以MgAl-NO3-LDHs为前驱体,采用离子交换法成功地将2-羟基-4-甲氧基二苯甲酮-5-磺酸(HMBA)阴离子插层到MgAl-NO3 -LDHs层间,借助SEM、XRD、FT-IR、TG-DTA和UV-Vis等手段对样品进行了表征.结果表明,HMBA阴离子可完全取代前驱体层间的NO;离子,并且与主体层板产生较强的超分子相互作用.MgAl-HMBA-LDHs的紫外吸收性能较HMBA客体增强,热稳定性明显提高.将MgAl-HMBA-LDHs加入至玻璃钢基体中,明显提高了玻璃钢基体的耐紫外光老化性能.
参考文献
[1] | Sasaki S;Aisawa S;Hirahara H;Sasaki A;Nakayama H;Narita E .Synthesis and adsorption properties of p-sulfonated calix[4 and 6]arene-intercalated layered double hydroxides[J].International Journal of Quantum Chemistry,2006(4):1129-1135. |
[2] | Zhang LY;Lin YJ;Tuo ZJ;Evans DG;Li DQ .Synthesis and UV absorption properties of 5-sulfosalicylate-intercalated Zn-Al layered double hydroxides[J].International Journal of Quantum Chemistry,2007(4):1230-1235. |
[3] | Ping Yueh W;Yu Ping C;Pei Zhen Y .The effect of a UV-absorber on the photostability of Acid dyes on silk[J].Dyes and Pigments,1996,30(02):141-149. |
[4] | Weisbrod CJ;Kunz PY;Zenker AK;Fent K .Effects of the UV filter benzophenone-2 on reproduction in fish.[J].Toxicology and Applied Pharmacology,2007(3):255-266. |
[5] | John C. Crawford .2(2-Hydroxyphenly)2H-benzotriazole ultraviolet stabilizers[J].Progress in Polymer Science,1999(1):7-43. |
[6] | Manzi-Nshuti C;Hossenlopp JM;Wilkie CA .Fire retardancy of melamine and zinc aluminum layered double hydroxide in poly(methyl methacrylate)[J].Polymer Degradation and Stability,2008(10):1855-1863. |
[7] | Wang ZY;Han EH;Ke W .Influence of nano-LDHs on char formation and fire-resistant properties of flame-retardant coating[J].Progress in Organic Coatings: An International Review Journal,2005(1):29-37. |
[8] | Cao Y;Zhao Y;Jiao Q .Fe-based catalysts from Mg/Fe layered double hydroxides for preparation of N-doped carbon nanotubes[J].Materials Chemistry and Physics,2010,122(2-3):612-616. |
[9] | Redouane Chebout;Didier Tichit;Geraldine Layrac;Akila Barama;Bernard Coq;luliana Cota;Eliana Ramirez Rangel;Francisco Medina .New basic catalysts obtained from layered double hydroxides nanocomposites[J].Solid state sciences,2010(6):1013-1017. |
[10] | Xian-Ming Liu;Yi-He Zhang;Xiao-Gang Zhang;Shao-Yun Fu .Studies on Me/Al-layered double hydroxides (Me = Ni and Co) as electrode materials for electrochemical capacitors[J].Electrochimica Acta,2004(19):3137-3141. |
[11] | M. Badreddine;A. Legrouri;A. Barroug .Ion exchange of different phosphate ions into the zinc-aluminium-chloride layered double hydroxide[J].Materials Letters,1999(6):391-395. |
[12] | L.C. Hsu;S.L. Wang;Y.M. Tzou;C. F. Lin;J.H. Chen .The removal and recovery of Cr(VI) by Li/Al layered double hydroxide (LDH)[J].Journal of hazardous materials,2007(1/2):242-249. |
[13] | Fusu Li;Lan Jin;Jingbin Han .Synthesis and Controlled Release Properties of Prednisone Intercalated Mg-Al Layered Double Hydroxide Composite[J].Industrial & Engineering Chemistry Research,2009(12):5590-5597. |
[14] | Fabiano Silverio;Marcio Jose dos Reis;Jairo Tronto;Joao Barros Valim .Removal of aliphatic amino acids by hybrid organic-inorganic layered compounds[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(13):5756-5761. |
[15] | Palmer S.J;Frost R.L.Use of Hydrotalcites for the Removal of Toxic Anions from Aqueots Solutions[J].Industrial and Engineering Chemistry Research,2010:8969-8976. |
[16] | Zhao Y.;Li F.;Zhang R.;Evans DG.;Duan X. .Preparation of layered double-hydroxide nanomaterials with a uniform crystallite size using a new method involving separate nucleation and aging steps[J].Chemistry of Materials,2002(10):4286-4291. |
[17] | Caniazo D;Domingo C;Martín C;Rives V .Structural and Texture Evolution with Temperature of Layered Double Hydroxides Intercalated with Paramolybdate Anions[J].Inorganic Chemistry,2005,45(03):1243-1251. |
[18] | Sun W;He Q;Lu L;Liu H .Synthesis and properties of layered double hydroxides intercalated with cinnamic acid series organic UV ray absorbents[J].Materials Chemistry and Physics,2008(2/3):261-265. |
[19] | Z. P. Xu;H. C. Zeng .Decomposition Pathways of Hydrotalcite-like Compounds Mg~1-xAl_x(OH)_2(NO_3)_x center dot nH_2O as a Continuous Function of Nitrate Anions[J].Chemistry of Materials,2001(12):4564-4572. |
[20] | Malanowski, P;Huijser, S;Scaltro, F;van Benthem, RATM;van der Ven, LGJ;Laven, J;de With, G .Molecular mechanism of photolysis and photooxidation of poly(neopentyl isophthalate)[J].Polymer,2009(6):1358-1368. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%