对双元氧化剂引起二元固溶合金在无外氧化膜条件下,发生两氧化剂分立内氧化层的现象作了重新审视.在摒弃前人某些假设并考虑可能出现的各种氧化膜结构的前提下,提出的理论模型可描述同时发生双元氧化与两者各自单独氧化时各氧化膜厚度之间的关系,双元氧化两内氧化层厚度比与它们的扩散系数的关系以及最活泼组元在界面富集的程度等.藉所提理论还讨论了迄今已报道的有关研究结果.
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