本文综述了中温热熔预浸料用环氧树脂体系,包括国内外基体树脂及固化体系的发展现状;分析了粘度对基体树脂的影响规律、固化剂和促进剂的匹配、催化剂的选择等;重点介绍了脲类衍生物和咪唑两类固化促进体系的进展;表明环氧树脂热熔预浸料研制的技术关键是选择合理的树脂体系组合,有较长潜伏期的固化剂和促进剂的匹配及合适的催化剂.
参考文献
[1] | Hajime Kishi;Masazuml Iokunoh;Testuyuki Kyono et al.Epoxy resin composition for a fiber reinforced composite material,yarn prepreg,and process and apparatus for preparing the same[P].US 6228474,2001-5-8. |
[2] | 大背户浩树;泽冈龟治;野田俊作 .纤维强化复合材料用环氧树脂组合物、预浸料坯及纤维强化复合材料[P].CN 988015250,2001-1-26. |
[3] | 欧阳国恩,孙其海,林凤森.高尔夫球杆用碳纤维预浸布品质研究[J].玻璃钢/复合材料,2003(06):30-32. |
[4] | Decker;Owen H;Mumford et al.Chemorheologically tailored matrix resin formulations and their use in making pre-impregnated fibers and in fabricating composite parts[P].US 5011721,1991-4-30. |
[5] | 洼寺一直;岛美树男;伊滕容记 .环氧树脂预浸处理制品[P].CN 911007520,1991-8-14. |
[6] | 张旭玲;彭先声;张世村 .环氧树脂组成物[P].CN 85102717,1986-10-8. |
[7] | Tsai;Hsi-Chuan;Muroi .Latent curing agent for epoxy resin and its preparation[P].US 5357008,1994-10-18. |
[8] | Zupancic Joseph J;Conrad et al.Substituted cyanoguanidines as curing agents for epoxy resins[P].US 5387656,1995-2-7. |
[9] | 陶永忠 .环氧树脂潜伏性固化剂[P].CN 03115860 9,2004-7-21. |
[10] | Poisson N.;Sautereau H.;Taha M.;Gambert X.;Maazouz A. .Curing of dicyandiamide epoxy resins accelerated with substituted ureas[J].Journal of Applied Polymer Science,1998(12):2487-2497. |
[11] | Wang Q.;Storm BK.;Houmoller LP. .Study of the isothermal curing of an epoxy prepreg by near-infrared spectroscopy[J].Journal of Applied Polymer Science,2003(14):2295-2305. |
[12] | Shangjin He;Keyu Shi;Jie Bai;Zengkun Zhang;Liang Li;Zongjie Du;Baolong Zhang .Studies on the properties of epoxy resins modified with chain-extended ureas[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(23):9641-9647. |
[13] | 王仲群;宁荣昌;焦剑.中温固化环氧树脂基体的研究[J].玻璃钢/复合材料,1997(03):10-11. |
[14] | Blyakhman;Yefim .1-imidazolylmethyl-2-naphthols as catalysts for curing epoxy resins[P].US 5591811,1997-1-7. |
[15] | John F. Timmerman;Matthew S. Tiliman;Brian S. Hayes .Matrix and fiber influences on the cryogenic microcracking of carbon fiber/epoxy composites[J].Composites, Part A. Applied science and manufacturing,2002(3):323-329. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%