近年来，磁性纳米粒子和镧系稀土荧光材料因其独特的荧光性能和磁学性能而引起广大研究者的兴趣。然而，随着生物科技的发展与进步，单一功能的材料已经不能满足实验研究的需求。因此，兼具磁性荧光双功能的复合材料备受关注。综述了不同稀土荧光基质的磁性荧光纳米复合材料的研究进展，主要总结了以 Fe3 O4纳米粒子为磁性核，镧系稀土离子掺杂化合物为荧光壳的磁性荧光纳米复合材料的制备方法，复合方式以及性能特点等。通过对磁性荧光双功能材料的研究，对于促进生物，医学等科学领域的发展具有重大意义。
In recent years,magnetic nanoparticles and lanthanum rare earth fluorescent materials have been a-roused a wide range of the researchers'interest because of their unique magnetic and fluorescent properties. However,with the development of biological science and technology,materials with single function have failed to meet the needs of experimental research.Therefore,the materials with both magnetic and fluorescent proper-ties have attracted much attention.This paper summarizes the research progress of magnetic-fluorescent,which was about different rare-earth fluorescent host-based nanocomposites,mainly introduced the preparation meth-ods,composite way and performance characterization of the magnetic-fluorescent nanocomposites,which Fe3 O4 nanoparticle was used as the magnetic core and lanthanum rare-earth doping nanoparticles were used as the fluo-rescent shell.The research based on the bifunctional nanoparticles with both magnetic and fluorescent proper-ties,which will play a key role in promoting the development in the field of biological,medical and so on.
参考文献
| [1] | Schladt, T.D.;Schneider, K.;Schild, H.;Tremel, W..Synthesis and bio-functionalization of magnetic nanoparticles for medical diagnosis and treatment[J].Dalton transactions: An international journal of inorganic chemistry,201124(24):6315-6343. |
| [2] | Chun Wang;Cheng Feng;Yongjun Gao.Preparation of a graphene-based magnetic nanocomposite for the removal of an organic dye from aqueous solution[J].Chemical engineering journal,20111(1):92-97. |
| [3] | Lunhong Ai;Chunying Zhang;Fang Liao;Yao Wang;Ming Li;Lanying Meng;Jing jiang.Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: Kinetic, isotherm and mechanism analysis[J].Journal of hazardous materials,2011:282-290. |
| [4] | Ma, J.;Fan, Q.;Wang, L.;Jia, N.;Gu, Z.;Shen, H..Synthesis of magnetic and fluorescent bifunctional nanocomposites and their applications in detection of lung cancer cells in humans[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,20104/5(4/5):1162-1169. |
| [5] | Zhu, LW;Chen, P;Guo, Y;Song, YY;Xue, XD;Cao, XB.Ternary ZnO/ZnS/gamma-Fe2O3 hollow sphere with surface hole: Microwave-enhanced rapid synthesis, bifunctional property, and immobilization of serum protein[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,20101/3(1/3):111-119. |
| [6] | Weesiong Chiu;Poisim Khiew;Michael Cloke.Heterogeneous Seeded Growth: Synthesis and Characterization of Bifunctional Fe3O4/ZnO Core/Shell Nanocrystals[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201018(18):8212-8218. |
| [7] | Yang P;Quan Z;Hou Z.A magnetic, luminescent and mesoporous core-shell structured composite material as drug carrier.[J].Biomaterials,200927(27):4786-4795. |
| [8] | Gonzalez-Fernandez, MA;Torres, TE;Andres-Verges, M;Costo, R;de la Presa, P;Serna, CJ;Morales, MR;Marquina, C;Ibarra, MR;Goya, GF.Magnetic nanoparticles for power absorption: Optimizing size, shape and magnetic properties[J].Journal of Solid State Chemistry,200910(10):2779-2784. |
| [9] | Grasset F;Dorson F;Molard Y;Cordier S;Demange V;Perrin C;Marchi-Artzner V;Haneda H.One-pot synthesis and characterizations of bi-functional phosphor-magnetic @SiO2 nanoparticles: controlled and structured association of Mo-6 cluster units and gamma-Fe2O3 nanocrystals[J].Chemical communications,200839(39):4729-4731. |
| [10] | Lu HC;Yi GS;Zhao SY;Chen DP;Guo LH;Cheng J.Synthesis and characterization of multi-functional nanoparticles possessing magnetic, up-conversion fluorescence and bio-affinity properties[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,20048(8):1336-1341. |
| [11] | Ping Li;Yanhui Song;Chengguo Liu;Xiaoming Li;Gang Zhou;Yubo Fan.Magnetic and fluorescent bifunctional chitosan microspheres embedding with fluorescent-labeling drug as a drug delivery system[J].Materials Letters,2014Jan.1(Jan.1):132-135. |
| [12] | Pankhurst QA.;Connolly J.;Jones SK.;Dobson J..Applications of magnetic nanoparticles in biomedicine [Review][J].Journal of Physics, D. Applied Physics: A Europhysics Journal,200313(13):R167-R181. |
| [13] | Harisinghani MG;Barentsz J;Hahn PF;Deserno WM;Tabatabaei S;van-de-Kaa CH;de-la-Rosette J;Weissleder R.Noninvasive detection of clinically occult lymph-node metastases in prostate cancer.[J].The New England journal of medicine,200325(25):2491-2499. |
| [14] | Peng, Hongxia;Cui, Bin;Li, Guangming;Wang, Yingsai;Li, Nini;Chang, Zhuguo;Wang, Yaoyu.A multifunctional beta-CD-modified Fe3O4@ZnO:Er3+,Yb3+ nanocarrier for antitumor drug delivery and microwave-triggered drug release[J].Materials science & engineering, C. Materials for Biogical applications,2015:253-263. |
| [15] | Kaittanis C;Naser SA;Perez JM.One-step, nanoparticle-mediated bacterial detection with magnetic relaxation[J].Nano letters,20072(2):380-383. |
| [16] | Jean-Christophe Leroux.Injectable nanocarriers for biodetoxification[J].Nature nanotechnology,200711(11):679-684. |
| [17] | 孙巍;李真;吴松海;贾绍义.磁分离技术在污水处理中的应用[J].磁性材料及器件,2006(4):6-10,24. |
| [18] | Bruchez,M Jr;Moronne,M;Gin,P;Weiss,S;Alivisatos,AP.Semiconductor nanocrystals as fluorescent biological labels (see comments)[J].Science,19985385(5385):2013-2016. |
| [19] | Wang, H;Yang, J;Zhang, CM;Lin, J.Synthesis and characterization of monodisperse spherical SiO2@RE2O3 (RE = rare earth elements) and SiO2@Gd2O3:Ln(3+) (Ln = Eu, Tb, Dy, Sm, Er, Ho) particles with core-shell structure[J].Journal of Solid State Chemistry,200910(10):2716-2724. |
| [20] | Shili Gai;Piaoping Yang;Jingai Hao.Fabrication of luminescent and mesoporous core-shell structured nanocomposites and their application as drug carrier[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,20101/3(1/3):128-135. |
| [21] | Wang, Q.;Qiu, J. B.;Song, Z. G.;Yang, Z. W.;Yin, Z. Y.;Zhou, D. C..Optical properties of Ce3+-Nd3+ co-doped YAG nanoparticles for visual and near-infrared biological imaging[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2015:898-903. |
| [22] | Fang, J;Saunders, M;Guo, YL;Lu, GZ;Raston, CL;Iyer, KS.Green light-emitting LaPO4 : Ce3+:Tb3+ koosh nanoballs assembled by p-sulfonato-calix[6]arene coated superparamagnetic Fe3O4[J].Chemical communications,201018(18):3074-3076. |
| [23] | Zhiwei Sun;Deming Liu;Lizhu Tong.Synthesis and properties of magnetic and luminescent Fe_3O_4/SiO_2/YVO_4:Eu~(3+) nanocomposites[J].Solid state sciences,20112(2):361-365. |
| [24] | Nam-Hyuk Cho;Taek-Chin Cheong;Ji HyunMin;Jun HuaWu;Sang Jin Lee;Daehong Kim;Jae-Seong Yang;Sanguk Kim;Young Keun Kim;Seung-Yong Seong.A multifunctional core-shell nanoparticle for dendritic cell-based cancer immunotherapy[J].Nature nanotechnology,201110(10):675-682. |
| [25] | Synthesis of Magnetic, Up-Conversion Luminescent,and Mesoporous Core-Shell-Structured Nanocomposites as Drug Carriers[J].Advanced functional materials,20107(7):1166. |
| [26] | Hongxia Peng;Bin Cui;Leilei Li.A simple approach for the synthesis of bifunctional Fe_3O_4@Gd_2O_3:Eu~(3+) core-shell nanocomposites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2012:30-33. |
| [27] | Hongxia Peng;Bin Cui;Yingsai Wang.Bifunctional Fe_3O_4@Gd_2O_3:Eu~(3+)nanocomposites obtained by the homogeneous precipitation method[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,20135(5):1767-1771. |
| [28] | Zhi Ya Ma;Dosi Dosev;Mikaela Nichkova.Synthesis and bio-functionalization of multifunctional magnetic Fe3O4@Y2O3:Eu nanocomposites[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200927(27):4695-4700. |
| [29] | Lizhu Tong;Jianhui Shi;Deming Liu.Luminescent and Magnetic Properties of Fe3O4@SiO2@Y2O3:Eu~(3+) Composites with Core-Shell Structure[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201212(12):7153-7157. |
| [30] | Jingxing Yang;Xuwei Yang;Hua Yang.Preparation and properties of multifunctional Fe@C@Y_2O_3:Eu~(3+) nanocomposites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20121(1):190-194. |
| [31] | Tong, L.;Shi, J.;Ren, X.;Li, Q.;Ding, H.;Yang, H..Multifunctional nanocomposites with different coupling agents: Synthesis, luminescent and magnetic properties[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,20135(5):1627-1-1627-9. |
| [32] | Lizhu Tong;Xiaozhen Ren;Xiaodong Chen.Magnetic and luminescent Fe3O4/Y2O3:Eu~(3+) composites with hollow spheres and mesoporous silica[J].Dyes and Pigments,2014:182-187. |
| [33] | Lizhu Tong;Xuefeng Ding;Xiaozhen Ren.Double-shell structured nanocomposites with magnetic and fluorescent properties[J].Dyes and Pigments,2015:117-120. |
| [34] | Wang, W.;Zou, M.;Chen, K..Novel Fe_3O_4@YPO_4:Re (Re = Tb, Eu) multifunctional magnetic-fluorescent hybrid spheres for biomedical applications[J].Chemical communications,201028(28):5100-5102. |
| [35] | Liu, Yanlin;Wang, Zhigang;Cheng, Gong;Zhang, Jilin;Hong, Guangyan;Ni, Jiazuan.Synthesis and characterization of Fe3O4@YPO4:Eu3+ multifunctional microspheres[J].Materials Letters,2015Aug.1(Aug.1):224-227. |
| [36] | Prasad, A.I.;Parchur, A.K.;Juluri, R.R.;Jadhav, N.;Pandey, B.N.;Ningthoujam, R.S.;Vatsa, R.K..Bi-functional properties of Fe_3O_4@YPO_4:Eu hybrid nanoparticles: Hyperthermia application[J].Dalton transactions: An international journal of inorganic chemistry,201314(14):4885-4896. |
| [37] | Zhiwei Sun;Lizhu Tong;Deming Liu.Preparation and properties of multifunctioeal Fe3O4 @YVO4:Eu~(3+) or Dy~(3+) core-shell eanocomposites as drug carriers[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201213(13):6280-6284. |
| [38] | Jianhui Shi;Deming Liu;Lizhu Tong.Magnetic and photoluminescence properties of Fe_3O_4@SiO_2@YP_(1-x)V_xO_4:Dy~(3+) nanocomposites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,201142(42):10211-10216. |
| [39] | Jianhui Shi;Lizhu Tong;Xiaozhen Ren;Quanhong Li;Hong Ding;Hua Yang.Bifunctional Fe_3O_4@C/YVO_4:Sm~(3+) composites with the core-shell structure[J].Materials Chemistry and Physics,20131(1):73-78. |
| [40] | Jianhui Shi;Lizhu Tong;Xiaozhen Ren.Multifuctional Fe_3O_4@C/YVO_4:Dy~ + nanopowers: Preparation, luminescence and magnetic properties[J].CERAMICS INTERNATIONAL,20136(6):6391-6397. |
| [41] | Quanhong Li;Xiaozhen Ren;Lizhu Tong.Deposition of luminescence YBO3:Eu~(3+),Gd~(3+) on ferromagnetic Fe@C nanoparticles[J].Dyes and Pigments,2014:161-165. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%