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透明导电薄膜在现代电子领域有着非常广泛的应用.我们利用简单的液面沉积法在柔性基底PET上成功制备了氧化石墨烯薄膜,在室温下经过碘化氢(HI)蒸汽还原后得到石墨烯透明导电薄膜.利用各种表征手段(SEM、TEM、AFM、吸收光谱(UV-Vis)和电阻分析(四探针法))系统的研究了不同沉积层数的石墨烯薄膜的透光性和导电性之间的关系:随着石墨烯沉积层数的增加,导电薄膜的导电性上升,但薄膜的透光率下降.在透光率(λ=550 nm)为82.22%时,导电薄膜的方块电阻为620Ω/□.

Transparent conductive film are widely used in electronics industry.Here we reported the Graphene oxide thin films were prepared on flexible substrates PET by liquid deposition method,the graphene transpar-ent conductive film were achieved after hydrogen iodide (HI)vapour reduction at room temperature.Several kinds of characterization (including SEM,TEM,AFM,UV-Vis and resistance analysis (four-probe method)) were employed to study the relationship between transmittance and conductivity with different deposited layers of graphene films.The results show that the conductive of the graphene film will be increased with the more layers of deposited graphene,but the light transmittance of films decreased.The conductivity of the graphene transparent film was 620 Ω/□ with 82.22% in light transmittance (λ=550 nm)were achieved.

参考文献

[1] Shuping Pang;Yenny Hernandez;Xinliang Feng;Klaus Mullen.Craphene as Transparent Electrode Material for Organic Electronics[J].Advanced Materials,201125(25):2779-2795.
[2] David S. Hecht;Liangbing Hu;Glen I ruin.Emerging Transparent Electrodes Based on Thin Films of Carbon Nanotubes, Graphene, and Metallic Nanostructures[J].Advanced Materials,201113(13):1482-1513.
[3] Bae, S.;Kim, H.;Lee, Y.;Xu, X.;Park, J.-S.;Zheng, Y.;Balakrishnan, J.;Lei, T.;Ri Kim, H.;Song, Y.I.;Kim, Y.-J.;Kim, K.S.;?zyilmaz, B.;Ahn, J.-H.;Hong, B.H.;Iijima, S..Roll-to-roll production of 30-inch graphene films for transparent electrodes[J].Nature nanotechnology,20108(8):574-578.
[4] Chang, Haixin;Wang, Guangfeng;Yang, An;Tao, Xiaoming;Liu, Xuqing;Shen, Youde;Zheng, Zijian.A Transparent, Flexible, Low-Temperature, and Solution-Processible Graphene Composite Electrode[J].Advanced functional materials,201017(17):2893-2902.
[5] Eda G;Fanchini G;Chhowalla M.Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material[J].Nature nanotechnology,20085(5):270-274.
[6] Liu, H.;Avrutin, V.;Izyumskaya, N.;?zgr, ?.;Morko?, H..Transparent conducting oxides for electrode applications in light emitting and absorbing devices[J].Superlattices and microstructures,20105(5):458-484.
[7] Wang X;Zhi LJ;Mullen K.Transparent, conductive graphene electrodes for dye-sensitized solar cells[J].Nano letters,20081(1):323-327.
[8] Qing Bin Zheng;Mohsen Moazzami Gudarzi;Shu Jun Wang.Improved electrical and optical characteristics of transparent graphene thin films produced by acid and doping treatments[J].Carbon: An International Journal Sponsored by the American Carbon Society,20119(9):2905-2916.
[9] Hailin Peng;Wenhui Dang;Jie Cao.Topological insulator nanostructures for near-infrared transparent flexible electrodes[J].Nature Chemistry,20124(4):281-286.
[10] Yong Hyun Kim;Christoph Sachse;Michael L. Machala;Christian May;Lars M tiller-Meskamp;Karl Leo.Highly Conductive PEDOT:PSS Electrode with Optimized Solvent and Thermal Post-Treatment for ITO-Free Organic Solar Cells[J].Advanced functional materials,20116(6):1076-1081.
[11] Desalegn Alemu;Hung-Yu Wei;Kuo-Chuan Ho;Chih-Wei Chu.Highly conductive PEDOT:PSS electrode by simple film treatment with methanol for ITO-free polymer solar cells[J].Energy & environmental science: EES,201211(11):9662-9671.
[12] Cho, C.-K.;Hwang, W.-J.;Eun, K.;Choa, S.-H.;Na, S.-I.;Kim, H.-K..Mechanical flexibility of transparent PEDOT:PSS electrodes prepared by gravure printing for flexible organic solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,201112(12):3269-3275.
[13] Wu ZC;Chen ZH;Du X;Logan JM;Sippel J;Nikolou M;Kamaras K.Transparent, conductive carbon nanotube films[J].Science,20045688(5688):1273-1276.
[14] Hu, L.;Hecht, D.S.;Grüner, G..Carbon nanotube thin films: Fabrication, properties, and applications[J].Chemical Reviews,201010(10):5790-5844.
[15] Zhibin Yu;Qingwu Zhang;Lu Li;Qi Chen;Xiaofan Niu;Jun Liu;Qibing Pei.Highly Flexible Silver Nanowire Electrodes for Shape- Memory Polymer Light-Emitting Diodes[J].Advanced Materials,20115(5):664-668.
[16] De, S.;Higgins, T.M.;Lyons, P.E.;Doherty, E.M.;Nirmalraj, P.N.;Blau, W.J.;Boland, J.J.;Coleman, J.N..Silver nanowire networks as flexible, transparent, conducting films: Extremely high DC to optical conductivity ratios[J].ACS nano,20097(7):1767-1774.
[17] Mikkel Jorgensen;Kion Norrrnan;Suren A. Gevorgyan;Thomas Tromholt;Birgitta Andreasen;Frederik C. Krebs.Stability of Polymer Solar Cells[J].Advanced Materials,20125(5):580-612.
[18] Geim AK;Novoselov KS.The rise of graphene[J].Nature materials,20073(3):183-191.
[19] Kuzmenko AB;van Heumen E;Carbone F;van der Marel D.Universal optical conductance of graphite[J].Physical review letters,200811(11):117401-1-117401-4-0.
[20] Berger, C;Song, ZM;Li, XB;Wu, XS;Brown, N;Naud, C;Mayo, D;Li, TB;Hass, J;Marchenkov, AN.Electronic confinement and coherence in patterned epitaxial graphene[J].Science,20065777(5777):1191-1196.
[21] Reina A;Jia XT;Ho J;Nezich D;Son HB;Bulovic V;Dresselhaus MS;Kong J.Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition[J].Nano letters,20091(1):30-35.
[22] Dongsheng Li;Wolfgang Windl;Nitin P. Padture.Toward Site-specific Stamping Of Graphene[J].Advanced Materials,200912(12):1243-1246.
[23] Keun Soo Kim;Yue Zhao;Houk Jang;Sang Yoon Lee;Jong Min Kim;Kwang S. Kim;Jong-Hyun Ann;Philip Kim;Jae-Young Choi;Byung Hee Hong.Large-scale Pattern Growth Of Graphene Films For Stretchable Transparent Electrodes[J].Nature,20097230(7230):706-710.
[24] Zheng, Q.;Ip, W.H.;Lin, X.;Yousefi, N.;Yeung, K.K.;Li, Z.;Kim, J.-K..Transparent conductive films consisting of ultralarge graphene sheets produced by Langmuir-Blodgett assembly[J].ACS nano,20117(7):6039-6051.
[25] Yanwu Zhu;Shanthi Murali;Weiwei Cai;Xuesong Li;Ji Won Suk;Jeffrey R. Potts;Rodney S. Ruoff.Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J].Advanced Materials,201035(35):3906-3924.
[26] Steurer, P;Wissert, R;Thomann, R;Mulhaupt, R.Functionalized Graphenes and Thermoplastic Nanocomposites Based upon Expanded Graphite Oxide[J].Macromolecular rapid communications,20094/5(4/5):316-327.
[27] Dongxing Yang;Aruna Velamakanni;Gulay Bozoklu.Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy[J].Carbon: An International Journal Sponsored by the American Carbon Society,20091(1):145-152.
[28] Guoxiu Wang;Bei Wang;Jinsoo Park.Synthesis of enhanced hydrophilic and hydrophobic graphene oxide nanosheets by a solvothermal method[J].Carbon: An International Journal Sponsored by the American Carbon Society,20091(1):68-72.
[29] Cote, LJ;Kim, F;Huang, JX.Langmuir-Blodgett Assembly of Graphite Oxide Single Layers[J].Journal of the American Chemical Society,20093(3):1043-1049.
[30] Franklin Kim;Laura J. Cote;Jiaxing Huang.Graphene Oxide: Surface Activity and Two-Dimensional Assembly[J].Advanced Materials,201017(17):1954-1958.
[31] Supinda Watcharotone;Dmitriy A. Dikin;Sasha Stankovich.Graphene-Silica Composite Thin Films as Transparent Conductors[J].Nano letters,20077(7):1888-1892.
[32] Blake P;Brimicombe PD;Nair RR;Booth TJ;Jiang D;Schedin F;Ponomarenko LA;Morozov SV;Gleeson HF;Hill EW.Graphene-based liquid crystal device[J].Nano letters,20086(6):1704-1708.
[33] Shu Jun Wang;Yan Geng;Qingbin Zheng.Fabrication of highly conducting and transparent graphene films[J].Carbon: An International Journal Sponsored by the American Carbon Society,20106(6):1815-1823.
[34] Vincent Lee;Luisa Whittaker;Cherno Jaye.Large-Area Chemically Modified Graphene Films: Electrophoretic Deposition and Characterization by Soft X-ray Absorption Spectroscopy[J].Chemistry of Materials: A Publication of the American Chemistry Society,200916(16):3905-3916.
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