石墨烯具有独特的结构和优异的物理、化学性能，其作为水处理材料的应用前景值得期待。本文介绍了石墨烯、氧化石墨烯及还原氧化石墨烯材料与水处理相关的主要性能，对石墨烯及其衍生物吸附重金属离子及有机物的研究及进展进行了综述，分析了相关的研究机理及主要影响因素；对各种石墨烯复合材料在水处理方面的研究逐一进行了介绍，包括磁性及非磁性石墨烯复合材料、石墨烯光催化复合材料；最后对该研究领域存在的问题及面临的挑战进行了分析，并对该领域研究发展趋势进行了展望。
Graphene is of a unique structure and has excellent physical and chemical properties,so it could be a promising material for water treatment.In this paper,the main properties of graphene,graphene oxide and re-duced graphene oxide related to water treatment were introduced,the recent progress for adsorption of heavy metal ions and organic compounds by graphene and its derivatives was reviewed,and the related adsorption mechanisms and the main factors influencing adsorption for the adsorbents were analyzed.The applications of kinds of graphene composites for water treatment were introduced one by one,including magnetic graphene composites,non-magnetic graphene composites,and photocatalytic graphene composites.Finally,the problems and challenges related to the researches on graphene materials for water treatment were analyzed and the trends of this research field were predicted.
参考文献
| [1] | R. Haberl.Constructed wetlands: a chance to solve wastewater problems in developing countries[J].Water Science and Technology,19993(3):11-17. |
| [2] | Vandenbossche, M.;Casetta, M.;Jimenez, M.;Bellayer, S.;Traisnel, M..Cysteine-grafted nonwoven geotextile: a new and efficient material for heavy metals sorption - Part A.[J].Journal of Environmental Management,2014:107-112. |
| [3] | 肖蓝;王祎龙;于水利;唐玉霖.石墨烯及其复合材料在水处理中的应用[J].化学进展,2013(2):419-430. |
| [4] | Quanjun Xiang;Jiaguo Yu;Mietek Jaroniec.Graphene-based semiconductor photocatalysts[J].Chemical Society Reviews,20122(2):782-796. |
| [5] | Compton, OC;Nguyen, ST.Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials[J].Small,20106(6):711-723. |
| [6] | Songfeng Pei;Hui-Ming Cheng.The reduction of graphene oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,20129(9):3210-3228. |
| [7] | Akbar Bagri;Cecilia Mattevi;Muge Acik.Structural evolution during the reduction of chemically derived graphene oxide[J].Nature Chemistry,20107(7):581-587. |
| [8] | Hua Bai;Chun Li;Gaoquan Shi.Functional Composite Materials Based on Chemically Converted Graphene[J].Advanced Materials,20119(9):1089-1115. |
| [9] | Sitko, R.;Turek, E.;Zawisza, B.;Malicka, E.;Talik, E.;Heimann, J.;Gagor, A.;Feist, B.;Wrzalik, R..Adsorption of divalent metal ions from aqueous solutions using graphene oxide[J].Dalton transactions: An international journal of inorganic chemistry,201316(16):5682-5689. |
| [10] | Huang, Z.-H.;Zheng, X.;Lv, W.;Wang, M.;Yang, Q.-H.;Kang, F..Adsorption of lead(II) ions from aqueous solution on low-temperature exfoliated graphene nanosheets[J].Langmuir: The ACS Journal of Surfaces and Colloids,201112(12):7558-7562. |
| [11] | Hou Wang;Xingzhong Yuan;Yan Wu;Huajun Huang;Guangming Zeng;Yan Liu;Xueli Wang;Ningbo Lin;Yu Qi.Adsorption characteristics and behaviors of graphene oxide for Zn(Ⅱ) removal from aqueous solution[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013Aug.15(Aug.15):432-440. |
| [12] | M. Machida;T. Mochimaru;H. Tatsumoto.Lead(II) adsorption onto the graphene layer of carbonaceous materials in aqueous solution[J].Carbon: An International Journal Sponsored by the American Carbon Society,200613(13):2681-2688. |
| [13] | Clemonne J. Madadrang;Hyun Yun Kim;Guihua Gao.Adsorption Behavior of EDTA-Graphene Oxide for Pb (II) Removal[J].ACS applied materials & interfaces,20123(3):1186-1193. |
| [14] | Liu, L.;Li, C.;Bao, C.;Jia, Q.;Xiao, P.;Liu, X.;Zhang, Q..Preparation and characterization of chitosan/graphene oxide composites for the adsorption of Au(III) and Pd(II)[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2012:350-357. |
| [15] | Wu, Y.;Luo, H.;Wang, H.;Wang, C.;Zhang, J.;Zhang, Z..Adsorption of hexavalent chromium from aqueous solutions by graphene modified with cetyltrimethylammonium bromide[J].Journal of Colloid and Interface Science,2013:183-191. |
| [16] | Han Yan;Xue Tao;Zhen Yang;Kun Li;Hu Yang;Aimin Li;Rongshi Cheng.Effects of the oxidation degree of graphene oxide on the adsorption of methylene blue[J].Journal of hazardous materials,2014Mar.15(Mar.15):191-198. |
| [17] | Caili Zhang;Lin Wu;Dongqing Cai.Adsorption of Polycyclic Aromatic Hydrocarbons (Fluoranthene and Anthracenemethanol) by Functional Graphene Oxide and Removal by pH and Temperature-Sensitive Coagulation[J].ACS applied materials & interfaces,201311(11):4783-4790. |
| [18] | Li, J.;Wang, F.;Liu, C.-Y..Tri-isocyanate reinforced graphene aerogel and its use for crude oil adsorption[J].Journal of Colloid and Interface Science,2012:13-16. |
| [19] | Yang, K.;Xing, B..Adsorption of organic compounds by carbon nanomaterials in aqueous phase: Polanyi theory and its application[J].Chemical Reviews,201010(10):5989-6008. |
| [20] | Yang, S.-T.;Chen, S.;Chang, Y.;Cao, A.;Liu, Y.;Wang, H..Removal of methylene blue from aqueous solution by graphene oxide[J].Journal of Colloid and Interface Science,20111(1):24-29. |
| [21] | Jing Xu;Li Wang;Yongfa Zhu.Decontamination of Bisphenol A from Aqueous Solution by Graphene Adsorption[J].Langmuir: The ACS Journal of Surfaces and Colloids,201222(22):8418-8425. |
| [22] | Fang Wang;Joris J.-H. Haftka;Theo L. Sinnige;Joop L.M. Hermens;Wei Chen.Adsorption of polar, nonpolar, and substituted aromatics to colloidal graphene oxide nanoparticles[J].Environmental Pollution,2014Mar.(Mar.):226-233. |
| [23] | Zhiguo Pei;Lingyun Li;Lixiang Sun.Adsorption characteristics of 1,2,4-trichlorobenzene, 2,4,6-trichlorophenol, 2-naphthol and naphthalene on graphene and graphene oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:156-163. |
| [24] | Onur Guven Apul;Qilicmg Wang;Yang Zhou;Tanju Karanfil.Adsorption of aromatic organic contaminants by graphene nanosheets: Comparison with carbon nanotubes and activated carbon[J].Water research: A journal of the international water association,20134(4):1648-1654. |
| [25] | Jun Wang;Zaiming Chen;Baoliang Chen.Adsorption of Polycyclic Aromatic Hydrocarbons by Graphene and Graphene Oxide Nanosheets[J].Environmental Science & Technology: ES&T,20149(9):4817-4825. |
| [26] | Ting Wu;Xiang Cai;Shaozao Tan.Adsorption characteristics of acrylonitrile, p-toluenesulfonic acid, 1-naphthalenesulfonic acid and methyl blue on graphene in aqueous solutions[J].Chemical engineering journal,20111(1):144-149. |
| [27] | Ramesha, G.K.;Vijaya Kumara, A.;Muralidhara, H.B.;Sampath, S..Graphene and graphene oxide as effective adsorbents toward anionic and cationic dyes[J].Journal of Colloid and Interface Science,20111(1):270-277. |
| [28] | Chandra, V.;Park, J.;Chun, Y.;Lee, J.W.;Hwang, I.-C.;Kim, K.S..Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal[J].ACS nano,20107(7):3979-3986. |
| [29] | Pengfei Zong;Shoufang Wang;Yaolin Zhao.Synthesis and application of magnetic graphene/iron oxides composite for the removal of U(VI) from aqueous solutions[J].Chemical engineering journal,2013:45-52. |
| [30] | Wu, Q.;Zhao, G.;Feng, C.;Wang, C.;Wang, Z..Preparation of a graphene-based magnetic nanocomposite for the extraction of carbamate pesticides from environmental water samples[J].Journal of chromatography, A: Including electrophoresis and other separation methods,201144(44):7936-7942. |
| [31] | Mancheng Liu;Changlun Chen;Jun Hu.Synthesis of Magnetite/Graphene Oxide Composite and Application for Cobalt(II) Removal[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201151(51):25234-25240. |
| [32] | Liu, M.;Wen, T.;Wu, X.;Chen, C.;Hu, J.;Li, J.;Wang, X..Synthesis of porous Fe_3O_4 hollow microspheres/ graphene oxide composite for Cr(vi) removal[J].Dalton transactions: An international journal of inorganic chemistry,201341(41):14710-14717. |
| [33] | Wenjing Zhang;Xinhao Shi;Yixuan Zhang.Synthesis of water-soluble magnetic graphene nanocomposites for recyclable removal of heavy metal ions[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20135(5):1745-1753. |
| [34] | Fuan He;Jintu Fan;Dong Ma.The attachment of Fe3O4 nanoparticles to graphene oxide by covalent bonding[J].Carbon: An International Journal Sponsored by the American Carbon Society,201011(11):3139-3144. |
| [35] | Hao, L.;Song, H.;Zhang, L.;Wan, X.;Tang, Y.;Lv, Y..SiO _2/graphene composite for highly selective adsorption of Pb(II) ion[J].Journal of Colloid and Interface Science,2012:381-387. |
| [36] | Jinfeng Wang;Takuya Tsuzuki;Bin Tang.Reduced Graphene Oxide/ZnO Composite: Reusable Adsorbent for Pollutant Management[J].ACS applied materials & interfaces,20126(6):3084-3090. |
| [37] | Mykola Seredych;Teresa J. Bandosz.Manganese oxide and graphite oxide/MnO2 composites as reactive adsorbents of ammonia at ambient conditions[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2012:55-63. |
| [38] | Enmin Zong;Dan Wei;Haiqin Wan.Adsorptive removal of phosphate ions from aqueous solution using zirconia-functionalized graphite oxide[J].Chemical engineering journal,2013:193-203. |
| [39] | Zhao, Z.-Q.;Chen, X.;Yang, Q.;Liu, J.-H.;Huang, X.-J..Selective adsorption toward toxic metal ions results in selective response: Electrochemical studies on a polypyrrole/reduced graphene oxide nanocomposite[J].Chemical communications,201216(16):2180-2182. |
| [40] | Baojun Li;Huaqiang Cao;Gui Yin.Cu2O@reduced graphene oxide composite for removal of contaminants from water and supercapacitors[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201129(29):10645-10648. |
| [41] | Zhang, H.;Lv, X.;Li, Y.;Wang, Y.;Li, J..P25-graphene composite as a high performance photocatalyst[J].ACS nano,20101(1):380-386. |
| [42] | Seema, H.;Christian Kemp, K.;Chandra, V.;Kim, K.S..Graphene-SnO _2 composites for highly efficient photocatalytic degradation of methylene blue under sunlight[J].Nanotechnology,201235(35):355705-1-355705-8. |
| [43] | Yan Yan;Shaofang Sun;Yang Song;Xu Yan;Weisheng Guan;Xinlin Liu;Weidong Shi.Microwave-assisted in situ synthesis of reduced graphene oxide-BiVO_4 composite photocatalysts and their enhanced photocatalytic performance for the degradation of ciprofloxacin[J].Journal of hazardous materials,2013Apr.15(Apr.15):106-114. |
| [44] | Jintao Zhang;Zhigang Xiong;X. S. Zhao.Graphene-metal-oxide composites for the degradation of dyes under visible light irradiation[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201111(11):3634-3640. |
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