本文系统地研究了MA、PA、BA三种苯并噁嗪树脂的黏度、固化特性和残炭率.研究结果表明,MA树脂虽残炭率最高,但要达到较好的浸渍工艺性需加热到100℃以上,且固化温度高;而BA树脂加热起泡严重,黏度很高,反应活化能最高,不适合直接加热浸渍;PA树脂加热到70℃就能达到很好的浸渍工艺性,且固化温度最低,反应活化能也最低,残炭率适中.
参考文献
[1] | Ning X;Ishida H .Novel approach to phenolic materials:synthesis and characterization of phenolic resins via ring opening polymerization[J].J Appl Polym Sci Chem Ed,1994,32(06):1121-1129. |
[2] | Hyun Jin Kim;Zdenka Brunovska;Hatsuo Ishida .Molecular characterization of the polymerization of acetylene-functional benzoxazine resins[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(7):1815-1822. |
[3] | H. J. Kim;Z. Brunovska;H. Ishida .Synthesis and thermal characterization of polybenzoxazines based on acetylene-functional monomers[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(23):6565-6573. |
[4] | Schreiber H .Phenolic resin as electric insulator[P].German:2217099,1973. |
[5] | 肖丽群,余若冰,赵圩,焦扬声.苯并噁嗪树脂基芳砜纶纤维及玻璃纤维复合材料性能的研究[J].玻璃钢/复合材料,2010(06):21-24. |
[6] | 王智,顾宜.碳纤维增强苯并噁嗪树脂基复合材料的研究进展[J].玻璃钢/复合材料,2011(04):68-72. |
[7] | 张世杰,张炜,郭亚林.纳米炭粉改性炭布/苯并噁嗪复合材料性能研究[J].玻璃钢/复合材料,2009(02):29-32. |
[8] | 尹昌平,肖加余,曾竟成,刘钧,代晓青.苯并噁嗪树脂流变特性及工艺窗口预报研究[J].材料工程,2008(06):5-8,12. |
[9] | 于伯龄;姜胶东.实用热分析[M].北京:纺织工业出版社,1990 |
[10] | Prime R B;Sacher E .Kinetics of epoxy cure:2.The system bisphenol-A diglycidyl ether/polyamide[J].Polymer,1972,13(09):455-458. |
[11] | Kissinger H E .Reaction kinetics in differential thermal analysis[J].Analytical Chemistry,1957,29(11):1702-1706. |
[12] | 李晔,黄启忠,朱东波,巩前明.液相浸渍法制备C/C复合材料[J].炭素,2001(04):14-18. |
[13] | 李晔 .树脂浸渍法增密制备炭/炭复合材料[D].中南大学,2002. |
[14] | Hemvichian, K;Kim, HD;Ishida, H .Identification of volatile products and determination of thermal degradation mechanisms of polybenzoxazine model oligomers by GC-MS[J].Polymer Degradation and Stability,2005(2):213-224. |
[15] | 白会超 .高残碳苯并噁嗪树脂的研究[D].武汉理工大学,2007. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%