采用U型弯曲加载和模拟大气加速腐蚀试验方法及扫描电镜,研究了包铝的两种工业高强铝合金LY12和LC4在受力状态下的大气腐蚀行为.结果表明,两种铝合金基体在此模拟大气加速腐蚀试验环境中对晶间腐蚀和应力腐蚀裂开均敏感.晶间腐蚀从局部开始,逐渐向四周扩展.在发生晶间腐蚀部位出现垂直于受力方向的沿晶裂纹,并随试验时间延长裂纹也逐渐加长;合金板材表面具有约90μm厚的包铝层,除点蚀外,这层包铝层未出现其它形式的局部腐蚀,说明包铝层对铝合金基体起到了很好的保护作用.两种包铝高强铝合金板材在包铝层完好时均对晶间腐蚀和应力腐蚀裂开的敏感性差.
参考文献
[1] | Sedriks AJ, Green JAS, Novak DL. Staehle RW, Brown BF,Kruger J, et al. Localized Corrosion Agarwal[C]. Houston,TX: NACE International, 1971. 569. |
[2] | Davies DE, Dennison JP, Mehta ML, et al. International Conference on Localized Corrosion, National Association of Corrosion Engineers[C]. Houston, TX, 1971. 608. |
[3] | Guillaumin V, Schmutz P, Frankel GS. Characterization of corrosion interfaces by the scanning Kelvin probe force microscopy technique[J ]. Journal of the Electrochemical Society,2001,148(5) :B163. |
[4] | Ramgopal T, Gouma PI, Frankel GS. Role of grain - bonudary precipitates and solute - depleted zone on the intergranular corrosion of aluminum alloy 7150[J ]. Corrosion, 2002, 58(8) :687. |
[5] | LIU Xiaodong, ZHANG Weilong, Frankel Gerald S. A Symposium Honoring the Contributions of R. W. Staehle[ C]. The Minerals, Metals & Materials Society, Warrendale, Pennsylvania, U. S., 2001. 543. |
[6] | Leard RR, Buchheit RG. Electrochemical characterization of copper- bearing intermetallic compounds and localized corrosion of Al - Cu - Mg - Mn alloy 2024 [J ]. Materials Science Forum, 2002, 396 - 4:1491. |
[7] | Mikhailov AA, Mikhailovskii YN, Sharonovanf NF, et al. Atmospheric corrosion of metals and alloys at the Mirnyi station in Antarctica[J ]. Protection of Metals, 1993,29( 1 ): 8. |
[8] | 王云,甘株.2024铝合金型材在不同气候区的大气腐蚀行为[J].腐蚀科学与防护技术,1993,5(4):3040. |
[9] | Godard HP, Jepson WB, Bothwell MR, et al. The Corrosion of Light Metals[M]. J. Wiley and Sons Inc., New York, 1967.70. |
[10] | Buchheit RG, Grant RP, Hlava PF, et al. Local dissolution phenomena associated with S phase (Al2CuMg)particles in aluminum alloy 2024 - T3 [J ]. J. Eletrochem. Soc., 1997, 144(8) :2621. |
[11] | Galvele JR, Micheli SMDD. Mechanism of intergranular corrosion of Al- Cu alloys[J]. Corrosion Science, 1970, 10:795. |
[12] | Guillaumin V, Mankowski G. Localized corrosion of 2024T351 aluminium alloy in chloride media[J]. Corrosion Science, 1999, 41:421 |
[13] | Burleigh TD. The postulated mechanisms for stress corrosion cracking of aluminum alloys. Corrosion, 1991,47(2 ) :89. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%