28] Lili Yan;Long Kong;Zan Qu.Magnetic Biochar Decorated with ZnS Nanocrytals for Pb (II) Removal[J].ACS Sustainable Chemistry & Engineering,20151(1):125-132.
[29] N. M. MUBARAK;M. RUTHIRAAN;J. N. SAHU;E. C. ABDULLAH;N. S. JAYAKUMAR;N. R. SAJUNI;J. TAN.ADSORPTION AND KINETIC STUDY ON Sn~(2+) REMOVAL USING MODIFIED CARBON NANOTUBE AND MAGNETIC BIOCHAR[J].International journal of nanoscience,20136(6):1350044-1-1350044-14.
[30] Dinesh Mohan;Ankur Sarswat;Vinod K. Singh.Development of magnetic activated carbon from almond shells for trinitrophenol removal from water[J].Chemical engineering journal,20112/3(2/3):1111-1125.
[31] Han, Zhantao;Sani, Badruddeen;Mrozik, Wojciech;Obst, Martin;Beckingham, Barbara;Karapanagioti, Hrissi K.;Werner, David.Magnetite impregnation effects on the sorbent properties of activated carbons and biochars[J].Water research: A journal of the international water association,2015Mar.1(Mar.1):394-403.
[32] Gu, L.;Zhu, N.;Zhang, D.;Lou, Z.;Yuan, H.;Zhou, P..A comparative study of aerobically digested and undigested sludge in preparation of magnetic chars and their application in 1-diazo-2-naphthol-4-sulfonic acid adsorption[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2013:719-724.
[33] Xiangdong Zhu;Yuchen Liu;Chao Zhou.Novel and High-Performance Magnetic Carbon Composite Prepared from Waste Hydrochar for Dye Removal[J].ACS Sustainable Chemistry & Engineering,20144(4):969-977.
[34] Devi, Parmila;Saroha, Anil K..Simultaneous adsorption and dechlorination of pentachlorophenol from effluent by Ni-ZVI magnetic biochar composites synthesized from paper mill sludge[J].Chemical engineering journal,2015:195-203.
[35] Yan, Jingchun;Han, Lu;Gao, Weiguo;Xue, Song;Chen, Mengfang.Biochar supported nanoscale zerovalent iron composite used as persulfate activator for removing trichloroethylene[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2015:269-274.
[36] Kastner, James R.;Mani, Sudhagar;Juneja, Ankita.Catalytic decomposition of tar using iron supported biochar[J].Fuel Processing Technology,2015:31-37.
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