采用电位-电容法及Mott-Schottky分析技术研究了自腐蚀电位条件下防锈油膜在5% Na2SO4溶液中失效过程的导电机制转变行为.防锈油膜在5% Na2SO4溶液中的失效过程存在半导体导电特征,随着浸泡时间的延长,防锈油膜从浸泡初期的p型半导体转变为n型半导体,转变过程中,防锈油膜中出现两个空间电荷过渡层.随着浸泡时间的延长,防锈油膜中的空间电荷层厚度皆逐渐减小,载流子密度则逐渐增加,并且计算了不同转变时期防锈油膜中的电子给体(ND)和电子受体(NA)密度大小.
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