欢迎登录材料期刊网

材料期刊网

高级检索

本文采用非等温DSC方法对碳纤维增强复合材料压力容器的树脂体系进行固化动力学研究.应用Malek方法处理实验数据,得到此树脂体系机理函数服从一个二参数(m,n)的自催化模型,其中活化能通过Ozawa法得到.通过温度场模拟结果与试验值比较,验证本文建立的动力学模型的可靠性.因此,可为复合材料压力容器固化成型过程中瞬态温度场的模拟提供必要子模型.

参考文献

[1] Ortega A. .ISOCONVERSIONAL METHOD IN CRTA[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,1997(1/2):161-164.
[2] 胡荣祖;史启桢.热分析动力学[M].北京:科学出版社,2001
[3] Zhongjun Li;Xiaoqing Shen;Xun Feng .Non-isothermal kinetics studies on thermal decomposition of zinc hydroxide carbonate[J].Thermochimica Acta,2005,438:102-106.
[4] N Sbirrazzuoli;Y Girault;L Elegant .The Málek method in the kinetic study of polymerization by differential acanning calorimetry[J].Thermochimica Acta,1995,249:179-187.
[5] Mohamed A Mohamed;Andrew K Galwey .A comparative study of the thermal reactivities of some transition metal oxalates in selected atmospheres[J].Thermochimica Acta,2004,411:13-20.
[6] Litwinienko G.;Kasprzycka-Guttman T. .A DSC study on thermoxidation kinetics of mustard oil[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,1998(1/2):185-191.
[7] Opfermann JR.;Kaisersberger E.;Flammersheim HJ. .Model-free analysis of thermoanalytical data-advantages and limitations[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2002(1/2):119-127.
[8] Rosu D;Mititelu A;Cascaval CN .Cure kinetics of a liquid-crystalline epoxy resin studied by non-isothermal data[J].Polymer Testing,2004(2):209-215.
[9] Zvetkov VL. .Comparative DSC kinetics of the reaction of DGEBA with aromatic diamines. I. Non-isothermal kinetic study of the reaction of DGEBA with m-phenylene diamine[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(16):6687-6697.
[10] Alessia Catalani;Maria Grazia Bonicelli .Kinetics of the curing reaction of a diglycidyl ether of bisphenol A with a modified polyamine[J].Thermochimica Acta,2005,438:126-129.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%